Phosphatic mineralization of seeds from archaeological sites

Recent investigations of botanical material from archaeological sites have provided seeds and plant remains exhibiting a crystalline or semi-crystalline appearance. X-ray diffraction and partial chemical analysis have revealed that the particular plant materials had been replaced by calcium phosphate. Using systematic sampling and retrieval techniques a significant body of data has been accumulated. Most mineralized botanical evidence has been recovered from faecal deposits, in particular cess pits and garderobes, and has provided an important source of information about aspects of diet of past populations.     

青海瞿昙寺壁画颜料的研究

通过对青海瞿昙寺画郎和建筑彩绘所用的22个绘画颜料样品的 x-射线衍射和同位素 x 荧光分析.共分析出20多种无机矿物颜料,此外.还有蓝钯、黄钯有机颜料。本文对这些颜料的分析结果进行丁综合论述.并与敦煌石窟、麦积山石窟、炳灵寺石窟等的彩绘颜料进行了研究。     

三峡出土宋元青白瓷产地的判别

为研究重庆地区三峡工程抢救性发掘出土了一批宋元时期青白瓷的产地,采用中子活化方法,分析了28枚三峡出土宋元时期的青白瓷残片和20枚时期相近、窑口已知的青白瓷残片,利用SPSS软件对上述样品胎体的微量元素数据进行统计分析.结果发现:江西产青白瓷的稀土元素含量与福建、安徽、湖北等地差异显著,而Rb、Cs、Hf、Th等微量元素含量也明显不同;三峡出土的青白瓷样品中,除编号为荣阳5和涂山窑5这两枚残片外,其余残片的元素特征与景德镇所产青白瓷颇为一致,拟断定这些青白瓷源自景德镇.     

X-ray powder diffraction analysis of Late Holocene reservoir sediments

X-ray powder diffraction (XRD) analysis of clays from anthropogenic Late Holocene reservoir sediments can provide a paleoclimatic proxy. Illite and smectite are climate sensitive clay minerals and their relative amounts correlate with climatic episodes. Relative percent composition of clays in Late Holocene reservoir sediment is diagnostic of different mineral source areas and their hydraulic transport processes, which are climate controlled. Climosequences of clay minerals from Late Holocene reservoir sediments are correlative with magnetic susceptibility records and provide a relatively simple and cost-effective tool for gaining insight into paleoclimate.     

Preliminary neutron diffraction study of two fenestrated axes from the ‘Enot Shuni' Bronze Age cemetery (Israel)

Neutron diffraction (ND) analyses of ancient metals show that this method is capable of detecting differences in the inner composition and microstructure of ancient metal objects. Here, ND measurements were conducted on two ‘eye shaped’ axes from the end of the 3rd-beginning of the 2nd millennium BC. The objects were excavated from the ancient cemetery of ‘Enot Shuni' Israel; one is made of bronze and the other of silver. Both artefacts are rare finds, with the silver axe unique in the archaeology of Israel, and therefore had to be analysed locally. For that purpose, a newly assembled diffractometer (KARL) at the IRR-1 of the Nuclear Research Centre (Soreq, Israel) was used. ND measurement on the bronze axe revealed the existence of an α-phase with a range of Cu/Sn ratios (Cu–Sn solid solutions) and some amount of a δ-phase (intermetallic compound of Cu and Sn). The silver axe ND pattern shows the existence of an α-phase (Ag–Cu solid solution) and some amount of copper metal. Our ND data are discussed in comparison with XRF surface measurements and thermal neutron radiography. The results are shedding more light on the in-depth material composition profile, as well as on the objects’ structural and compositional affinities, and help to better understand the production processes and assist in conservation decisions.     

The influence of different tempers on the composition of pottery

The modification of the raw clay by the potter to produce a paste suitable for the intended purposes adds a layer of obfuscation to the problem of provenancing the original clay source by chemical fingerprinting. By preparing different pastes from the same commercially available raw clay and their chemical analysis by Instrumental Neutron Activation Analysis, an experiment under controlled conditions (tempers, mixing ratios, firing temperatures and sampling methods) sheds light on the influence of different tempers.     

Geomorphological setting and Native American acquisition of buff-firing ceramic clays in the Lower and Middle Gila River Valley, Arizona

This study addresses buff-firing clay sources in dynamic alluvial settings along Arizona’s Gila River in the U.S. Southwest. We establish clay resource distribution relative to the geomorphic histories of the Lower and Middle Gila River based on 38 clay samples and ethnographic data from two US Bureau of Reclamation (BOR) projects. Buff-firing clayey alluvium, deposited in the Gila River floodplain 800 to 1,500 or more years ago, was a surficial ceramic raw material source for prehistoric Hohokam and lowland Patayan potters. This geomorphic unit was later removed in some places and buried by up to 3-4 m of sediment in others, reducing the availability of buff-firing clays in the Hohokam Classic period and requiring historic Pee Posh and Akimel O’odham potters to dig pits to access it. Sources were further destroyed in catastrophic floods in the late 19th and early 20th century, affecting ceramic manufacture patterns and ultimately contributing to the decline of pottery production by the O’odham living in the Gila River Valley. Our results contribute to regional ceramic ecology and should also be of interest to others investigating alluvial clay use in general or buff-firing alluvial clays in particular. The study also illustrates the value of combining geomorphic and ethnographic data to examine major changes in resource distribution and use.     

A new perspective on Late Holocene social interaction in Northwest Alaska: results of a preliminary ceramic sourcing study

This research examines the evidence for prehistoric ceramic exchange networks over the last 2000 years in northwest Alaska through the use of neutron activation analysis of ceramic artifacts. Results from ceramic analysis on eight coastal and inland archaeological sites identified three source macrogroups and three associated subgroups. Clay source diversity and shared source macrogroups between geographically distant sites suggest the use of multiple sources and/or the movement of pots between production locales, mirroring related patterns in pottery stylistic data. Although additional analytical work is needed to fully understand the changing character of clay procurement and ceramic distribution across this time period, this study provides exploratory data on past ceramic production and distribution that hints at changes in exchange and territoriality in northwest Alaska during the late Holocene.     

Cultural dynamics and ceramic resource use at Late Bronze Age/Early Iron Age Troy,northwestern Turkey

Changes in resource use over time can provide insight into technological choice and the extent of long-term stability in cultural practices. In this paper we re-evaluate the evidence for a marked demographic shift at the inception of the Early Iron Age at Troy by applying a robust macroscale analysis of changing ceramic resource use over the Late Bronze and Iron Age. We use a combination of new and legacy analytical datasets (NAA and XRF), from excavated ceramics, to evaluate the potential compositional range of local resources (based on comparisons with sediments from within a 10 km site radius). Results show a clear distinction between sediment-defined local and non-local ceramic compositional groups. Two discrete local ceramic resources have been previously identified and we confirm a third local resource for a major class of EIA handmade wares and cooking pots. This third source appears to derive from a residual resource on the Troy peninsula (rather than adjacent alluvial valleys). The presence of a group of large and heavy pithoi among the non-local groups raises questions about their regional or maritime origin.     

Assessing Ceramic Compositional Data: A Comparison of Total Reflection X‐ray Fluorescence and Instrumental Neutron Activation Analysis On Late Iron Age Spanish Celtiberian Ceramics

A solid‐phase, non‐chemical processing protocol was recently developed as a means of chemically characterizing archaeological ceramics by total reflection X‐ray fluorescence (TXRF). Following this methodology, TXRF can provide semi‐quantitative determinations for 18 elements with comparable levels of precision and accuracy for the majority of them in comparison with a clay reference material analysed by instrumental neutron activation (INAA). In order critically to assess the analytical capabilities of TXRF, a large sample set of Late Iron Age Spanish Celtiberian ceramics and modern clays was analysed both by TXRF and INAA. Semi‐quantitative chemical data provided by TXRF and quantitative data provided by INAA were subjected to commonly used multivariate statistical methods as a way of evaluating the ability of the new technique to discriminate among different compositional groups. The comparison of the two data sets shows no significant discrepancies, thereby allowing support for the same archaeological interpretation. These results suggest that TXRF has potential applicability for compositional characterization of archaeological ceramics, providing data that are useful for provenance studies.