Low‐temperature catalytic CO2 hydrogenation with geological quantities of ruthenium: a possible abiotic CH4 source in chromitite‐rich serpentinized rocks

Metal‐catalysed CO₂ hydrogenation is considered a source of methane in serpentinized (hydrated) igneous rocks and a fundamental abiotic process germane to the origin of life. Iron, nickel, chromium and cobalt are the catalysts typically employed in hydrothermal simulation experiments to obtain methane at temperatures >200°C. However, land‐based present‐day serpentinization and abiotic gas apparently develop below 100°C, down to approximately 40–50°C. Here, we document considerable methane production in thirteen CO₂ hydrogenation experiments performed in a closed dry system, from 20 to 90°C and atmospheric pressure, over 0.9–122 days, using concentrations of non‐pretreated ruthenium equivalent to those occurring in chromitites in ophiolites or igneous complexes (from 0.4 to 76 mg of Ru, equivalent to the amount occurring approximately in 0.4–760 kg of chromitite). Methane production increased with time and temperature, reaching approximately 87 mg CH₄ per gram of Ru after 30 days (2.9 mgCH₄/g_ru/day) at 90°C. At room temperature, CH₄ production rate was approximately three orders of magnitude lower (0.003 mgCH₄/g_ru/day). We report the first stable carbon and hydrogen isotope ratios of abiotic CH₄ generated below 100°C. Using initial δ¹³C_CO2 of ‐40‰, we obtained room temperature δ¹³C_CH4 values as ¹³C depleted as ?142‰. With time and temperature, the C‐isotope separation between CO₂ and CH₄ decreased significantly and the final δ¹³C_CH4 values approached that of initial δ¹³C_CO2. The presence of minor amounts of C₂‐C₆ hydrocarbons is consistent with observations in natural settings. Comparative experiments at the same temperatures with iron and nichel catalysts did not generate CH₄. Ru‐enriched chromitites could potentially generate methane at low temperatures on Earth and on other planets.     

Middle Bronze Age Arsenical Copper Alloys in Southern Portugal

In the Iberian Peninsula, the copper metallurgy from the Chalcolithic to the Middle Bronze Age (MBA) was mostly characterized by low arsenic contents. A collection of 53 MBA artefacts from southern Portugal was analysed by micro‐EDXRF, optical microscopy, SEM–EDS and Vickers to investigate the metal composition and manufacture. No technological distinction was found between artefacts from domestic and funerary contexts, which were radiocarbon‐dated to 2000–1500 cal bc . The arsenic contents of almost 100 MBA artefacts from this region, including the above‐mentioned set, have a Gaussian distribution with a high average (3.9 wt% As). Possible explanations are discussed for this distinctive metallurgy at the south‐western end of the Iberian Peninsula.     

Characterization of a Historical Cannonball from the Fortress of San Juan De Ulúa Exposed to a Marine Environment

Metallurgical analyses and chemical characterizations were carried out on historical cannonballs from the Fortress of San Juan de Ulúa, Veracruz, México. Cannonballs dating from the 18th and 19th centuries share metallurgical characteristics similar to those of material coming from a shipment of ammunition found in the wreck of a sunken French ship from the battle of Trafalgar. The analyses show that the base material is grey cast iron with a carbon equivalent of 4.94 and a ferritic–perlitic matrix, in which the high phosphorus content has led to the formation of iron phosphide compounds in conjunction with a homogeneous distribution of carbon graphite flakes of Type C. In addition, corrosion products from samples revealed the presence of various crystalline iron compounds (X‐ray diffraction), mostly highly chlorinated iron compounds identified as akaganeite. X‐ray fluorescence identified various characteristics of the corrosion products as a function of the sampling depth. FT–IR spectroscopy revealed that the main difference between the corrosion products (internal and external) is determined by the number of organic species. Differential scanning calorimetry corroborated that these corrosion products are thermally stable compounds at elevated temperatures.     

Salafī‐Ashʻarī Polemics of the 3rd & 4th Islamic Centuries

While Sunnism is the largest sect of Islam, Sunnism itself is divided into many strands. The two main strands of Sunnism for the last few centuries are the Atharī (or Salafī) strand, and the Ash?arī strand. This papers seeks to examine the earliest recorded controversies that signal this intra‐Sunnī divide. While each of these two groups has historically attempted to claim true Sunnī ‘orthodoxy’ by denying the legitimacy, and at times even the early existence, of the other, it will be shown that the genesis of this intra‐Sunnī divide dates back to the first century of Sunnism itself, viz., the 3^rd AH/8^th CE centuries, and that there are specific historic incidents that indicate theological tensions within the nascent Sunnī movement that would later be manifested in the two streams of Ash?arism and Salafism. Hence, it can be argued that Sunnism was never truly unified to begin with, and that these incidents demonstrate theological tensions that existed from its very origins.     

民国《贵州通志·艺文志》“《尔雅集韵》”条辩证

民国《贵州通志·艺文志》著录黄彭年撰《尔雅集韵》一书。而追索《艺文志》著录的史源,并取其他史料相印证,推寻其致误的原因,证明黄彭年曾批校《尔雅》《集韵》二书,但并未撰《尔雅集韵》一书。此外,又据各家书目题跋,梳理了黄彭年批校《集韵》的经过及其批校本流传情况。     

“With almost clean or at most slightly dirty hands”. On the self-denazification of German geography after 1945 and its rebranding as a science of peace

Since the 1980s there is an overall agreement that German academic and applied geography between 1933 and 1945 were closely linked to the ideology and practice of National Socialism. There is very little historical work, however, on how geography was reestablished in Germany after the end of National Socialism. This paper deals with West German geography after 1945 and the attempts to reestablish geography as a legitimate discipline within academia. Taking the influential paper by German geographer Carl Troll as a starting point, this paper deals, on the one hand, with the way geographers positioned geography in relation to National Socialism, and how they told the history of their recent past. It then asks what the defeat of Germany and the experiences of the war in general meant for how geographers in Germany thought about the relation between the discipline and politics. It is argued that a number of cleansing and legitimating strategies that freed geography from direct involvement with National Socialism, went hand in hand with a very quick adaption to the new world order and a rebranding of geography as a science of peace.     

King Davidʼs Exposure while Dancing: A Queer Reading of 2 Samuel 6

According to the Hebrew version of the transport of the ark to Jerusalem in 2 Samuel 6, King David is so scantily dressed that he publicly exposes himself while dancing before G*d (????). David?s wild, gay and possibly sexual conduct can evoke associations with the behavior of gay persons of today. Queer readers may identify with David and like him turn their backs on dominant rulers—like the members of Saul?s dynasty—if they are not respected because of their queer way of life, but persecuted—as David was persecuted by King Saul. Such an interpretation implies that G*d (????) is on the side of persons like King David, who—from the point of view of other people as well as of David?s wife Michal—behave in a strange fashion, thus act queerly.     

Context and the role of policies to attract foreign R&D in Europe

This paper explores the effectiveness of policies ‘in’ attracting the foreign research and development (R&D) of multinational enterprises (MNEs) to specific countries in Europe. We develop a macroeconomic investigation covering 29 European countries during the period between 1990 and 2012 in order to address: (a) whether the provision of direct financial support for business R&D is effective for the attraction of foreign R&D; (b) whether direct support is more effective than indirect support for this purpose and (c) whether the link between direct financial support for business R&D and the foreign R&D of MNEs is conditioned by the context within which the support is provided. The results of the analysis show that, first, the provision of direct financial support is generally effective for the attraction of foreign R&D by MNEs. Second, direct support for business R&D is more effective for this purpose than indirect support. Third, the provision of direct financial support for business R&D yields greater returns in contexts that are more socio-economically suitable for knowledge-intensive, innovative activity.     

Snail assemblages: interrogating an environmental controversy involving Powelliphanta augusta and the mining industry in Aotearoa New Zealand

In 2004, a controversy arose in Aotearoa New Zealand's coal mining sector that involved Powelliphanta augusta, a species of land snail. This paper considers that controversy in terms of emergent assemblages involving the snail, the mining industry, the Department of Conservation, political action by environmental non‐government organisations, and public expressions of environmental and other values. Three sets of relations embedded in those assemblages are examined—those related to positioning and organising nature; values, politics, and power relations; and human and non‐human materialities. Those relations illuminate how a protracted controversy and its objects form a “social test bed” for contested views in legislation and guidelines dealing with economy, conservation, and restoration. To assess the dynamics, complexities, and contingencies of such relations, attention is paid to the controversy's detailed time line and legal framing, as well as to ontological shifts of snail and habitat and snail metrics. This analytical focus highlights the shifting quality of ideas about how the snail and its habitat are understood as entangled in fraught and mutating strategies of translocation that are played out in a particular regulatory setting. It also provides insights into international geographical efforts to re‐shape environmental governance and management.