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11.
Colour measurements and non‐destructive μ‐X‐ray mappings have been used for the first time in a comprehensive study of medieval émail champlevé works from different production areas in France and Germany. This approach has given a new insight into the enamel powder preparation process of the glass material used for enamelling. Colour measurements demonstrated that all production centres used glass of very similar hues, but with large differences in colour saturation. The μ‐X‐ray mapping results of blue enamels are described by a semi‐qualitative approach. Significant variations in oxide contents of lead, cobalt, manganese and antimony oxides were found. The variations suggest that more than one glass material was used to prepare the powder for enamelling. The variations in antimony and cobalt show that glass had different degrees of opacity and colour depth. The manganese and lead contents, which do not correlate with the cobalt or antimony contents, indicate that probably glass of different base compositions was used to prepare the enamel powder for one champlevé field. 相似文献
12.
Z. Liu A. Mehta N. Tamura D. Pickard B. Rong T. Zhou P. Pianetta 《Journal of archaeological science》2007
Until the 19th century, most pigments were based on naturally occurring colored minerals and dyes, with three significant exceptions: Egyptian Blue, Chinese Blue/Purple and Maya Blue. The former two are alkaline-earth copper silicates, and because of this similarity it has been proposed that the Chinese pigments were derived from Egyptian Blue. Herein, we analyzed clumps of pigment from the Qin warriors and discovered that in spite of the structural similarity to Egyptian Blue, the micro-structural morphology of Chinese Purple is very different. Therefore, we believe that the synthesis technology for the Chinese pigments was a by-product of high-refractive index glasses (artificial jades) produced by Taoist monks. Further, the disappearance of these pigments from Chinese art and monuments concurrently with the decline of Taoism not only substantiates the link between the two, but also gives a striking example of how cultural changes in the society affected the scientific developments in ancient China. 相似文献
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14.
C. N. Duckworth R. Córdoba de la Llave E. W. Faber D. J. Govantes Edwards J. Henderson 《Archaeometry》2015,57(1):27-50
Twenty‐six samples from domestic assemblages of 9th–12th century Córdoba were subjected to electron microprobe analysis. The results reveal two main compositional types. The first, encountered in 13 of the samples, seems to result from the combination of plant ashes with high‐impurity sand, and has some contemporary parallels from Syria and Egypt. The second type is a lead–soda–silica glass, encountered in a relatively high proportion of the glasses (11 of the 26 sampled), possibly formed by the addition of lead metal to existing glasses and with very few known parallels. These are among a very small number of results available to date on the chemical composition of glasses from medieval Spain, and the presence of a high proportion of lead–soda–silica glasses is particularly interesting, possibly indicating a technological practice unique to, or originating in, the western Muslim world. 相似文献
15.
V. Kemp K. Schmidt W. Brownscombe K. Soennecken D. Vieweger J. Häser A. Shortland 《Archaeometry》2020,62(6):1164-1181
Fourteen glass objects recovered from excavations at the ancient city of Tall Zirā‛a, Jordan, were analysed using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to determine the period and origin of manufacture. The composition of glasses manufactured in the Late Bronze Age (LBA) and Iron Age are distinctly different, therefore major element analysis can be used to distinguish between the groups relatively easily. The LA-ICP-MS analysis provided quantitative trace element data which were used to determine the provenance of those glasses identified as LBA. This research discusses the implications of the presence of both Egyptian and Mesopotamian LBA glasses and examines the varying compositions and colour strategies employed in both the LBA and Iron Age objects. Specifically, glass in the LBA was considered to be one of the highest status items attainable, playing an instrumental role in diplomatic gift-giving. When considered with the archaeological information, the significance of these finds at Tall Zirā‛a indicates that this city was a settlement of high status, not primarily a convenient trading stop on the Transjordan route. 相似文献
16.
The study analyses the chemical composition of 57 glass samples from 40 beads discovered at 20 archaeological sites in Poland. The beads are dated to Hallstatt C–Early La Tène periods (c.800/750–260/250 bce ). Analyses were carried out using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Two groups were distinguished among the glasses based on the MgO/K2O ratio: high-magnesium glass (HMG), five samples; and low-magnesium glass (LMG), 52 samples. The former were melted with halophyte plant ash, the second with mineral soda. These glasses were produced in the Eastern Mediterranean (more likely in Mesopotamia or Syro-Palestine than in Egypt) and transported in the form of semi-products to secondary glass workshops in Europe. Some of the white opaque glass was coloured and opacified in Europe. 相似文献
17.
本文利用激光拉曼光谱仪和能量色散X-射线荧光光谱仪对21件取自故宫博物院院藏宋代官窑完整器及42件取自杭州老虎洞官窑窑址的青瓷样品表面釉层进行了测量与分析。通过计算瓷釉样品拉曼光谱中位于500cm-1附近宽带与位于1000cm-1附近宽带的面积比值(Ip值)及利用EDXRF分析样品的元素成分,讨论了这些样品的主要助熔剂成分Ca O、K2O含量与Ip值之间的关系,并通过对成分具有两类典型官窑瓷器釉料特征且在不同烧成温度下烧制的模拟釉块进行拉曼分析,对宋官窑青瓷样品的釉烧温度进行了讨论。 相似文献
18.
G. Huelga‐Suarez M. Moldovan M. Suárez Fernández M. Ángel de Blas Cortina J. I. García Alonso 《Archaeometry》2014,56(4):651-664
This paper continues the characterization of the lead isotopic fingerprint of ancient copper mines in the north‐west of Spain. In this work, the lead isotopic compositions found in copper ores from the La Profunda mine are presented. Azurites and malachites sampled from this deposit were subjected to lead isotope analysis by multicollector ICP–MS. The results showed a clear radiogenic lead signature compatible with the presence of uranium‐rich minerals (such as zeunerite) in the same mining complex. Moreover, a rare copper artefact, found in the galleries of the mine during its modern exploitation, was also analysed and showed that local mineral was used for its manufacturing. 相似文献
19.
论文对加拿大二线城市卡尔加里和爱德蒙顿华人新移民的主要特点、移民动机和融合过程中的主要障碍进行了分析,探讨了新移民在加拿大向下层社会流动的问题。研究显示,新移民在经济融合过程中遭遇多方面的障碍,尤其在就业和语言方面。他们在移民加拿大之后,经历了去技能化和以前的学历和工作经验贬值,促使他们向下层社会流动,而这种状况反过来又阻碍了他们的融合进程。华人新移民的负面经历可以归因于由玻璃大门、玻璃房门和玻璃天花板构成的"三重玻璃效应"。加拿大政府应采纳融合框架政策,除承认移民的流动自由外,还要保证他们能享有与其他加拿大人一样同等的公民权益。 相似文献
20.