Assessing Ceramic Compositional Data: A Comparison of Total Reflection X‐ray Fluorescence and Instrumental Neutron Activation Analysis On Late Iron Age Spanish Celtiberian Ceramics

A solid‐phase, non‐chemical processing protocol was recently developed as a means of chemically characterizing archaeological ceramics by total reflection X‐ray fluorescence (TXRF). Following this methodology, TXRF can provide semi‐quantitative determinations for 18 elements with comparable levels of precision and accuracy for the majority of them in comparison with a clay reference material analysed by instrumental neutron activation (INAA). In order critically to assess the analytical capabilities of TXRF, a large sample set of Late Iron Age Spanish Celtiberian ceramics and modern clays was analysed both by TXRF and INAA. Semi‐quantitative chemical data provided by TXRF and quantitative data provided by INAA were subjected to commonly used multivariate statistical methods as a way of evaluating the ability of the new technique to discriminate among different compositional groups. The comparison of the two data sets shows no significant discrepancies, thereby allowing support for the same archaeological interpretation. These results suggest that TXRF has potential applicability for compositional characterization of archaeological ceramics, providing data that are useful for provenance studies.     

海洋出水木质文物保护中的硫铁化合物问题

海洋出水的木质文物中通常会沉积硫铁化合物。打捞出水后,硫铁化合物遇到空气和水分后会发生氧化,生成硫酸以及各种硫酸盐,并引起有机质的降解。近年来,硫铁化合物对海洋出水木质文物的危害已引起广泛关注。为此,本工作阐述了硫铁化合物相关问题的研究现状,就硫铁化合物的产生原因、危害以及目前控制方法的研究进展进行了总结,同时评述了针对硫铁化合物的处理方法。     

甘肃拉卜楞寺壁画表面涂层材质分析

西藏壁画表面大多刷有保护涂层。据记载,其材质主要是桐油、牛胶或清漆等。但目前,对该涂层材质科学的研究却较少,不利于后期保护修复。为配合拉卜楞寺壁画保护修复项目,本研究以衰减全反射红外光谱法(ATR-FTIR)、核磁共振氢谱法(~1H-NMR)、热裂解-气相色谱-质谱联用(Py-GC-MS)技术等分析手段,对甘肃夏河拉卜楞寺弥勒佛殿、时轮学院主殿壁画的涂层进行了分析。结果表明,两处佛殿壁画涂层可确定是一种干性油,种类与桐油较接近。但由于西藏壁画在材料和工艺上的独特性,材料老化等因素,拉卜楞寺壁画涂层在组成和结构上,与现代桐油有一定差别,表现出一定的丰富性和复杂性。后期修复,可采用性质与西藏传统涂层材料接近的干性油,例如桐油,作为新的壁画表面涂层材料。     

A Multi-Mode Method for Estimation of Floor Response Spectra

A new simplified procedure for estimation of floor response spectra (FRS) is proposed. This methodology enriches the most common procedures using nonlinear response-history analysis to predict FRS by including a direct multi-mode technique to estimate FRS. A novel feature of the procedure is that the coupling effect is considered to establish equivalent modal systems and the FRS are developed by incorporating capacity spectrum method in conjunction with ductility-based FRS for each modal system. Both the proposed method and the traditional method are applied to three steel moment frame structures, and a reasonable accuracy is demonstrated.     

Seismic Evaluation of Tall Buildings Using a Simplified but Accurate Analysis Procedure

A simplified analysis procedure for evaluating the nonlinear seismic responses of tall reinforced concrete (RC) buildings is examined in this study. It is called the Uncoupled Modal Response History Analysis (UMRHA) procedure. It can be viewed as an extended version of the classical modal analysis procedure, where the nonlinear response of each vibration mode is first computed, and they are later on combined into the total response of the structure. The procedure requires the knowledge of the modal hysteretic behavior, which can be obtained from a cyclic modal pushover analysis. The responses of four tall buildings in Bangkok to distant large earthquakes are computed by this procedure and compared with those obtained from the Nonlinear Response History Analysis (NLRHA) procedure. These four buildings have different heights—varying from 20 to 44 stories, different configurations of floor plan, and different arrangement of RC walls. The comparison shows that the UMRHA procedure is able to accurately compute the story shears and story overturning moments, floor accelerations, and inter-story drifts of all these tall buildings. The required computational effort is also extremely low compared to that of the NLRHA procedure. Moreover, since the UMRHA procedure computes the response of each individual vibration mode, it provides more understanding and insight into the complex nonlinear seismic responses of these tall buildings.     

Effects of Geometrical Features on the Seismic Response of Historical Masonry Towers

ABSTRACT

Historical masonry structures are often located in earthquake-prone regions and the majority of them are considered to be seismically vulnerable and unsafe. Historical masonry towers are slender structures that exhibit unique architectural features and may present many inadequacies in terms of seismic performance. The seismic protection of such typologies of structures and the design of effective retrofitting interventions require a deep understanding of their behavior under horizontal loads. This paper presents the results of the seismic performance evaluation of historical masonry towers located in Northern Italy. A large set of case studies is considered, comprising a significant number of towers with high slenderness and marked inclination. First, a preliminary assessment of the dynamic behavior of the different towers is carried out through eigenfrequency analyses. Then, non-linear dynamic simulations are performed using a real accelerogram with different peak ground accelerations. A damage plasticity material model, exhibiting softening in both tension and compression, is adopted for masonry. The huge amount of results obtained from the non-linear dynamic simulations allows a comparative analysis of the towers to be performed in order to assess their seismic vulnerability and to show the dependence of their structural behavior on some geometrical characteristics, such as slenderness, inclination, and presence of openings and belfry. The evaluation of different response parameters and the examination of tensile damage distributions show the high vulnerability of historical masonry towers under horizontal loads, mainly in the presence of marked inclination and high slenderness. Some general trends of the seismic behavior of the towers are deduced as a function of the main typological features.     

Scalar Structure-Specific Ground Motion Intensity Measures for Assessing the Seismic Performance of Structures: A Review

The assessment of the seismic performance depends on the choice of the earthquake Intensity Measure (IM). During the past years many IMs, which take into account not only earthquake characteristics but also structural information, have been proposed. However, no consensus on which IM is the best predictor of the seismic response exists. Along these lines, the objective of this paper is to present the various developed scalar structure-specific seismic IMs and the problems associated with their use in practice, so that the engineer may become familiar with them and their implications in the context of Performance-Based Earthquake Engineering.     

PROVENANCING AND ARCHAEOLOGY OF ROMAN MILLSTONES FROM SARDINIA (ITALY)

Summary. Sardinia was an important Roman settlement and trade centre between 238 BC–500 AD and is an ideal site for study of Roman trade. Study of Roman millstones in Sardinia shows that the commonest type is the Pompeian (hour-glass) mill (forty-eight stones studied), with smaller numbers of cylindrical hand querns (sixteen stones studied). Most of these millstones are composed of igneous rocks which include grey vesicular lavas of basic/intermediate composition and a distinctive reddish rhyolitic ignimbrite. There is historical and archaeological evidence for millstone manufacture at six localities in Sardinia. Visual and petrographic study and X-ray fluorescence analysis for major and trace elements of seventeen millstone samples, and fifty rock samples from potential source areas have been used to provenance the igneous rock millstones. The grey vesicular lava millstones have varied sources within the Tertiary-Recent volcanic rocks of Sardinia, while the millstones composed of rhyolitic ignimbrite are from a single source of Tertiary ignimbrite at Mulargia (central west Sardinia). A single hand mill from the north of Sardinia was imported probably from Agde in southern France, and is the only sample composed of non-local rock. Mulargia millstones were widely traded within the western Mediterranean and show a rapid decrease in frequency of occurrence with increasing distance from the source. Sardinia was therefore an important centre of Roman millstone production and a source of millstone trade during the period of Roman settlement.     

Poaceae phytoliths from the Niassa Rift,Mozambique

The most common grass phytoliths from “Zambezian” miombos are described here for the first time. Their potential for long term preservation in sediments makes them a useful tool in the reconstruction of ancient plant communities and plant/human interactions. We processed 60 plant samples (26 identified genera and species), with an average of 300 phytoliths counted per sample to a total of 18,586. Forty-seven morphotypes were described as per the International Code for Phytolith Nomenclature, with exceptions, including forty-five discreet shapes and two articulated forms, which can be used as comparative reference materials. We conducted three forms of statistical analyses: Discriminant Analysis, Cluster Analysis, and Principal Component Analysis. The highest biomineral content was recorded among the Bambuseae and Paniceae, while the lowest silica production is detected in the Cynodonteae tribe. Typologically, the subfamily Panicoideae yielded 50% of the types reported here, 32% are from the Chloridoideae, 12% from the Bambusoideae, and 8% from the Arundinoideae sensu lato. Overall, the idealized Zambezian Poaceae phytolith spectrum is dominated by a small subset of Poaceae short cells, which include five morphotypes conventionally associated with Panicoid grasses (Bilobate concave outer margin long shaft, Bilobate concave outer margin short shaft, Bilobate convex outer margin long shaft, Bilobate convex outer margin short shaft, Cross), one morphotype commonly seen in Chloridoid taxa (saddle), and two types that appear across subfamily boundaries (tower, tower horned). The next logical step to take in regional phytolith research is the account of phytoliths deposited in soils underneath living plants, for they represent the interface between existing vegetation communities and the inevitably distorted fossil assemblages that the paleobotanist uses for environmental reconstruction.     

Production centers of cooking pots in Iron Age Judah

This paper will present and discuss a multifaceted research project dealing with the production of cooking pots during the Iron Age II (ca. 1,000–586 BCE) Judah (modern Israel). In particular the new compositional analysis of 541 cooking vessels from 11 sites in Iron Age Judah will be presented. The study employs petrographic and chemical (NAA) analysis. The results of this ongoing research have already produced interesting information about production centers and movements of cooking pots in Iron Age II Judah. Apparently, the vast majority of the cooking pots sampled were made of a similar type of clay, related to terra rossa soil. This is true also for sites in the northern Negev and Judean Desert, where the type of soil was not available in the region of the sites. Furthermore, many of the cooking pots distributed around Judah were made in Jerusalem according to a well-located chemical profile (JleB). Other groups may represent Judean Shephelah production centers as the Lachish area as well as production centers in southern Israel or ancient Edom. The implications of the importation patterns of cooking pots by peripheral Judean sites will be discussed.