一批中国古代镶嵌玻璃珠化学成分的检测报告

结合外束质子激发X荧光（proton induced X-ray emission,PIXE）和能量色散X射线荧光（energy dispersive X-ray emission,EDXRF）分析技术,对中国新疆、湖北、四川、广东出土的古代镶嵌玻璃珠的化学成分进行了检测.结果表明：新疆拜城克孜尔墓地出土的西周-春秋时期镶嵌玻璃珠为CaO-MgO-SiO2玻璃,战国时期中国境内的PbO-BaO-SiO2和Na2O-CaO-SiO2镶嵌玻璃珠是同时存在的.本文亦对相关问题进行了一些讨论,并提出了部分今后的工作建议.     

Archaeometric investigation of Roman tesserae from Herculaneum (Italy) by the combined use of complementary micro-destructive analytical techniques

Vitreous tesserae from two mosaics in Herculaneum (Italy) dating from the 1st century AD have been investigated in order to gather information on Imperial Age opaque glass. The combined use of complementary micro-destructive analytical techniques, namely optical microscopy (OM), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), inductively coupled plasma-mass spectrometry (ICP-MS), transmission electron microscopy (TEM), and X-ray powder diffraction (XRPD) allowed to define the nature of formers, fluxes, chromophores and opacifying compounds and to determine the type of raw materials employed for their introduction. The results confirmed the high technological level of Imperial Age glassmakers and clarified some details of the production processes. Experimental data have been obtained concerning formation of antimony-based opacifiers. The presence of tin-containing Ca- and Pb-antimonates has been ascertained in various green, yellow and turquoise tesserae. Moreover, unusual divergences from the established Roman age ‘low magnesia–low potash’ (LMLK) glass composition have been found for some red and green samples.     

High precision isotopic analyses of lead ores from New Mexico by MC-ICP-MS: implications for tracing the production and exchange of Pueblo IV glaze-decorated pottery

Between ca. 1275 and 1700 CE, Pueblo groups in the northern Southwest United States produced and exchanged ceramic bowls decorated with lead-based glaze paints. Previous studies of these glaze-decorated bowls have used lead isotopic analysis by ICP-MS to identify the sources of lead used by Pueblo potters, and investigate how social or economic factors may have influenced resource use among different Pueblo communities (e.g. 13 and 14; Huntley et al., 2007; Huntley, 2008). However, interpretations of much of this isotopic data have remained provisional because of overlap among the isotopic ratios of potential sources and because the isotopic composition of many glaze paints do not clearly match any known source. Here, we use multi-collector ICP-MS to re-measure the lead isotopic composition of 48 samples of lead sulfide (galena) and lead carbonate (cerussite) from sources in New Mexico that were potentially utilized by Pueblo potters, including mines within the Cerrillos Hills, Magdalena, Hansonburg, and Joyita Hills mining districts. These results define the isotopic composition of lead ores from these districts with greater precision and accuracy than achieved in previous studies and better distinguish among these mining districts in lead isotope space. Most significantly, we find that galena mineralization within the Cerrillos Hills only has a modest degree of isotopic variation, with ²⁰⁶Pb/²⁰⁴Pb ratios from 18.508 to 18.753, ²⁰⁷Pb/²⁰⁴Pb ratios from 15.580 to 15.607, and ²⁰⁸Pb/²⁰⁴Pb ratios from 38.388 to 38.560. These ranges are far narrower than previously reported, and should supersede previously published values for this district. In total, we conclude that isotopic measurements of both ores and glaze paints made by MC-ICP-MS will provide new information about the provenance of lead in glaze paints and allow for more detailed interpretations about resource procurement and exchange in the Pueblo world.     

Condemned to metallum? The origin and role of 4th–6th century A.D. Phaeno mining campresidents using multiple chemical techniques

The Byzantine period (4th–7th centuries A.D.) site of Khirbet Faynan (Phaeno) was a state-run mining camp described in ancient sources as a destination for Christian martyrs and others prosecuted by the administration who were condemned to the mines (damnatio ad metallum). However, other evidence suggests that Phaeno had a much broader role and population in antiquity than that described by ancient writers. Here, strontium and oxygen isotope data on the level of migration into Phaeno were compared with elemental data on lead and copper skeletal levels to illuminate the varied exposure of local vs. non-local individuals to contaminated environments (presumably from working in mining and smelting operations). Dental enamel ⁸⁷Sr/⁸⁶Sr and δ¹⁸O data from 31 individuals excavated from the Southern Cemetery identified one individual born in a region with different strontium isotope values in the bedrock yet similar oxygen isotope signatures as Faynan. Most of the primarily locally-derived Faynan residents displayed skeletal copper and lead levels exceeding those seen in comparative samples, confirming that growing up and residing in the polluted environment of Faynan led to notable bioaccumulation of heavy metals and its resulting health effects. In addition, ten individuals had extremely elevated lead and copper levels in their skeleton resulting from more intensive exposure to contaminated environments, possibly through smelting and mining activities. These data confirm the relatively localized nature of this imperial operation and that this predominantly locally-derived population had different activities that put them ask varied risk for contamination by heavy metals.     

Lead isotope analyses of gold–silver ores from Roşia Montană (Romania): a first step of a metal provenance study of Roman mining activity in Alburnus Maior (Roman Dacia)

The Ro?ia Montan? ore deposit (Apuseni Mountains, Romania) is Europe’s largest Au–Ag deposit. It also corresponds to the Roman Alburnus Maior mining site, known by historians and archaeologists due to the discovery of dozens of Roman wooden wax tablets during the underground works carried out during the 18th and 19th centuries.     

XRF analysis of glass beads from the Mycenaean palace of Nestor at Pylos,Peloponnesus, Greece: new insight into the LBA glass trade

In recent years there has been a growing interest in Mycenaean glass among archaeologists and scientists. Scholars have traditionally thought that all Mycenaean glass was imported either in finished form or as ingots and simply shaped or worked at the Mycenaean sites. Chemical studies of other Mycenaean glass (50 and 43) support the hypothesis that glass was imported into Mycenaean Greece, but there is also indication for glass production in mainland Greece at the palace of Thebes (Nikita and Henderson, 2006). There is no evidence for glass making or working at the Palace of Pylos, yet there is an abundance of glass beads there. The aim of this paper is to identify the technology and source for the glass of these beads and thus to ascertain how Pylos was connected to the broader Mycenaean and Mediterranean economies. The composition of the glasses was determined by means of portable XRF analysis and compared to that of other Late Bronze Age glasses from Egypt, Mesopotamia and mainland Greece. Four blue beads coloured with cobalt and one blue bead coloured with copper have Ti and Zr compositions consistent with an Egyptian origin of manufacture while five other beads show Ti and Zr concentrations consistent with a Mesopotamian origin (Shortland et al., 2007). Based on the dearth of Egyptian and Mesopotamian imports in Pylos, the presented data support the hypothesis that Pylos was receiving via internal Greek trade routes foreign-produced glass, which may have been worked abroad or in Greece.