Bulk element composition versus trace element composition in the reconstruction of an obsidian source system

It has become possible, through compositional analysis, to differentiate among discrete obsidian quarry and collecting localities within a single source area. The analytical potential of such information is considerable yet studies are seldom undertaken owing to the difficulties associated with trace element analysis.This study is intended to explore the feasibility of using bulk element data instead of trace element data in such compositional analyses. Techniques of bulk element analysis are far more accessible to archaeologists. The results of an experiment utilizing carefully controlled samples from the El Chayal obsidian source, Guatemala, are reported and discussed.     

X-ray and spectrographic analyses of terracotta figurines from myrina: an attempt to characterize workshops

Physico-chemical techniques of analysis have been applied to a series of Hellenistic terracotta figurines found at Myrina on the coast of Asia Minor to explore the feasibility of using chemical and mineralogical composition as parameters in the identification of figurine workshops. The results suggest that there is a tentative basis for the correlation between composition and stylistic criteria among the figurines. The difficulties associated with this approach are discussed, and account is taken of an earlier enquiry that was carried out on similar lines.     

Iron-57 Mössbauer spectral studies of medieval stained glass

⁵⁷Fe Mössbauer spectral data for six excavated and two simulated medieval stained glass samples are reported. Iron-containing precipitates are observed in the two simulated medieval glasses and are responsible for the amber colour of these samples. The ferrous/ferric ratio of the other samples is dependent on the glass composition and glass making conditions. The green glasses are associated with the presence of both ferrous and ferric iron, the ratio being very similar in three of the glasses studied, while in the purple and emerald green glasses the iron which is constitutionally incorporated in the glass is solely in the ferric oxidation state. The UVvisible spectra of some of the glasses are used to assist in interpretation of the colourant action of iron, and the role of Mössbauer spectroscopy in linking separate glass fragments with a common source is also indicated.