TECHNOLOGY AND COLOUR DEVELOPMENT OF HISPANO-MORESQUE LEAD-GLAZED POTTERY

Lead-glazed pottery from the medieval workshop of Les Olleries Majors (Paterna, Spain) has been studied by Mössbauer spectroscopy, X-ray diffraction, X-ray fluorescence and optical spectroscopy. Yellow, brown and honey-coloured glazes occur on pots glazed on only one surface. They have virtually identical compositions and transmittance spectra, their apparent differences in colour are due to the colours of the underlying pastes. Yellow glazes occur on cream-coloured calcareous bodies, honey-coloured glazes occur on less calcareous bodies with some development of hematite, while brown glazes occur on red siliceous cooking-pots. Green glazes are found on pots glazed on both surfaces; the glazes trapped CO₂ evolved by decomposing carbonates, resulting in an internal reducing environment. This caused the reduction of iron to the ferrous state which coloured the glaze green by diffusion.     

QUANTITATIVE ANALYSIS OF COPPER-TIN BRONZES BY MEANS OF GLOW DISCHARGE OPTICAL EMISSION SPECTROMETRY

Glow discharge optical emission spectrometry (GDOES) has been used for obtaining calibration curves for copper, tin, lead, silver, antimony, arsenic, zinc and iron from standards including copper-base alloys (Cu 61.33-99.95%) and from bronze Punic coins. The GDOES results were calibrated using atomic absorption spectroscopy with inductively coupled plasma atomization (ICPAAS) to analyse the standards and coins. For all these materials, the results show that via GDOES it is possible to obtain reliable and reproducible calibration curves for copper, tin, lead, zinc and iron with a linear behaviour as a function of the content. The quantitative GDOES and ICPAAS data for the coins have been also compared with those obtained via X-ray fluorescence (XRF) and it is shown that GDOES, ICPAAS and XRF agree well with one another considering that the bronze coins are inhomogeneous to some degree. As an example of GDOES analytical features, a depth concentration profile through a thin bronze patina is shown and briefly discussed.     

LIME PLASTER AS AN ADHESIVE FOR HAFTING EIGHTEENTH-DYNASTY FLINT SICKLES FROM TELL EL DAB'A,EASTERN NILE DELTA (EGYPT)*

A combination of analytical techniques, including thin-section observations, scanning electron microscopy, X-ray diffraction and X-ray fluorescence analysis, was applied to study the nature and origin of an adhesive used for mounting flint sickle blades to a wooden handle, recovered from early Eighteenth Dynasty culture layers of the multi-layer settlement at Tell el Dab'a, Lower Eygpt. The results obtained from these investigations led to the conclusion that the adhesive is a pure lime plaster, thus providing the oldest evidence for the use of this material as a binding agent so far known in ancient Egypt.     

X-RAY FLUORESCENCE AND DENSITY MEASUREMENTS ON SURFACE-TREATED ROMAN SILVER COINS*

Some 630 Roman silver coins excavated at Augusta Raurica (Switzerland) have been analysed by non-destructive X-ray fluorescence and X-ray diffraction. Furthermore, the density and the weight have been determined. The measured average density of plated and massive depletion-silvered coins is lower than the density calculated from the chemical composition, whereas massive coins display equal values for both of the densities. Based on experimental X-ray investigations of modern silver (tempering, acid treatment, production of corrosion layers), the nature of corrosion products on silver, their impact on surface analysis, and aspects of wearing-off by circulation are briefly discussed.     

The Chemical Composition and Production Area of Early Western Zhou Proto‐Porcelain Unearthed from Yejiashan Cemetery,Suizhou, China

The bodies and glazes of 27 early Western Zhou proto‐porcelain samples from Yejiashan cemetery, Hubei Province, were analysed using LA‐ICP–AES, SEM, XRD, a thermal expansion instrument and other analytical methods. The results indicated that the bodies of all samples were characterized by high silicon and low aluminium, and were made with porcelain stone raw materials found in the south of China. The glazes are typical of high‐temperature calcium glazes of the CaO (MgO) – K₂O (Na₂O) – Al₂O₃ – SiO₂ series, with relatively high Mn and P content, which was probably caused by the addition of plant ashes. The physical properties and phase compositions of Yejiashan proto‐porcelain show that firing processes were still in the early stages of development in ancient China. Multivariate statistical analyses indicated that Yejiashan proto‐porcelain might have come from the Deqing area, in Zhejiang Province. These results provide new archaeological evidence for research on issues related to material flow in the Western Zhou dynasty.     

Operating anew: Queering GIS with good enough software

In the last decade, conversations around queering of GIScience emerged. Drawing on literature from feminist and queer critical GIS, with special attention to the under‐examined political economy of GIS, I suggest that the critical project of queering all of GIS, both GIScience and GISystems, requires not just recognition of the labour and lives of queers and research in geographies of sexualities. Based upon a queer feminist political economic critique and evidenced in my teaching critical GIS at two elite liberal arts colleges, I argue that the “status quo” between ESRI and geography as a field must be interrupted. Extending a critical GIS focus beyond data structures and data ethics, I argue that geographic researchers and instructors have a responsibility in queering our choice and production of software, algorithms, and code alike. I call this production and choice of democratic, accessible, and useful software by, for, and about the needs of its users, good enough software.     

Investigating Human Migration and Horse‐Trading in Yelang (夜郎) Through Strontium Isotope Analysis of Skeletons from Zhougshui Sites,South‐West China (1300 bc – ad 25)

Yelang (夜郎), a mysterious state located in the south‐western area of early China and dating from the Bronze Age to the Early Iron Age (1300 bc – ad 25), is a cultural interactive junction between the Yunnan–Guizhou Plateau and the Yangtze River Basin. The Zhongshui Basin in Weining County, Guizhou Province, was one of the important distribution areas of the Yelang civilization. This area, which includes sites at Jigongshan (鸡公山; 1300 – 800 bc ), Hongyingpan (红营盘; 700 – 400 bc ) and Yinzitan (银子坛; 400 bc – ad 25), has provided a very integrated chronology, spanning from the Bronze Age to the Early Iron Age in the eastern Yunnan – western Guizhou area. To investigate human migration and horse‐trading at these Yelang sites, we conducted a strontium isotopic analysis on the teeth enamel of humans and horses unearthed from these three sites. The results indicated the following: (1) people at the earlier sites (Jigongshan and Hongyingpan) were all indigenous, whereas in the Yinzitan cemetery, there was a more immigrant population, and all the people who were buried in an upper limb flexed supine position were non‐local; and (2) most of the horses found at the Jigongshan and Yinzitan sites show different provenances, probably related to the famous Dian (滇) and Zuo (筰) horses recorded in historical documents, providing more clues for further study on horse‐trading in South‐West China during the Bronze Age and the Early Iron Age.     

The Archaeometry and Archaeology of Ancient Chinese Glass: a Review

This paper provides a new review of archaeometric research carried out on glass found in China, set in an archaeological context, from its earliest occurrence to the Song dynasty. It is set within a broad geographical context taking the terrestrial and maritime Silk Road contacts into account. We discuss chemical and isotopic compositional contrasts in glasses from different periods found in different parts of China, the glasses that were almost certainly made in China and those that were imported. A theme that runs through the paper is the problem of provenancing glass found in China, along with a lack of evidence for primary glass‐making sites and minimal evidence for secondary glass production. We discuss the glass artefacts that are of typical Chinese types and contrast these with imports; the structure reflects this contrast. We discuss potential new scientific and archaeological approaches to Chinese glass.     

The Evolution of the Vitruvian Recipes over 500 Years of Floor‐Making Techniques: The Case Studies of the Domus delle Bestie Ferite and the Domus di Tito Macro (Aquileia,Italy)

The paper reports the results of a research project aimed at the characterization of the floor bedding mortars of two Roman houses in Aquileia (north‐eastern Italy), the Domus delle Bestie Ferite and the Domus di Tito Macro. Seventy floor bedding mortars of the two domus were selected and almost half were fully minero‐petrographically characterized by means of optical microscopy operated in transmitted light (OM‐TL), X‐ray powder diffraction analyses coupled with quantitative phase analysis by means of the Rietveld method (XRPD‐QPA) and scanning electron microscopy with EDS microanalysis (SEM–EDS). The results indicate an evolution of the mortar preparation techniques over time in the mosaic of both houses. The materials are compared to the traditional Roman recipes for specific construction techniques.