关于浙江“黄岩窑”青瓷工艺技术相关问题的研究——以黄岩沙埠窑址群为例

为探索\"黄岩窑\"青瓷的工艺技术及艺术装饰特征,并探讨该窑场与同时期浙东地区的\"越窑\"青瓷的关系,本研究从田野考古调查入手,通过对黄岩沙埠窑窑址及窑场周围地面考古调查和典型青瓷标本的实物取样,结合科技考古的手段,着重对其产品特征、制瓷工艺技术及烧造年代等方面进行科学研究。通过光学显微镜解剖了黄岩出土青瓷胎釉的内部结构;通过热释光技术对黄岩出土青瓷典型标本进行年代测定;并运用EDXRF技术对黄岩出土青瓷标本和上林湖越窑标本的胎釉化学成分进行检测并对比分析。研究表明:浙江黄岩沙埠窑址是晚唐至南宋时期浙江重要的窑址遗存,具有较高的陶瓷烧造技艺。     

On the intrinsic accuracy and precision of luminescence dating techniques for fired ceramics

Luminescence dating techniques have been used extensively for archaeological and geological samples. Such techniques are based on thermally or optically stimulated signals. This paper presents simulations of several luminescence techniques for equivalent dose (ED) estimation for ceramic materials containing quartz. The simulations are carried out using a recently published comprehensive kinetic model for quartz, consisting of 11 electron and hole traps and centers. The complete sequence of the experimental protocols for several thermoluminescence (TL) and optically stimulated luminescence (OSL) techniques are simulated using the same set of kinetic parameters. The specific simulated protocols are: additive dose TL protocol, predose technique (both additive and multiple activation versions), phototransfer protocol, single aliquot regenerative optically stimulated luminescence (SAR-OSL) protocol, and SAR thermoluminescence protocol (SAR-TL). One hundred random variants of the natural samples were generated by keeping the transition probabilities between energy levels fixed, while allowing simultaneous random variations of the concentrations of the 11 energy levels. The relative intrinsic accuracy and precision of the protocols are simulated by calculating the equivalent dose (ED) within the model, for a given natural burial dose of the sample. The intrinsic accuracy of these techniques is estimated by simulating natural irradiation of the samples with a known burial dose, followed by simulation of the luminescence method used to recover the estimated dose ED. The percent difference between the burial dose and the ED value represents the simulated accuracy of the luminescence technique. The relative intrinsic precision of these techniques is estimated by fitting Gaussian probability functions to the ED values obtained with the 100 model variants. It is found that the various techniques can reproduce natural paleodoses in the range 10 mGy–10 Gy with a typical intrinsic accuracy of +1 to 10%. Techniques based on single aliquot protocols were found in general to be more precise than techniques requiring the use of multiple aliquots. In addition, techniques based on interpolation of experimental data were found to be consistently both more precise and accurate than those based on extrapolation of experimental data.     

耀州窑瓷器的热释光特性研究及年代测定

耀州窑是中国古代北方青瓷的代表,在青瓷发展史上占有重要位置。为了深入研究耀州窑青瓷的热释光特性,提高热释光测定耀州窑瓷器年代的准确性,本研究测试了16件耀州窑瓷片。前剂量饱和指数法被应用于测定耀州窑青瓷的古剂量。运用厚源计数法测量瓷胎与埋藏环境土壤样品的α计数、X射线荧光光谱仪测量K含量等方法进行年剂量测定;得到了针对测量耀州窑瓷器样品的热释光特性参数,优化了测量程序,获得了更适用于耀州窑地理环境的年剂量数据,减小了未来样品的取样量,为更好地研究与鉴别其真伪提供了有效的科学依据与方法。     

Preliminary U-series and Thermoluminescence dating of excavated deposits in Liang Bua sub-chamber,Flores, Indonesia

We report the results of a test excavation of deposits in a limestone cave sub-chamber located beneath the main chamber of Liang Bua, Flores, Indonesia; the discovery site of the small hominin species, Homo floresiensis. Well-preserved remains of extinct Pleistocene fauna and stone artefacts have previously been identified on the surface of a sediment cone within the sub-chamber. Our excavation of the deposits, at the base of the sediment cone in the sub-chamber (to 130 cm depth) yielded only a few fragmentary bones of extant fauna. Uranium/Thorium (U-series or U/Th) dating of soda straw stalactites excavated from 20 to 130 cm in depth demonstrates that the excavated sediments were deposited during the Holocene. Red Thermoluminescence (TL) dating of the sediments at the base of the excavation (130 cm depth) indicates these sediments were last exposed to sunlight at 84 ± 15 ka (thousand years), similar to red TL ages of cave sediments from the main chamber. Together, these results indicate that the surface faunal remains, which are morphologically analogous to Pleistocene finds from the main chamber excavations, were transported to the sub-chamber relatively recently from the main chamber of Liang Bua and probably originated from conglomerate deposits at the rear of the cave and from deposits around the front entrance. There is no evidence for hominin occupation of the sub-chamber, instead it seems to have acted as a sink for cultural materials and fossil remains transported from the surface via sinkholes. Despite the small number of finds from the test excavation, it is possible that more extensive excavations may yield additional transported cultural and faunal evidence at greater depths.     

Thermoluminescence dating of a Stillbay–Howiesons Poort sequence at Diepkloof Rock Shelter (Western Cape,South Africa)

New excavations have been undertaken at Diepkloof Rock Shelter (DRS; South Africa) since 1999. It is one of the very few sites where Howiesons Poort and Stillbay assemblages can be collected from the same archaeological sequence. These Middle Stone Age techno-complexes are particularly interesting for their affinities with the much younger Later Stone Age facies, and their association with evidence for symbolic behaviour. Establishing their chronology is therefore particularly important for the understanding of the apparition and the evolution of the so-called “modern” behaviours. Data already available suggest ages ranging from 55 to 80 ka for the Howiesons Poort and from 70 to 80 ka for the Stillbay techno-complexes in several South African sites. The thermoluminescence dating undertaken at DRS on 22 stone samples originating from the entire stratigraphic record indicates intervals starting 10–50 ka earlier for these techno-complexes in this site. Possible caveats in the dating process are examined but to the best of our current knowledge must be rejected.     

原始瓷的三种年代测定方法结果比较

采用常规的热释光细粒混合矿物法、热释光前剂量饱和指数法以及单片再生剂量光释光法三种测年方法,对中国上海、浙江萧山地区出土的7件西周、春秋、战国以及汉代的原始瓷样品进行了年代测定,并对测得的每个样品的3个年代结果与已知年代进行比对。用热释光细粒混合矿物法测定得到了较为理想的年代结果,与样品的已知年代结果相比吻合得较好。用热释光前剂量饱和指数法测定得到了该方法的上限饱和年代,即距今1800年左右。用再生剂量光释光法测定得到了这些样品的年代,只是实际年代的50％-80％左右,结果不太理想。因此,采用热释光细粒混合矿物法测定这类样品的年代,只要解决了制样问题,还是目前较好的测年方法。     

瓷器热释光测定年代研究

本工作从标准的(即线性的)前剂量技术着手,研究了瓷器热释光测定年代的方法。在这个研究中,发现了瓷器的灵敏度对剂量的非线性响应和灵敏度随剂量变化的指数模式。因此,一个用饱和指数拟合的方法被提了出来。实验表明,这是一个测定瓷器年代的成功方法。另外,还对一些与测定年代有关的复杂因素进行了讨论。例如,当少数瓷器的灵敏度与剂量不呈指数关系时,就要改变拟合模式或采用B的平均值方法等。     

Luminescence chronology of the medieval citadel of Termez,Uzbekistan: TL dating of bricks masonries

Among the dating methods in archaeology, thermoluminescence (TL) is widely developed. The present research concerns the construction chronology of the citadel of Termez (Uzbekistan) in the medieval period. On the methodological side along the TL study, we had to take into account two decisive factors that are expected to affect the accuracy: control of anomalous fading on the polymineral fraction (quartz and feldspars) and the effect of thermal treatments on the luminescence properties of the dated material. With regard to the determination of the annual dose, difficulties, associated with the evolution of the radiochemical composition of the dated samples and their environment over time, were overcome.