Non-ferrous metallurgy from the Phoenician site of La Fonteta (Alicante, Spain): a study of provenance

The lead isotope composition of 22 samples from the excavation of the Phoenician site of La Fonteta (Guardamar del Segura, Alicante, Spain) has been analysed in a preliminary study of their provenance. These materials span chronologically from the first half of the 8th century BC to the middle of the 6th century BC.The samples have been selected to include materials used in lead and silver production, as well as in copper-based metallurgy. Therefore, lead droplets, galena nodules and fragments of litharge have been analysed, together with a fragment of a copper ingot, an object, a melting waste composed of a Cu–Pb alloy, and two fragments of a material that we have provisionally labelled ‘Pb–Cu cupellation debris’.All these materials have been initially analysed by X-Ray Fluorescence-Spectrometry to identify their bulk compositions. Some of them have been also analysed by SEM–EDX and ICP–OES. Subsequently, lead isotope analyses (LIA) have been performed using Thermal Ionization Mass Spectrometry (TIMS). The new LIA data obtained has been compared with published lead isotope data from the Mediterranean area. The identification of different groups suggests a significant complexity of the internal and external trade routes during the Orientalising period. For this reason, the provenance study of these materials is especially important in shedding light on the commercial dynamics that the Phoenicians established with native people to control the raw materials and to commercialise finished products.     

Indications of embalming in Roman Greece by physical,chemical and histological analysis

The partially mummified remains of a high-status female (ca. 1700 BP, Thessaloniki, Greece) were found inside a Roman-type marble sarcophagus containing a lead coffin. The individual was positioned on a wooden pallet, wrapped in bandages, and covered with a gold-embroidered purple silk cloth. Besides the clothes, remnants of soft tissue as well as the individual's original hair style and eyebrows were exceptionally well preserved. In addition to the macroscopic examination, microscopic and biochemical analyses were undertaken. Scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, and gas chromatography/mass spectrometry (GC/MS) were applied to examine the tissue preservation and probable mechanisms of mummification. The presence of chemical components, such as sesquiterpenes, triterpenoids, and diterpenoids, originating from coniferous and pistacia resins, myrrh, and other spices, verify ancient information on preparation methods of the dead in Greek and Roman times. These chemical components are thought to have played a prominent role in the mummification mechanism in this particular case. The potential effect of the lead coffin in the mummification process was also examined. Energy-dispersive X-ray analysis failed to detect lead penetration into the tissues, suggesting that the coffin played a limited role in the preservation of soft tissue.     

Ancient copper and lead pollution records from a raised bog complex in Central Wales,UK

This paper presents records of metal deposition as preserved by a peatland which has accumulated in the lowland coastal zone at Borth, near Aberystwyth, Ceredigion, mid-Wales, U.K. The research objective was to explore the origins and history of metal mining and (or) metallurgy by reconstructing a geochemical record of copper, lead and zinc pollution for the last four millennia. Two cores were extracted from Borth Bog, one from the raised ombrotrophic part of the bog and another from a minerotrophic part of Borth Bog close to the ancient copper workings at Llancynfelin. Although peat stratigraphy and nutrient status have influenced the geochemical record, the results suggest that an early phase of copper and lead pollution occurred at Llancynfelin whilst lead enrichment occurred in the peat core taken close to the centre of Borth Bog during the Bronze Age and the Roman occupation. Therefore the origins of copper and lead mining and metallurgy possibly extend back to the Bronze Age in central Wales. No record of historical pollution exists at either site. The results of this study also provide further evidence that lead and copper are immobile in ombrotrophic peat and that pollution records can be elucidated from minerotrophic peat. Zinc, however, may have suffered from post-depositional mobility.     

Revisiting Key Sedimentary Archives Yields Evidence Of A Rapid Onset Of Mining In The Mid‐13th Century At The Great Copper Mountain,Falun, Sweden

Mining in Falun, Sweden, was first mentioned in a deed from ad 1288, but previous studies of peat and lake sediments inferred that mining began during the fifth to eighth centuries. In order to reassess these findings, we performed new geochemical analyses on new samples from three key sites: Tisksjöbergets myr, a buried mire alongside the mine; Tisken, a small lake in Falun; and Runn, the main recipient for waters draining through Falun. At Tisksjöbergets myr, the peat contains up to 6% copper, giving it the characteristics of a cupriferous bog. Hence, this record is not useful for tracing early mining. The sediments of Tisken—upon which many of the old interpretations have relied—contain numerous cut wood fragments, and two of those gave young and reversed radiocarbon dates (19th and 16th centuries for 192 and 187 cm, respectively). This indicates that the sediment was derived from infilling and, thus, has little value as a historical record. Runn's sediment—the only reliable record—provides clear evidence of a rapid onset of large‐scale mining from c. ad 1245, with abrupt increases in ore‐related elements—for example, a 34‐fold increase in copper—this increase is consistent with the mid‐13th century burial of the mire at Tisksjöberget.     

Insights into immigration and social class at Machu Picchu,Peru based on oxygen,strontium, and lead isotopic analysis

The Inca Empire (AD 1438–1532) made common practice of relocating individuals, households and entire communities throughout their expansive realm for different reasons depending on subjects' assigned social class. Reconstructing patterns of immigration at Inca-period sites could therefore permit some estimation of the social class(es) among their constituents, and thereby provide insights into the functional dynamics of Inca political economy. However, this is a difficult endeavor using only archaeological lines of evidence. This study presents oxygen, strontium and lead isotopic results from the well-preserved, well-contextualized skeletal population (N = 74) from the Inca site of Machu Picchu, Peru. Isotopic data are used to reconstruct patterns of immigration at the site, which are in turn used to directly estimate the social class of the population. The resulting isotopic data are widely distributed with no apparent modality, matching the expected distribution of a particular class of nonelite retainers. A novel application of multivariate statistics coupled with geological and faunal isotopic reference data also permits tentative estimation of individuals' regions of origin. This study provides empirical and analytical frameworks for future research in reconstructing residential movement and class dynamics in the late prehistoric Andes.     

Strontium isotope analysis of Neolithic and Copper Age populations on the Great Hungarian Plain

The strontium isotope ratio (⁸⁷Sr/⁸⁶Sr) is used in archaeological studies to identify major events of population movement in prehistory such as migration, conquest, and inter-marriage. This study shows that the strontium isotope method can be expanded to identify more subtle shifts in prehistoric human mobility. ⁸⁷Sr/⁸⁶Sr isotope ratios were analyzed in dental enamel from human and faunal specimens from the Late Neolithic and Copper Age on the Great Hungarian Plain. The archaeological record indicates that several aspects of life changed during the transition from the Late Neolithic to the Copper Age (ca. 4500 BC) in Hungary; evidence for increased interaction over a wide geographical area, less resource pooling and the use of secondary products has been used to support the idea that local populations became more mobile, perhaps due to the adoption of an agro-pastoral economy. Results from this study identify a change in the range of strontium isotope values from the Late Neolithic to the Copper Age from a very narrow range of values to a much broader range of values, which suggests that changes in how land and resources were utilized on the Great Hungarian Plain affected incorporation of strontium into the skeletal system. This study indicates that the strontium isotope ratio is a valuable tool for identifying more subtle changes in prehistoric behavior such as a shift to a more pastoral economy.     

Croatian Appoxiomenos alloy composition and lead provenance study

An ancient bronze statue of an athlete with a strigil (known as Apoxiomenos) – was raised from the north Adriatic Sea in 1999. In order to help to determine its place and date of manufacture various scientific techniques were used. ¹⁴C dating performed by the Accelerator Mass Spectrometry (AMS) on the organic material found inside the statue gave calibrated dates between 100 B.C. and 250 A.D. Non-destructive analysis performed by portable X-Ray Fluorescence (XRF) system and external beam Particle Induced X-Ray Emission (PIXE) spectroscopy could not provide representative results for metal alloy composition due to the electrochemical deterioration of the surface of bronze in seawater. This was observed by the analysis of alloy cross-sections performed by the proton microprobe. The analysis showed much higher lead concentrations on the surface of the bronze than inside, confirming that realistic alloy composition can be only performed on samples taken from at least 0.6 mm below the surface. Subsequent micro-PIXE analysis on metal cross-section showed inhomogeneous lead concentrations between 1 and 12%. Lead isotope analysis for provenance investigation has been done on 15 samples using Multi Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS). Analysis showed that lead isotope composition is consistent with some of the lead ores originating either from the Eastern Alps or from Sardinia. Altogether, the results lead to the conclusion that the statue is not of a Greek origin, but most probable it is a Roman copy of the Greek original.     

Lead isotope and metal source of Shang bronzes: a response to Sun et al.’s comments

In this brief response to Sun et al.’s ( 2018 ) comments on our paper, we re‐emphasize that archaeological, chemical and isotopic evidence are all relevant to the discussion about the metal source of the Shang period with highly radiogenic lead isotope ratios. The southern African bronzes have much lower lead contents and quite different lead isotopic signatures than the Shang bronzes. More importantly, there was no metallurgy of any kind in southern Africa before c.200 ce , so southern Africa cannot possibly be the source of Shang bronze, which date to about 1500 to 1000 bce .     

A new approach to tracking connections between the Indus Valley and Mesopotamia: initial results of strontium isotope analyses from Harappa and Ur

Exchange and interaction between early state-level societies in Mesopotamia and the Indus Valley during the 3rd millennium BC has been documented for some time. The study of this interaction has been dominated by the analysis of artifacts such as carnelian beads and marine shell, along with limited textual evidence. With the aid of strontium, carbon, and oxygen isotopes, it is now possible to develop more direct means for determining the presence of non-local people in both regions. This preliminary study of tooth enamel from individuals buried at Harappa and at the Royal Cemetery of Ur, indicates that it should be feasible to identify Harappans in Mesopotamia. It is also possible to examine the mobility of individuals from communities within the greater Indus Valley region.     

A New Method For Combining Lead Isotope and Lead Abundance Data to Characterize Archaeological Copper Alloys*

We present a new methodology for interpreting lead isotope data from archaeological copper alloy objects. It is not based on the conventional isotope ratio biplots, which were originally devised to allow the calculation of the geological age of the lead mineralization, but is derived from isotope mixing models, more often used for presenting strontium isotope data. We illustrate the method by reworking published data on Sardinian Nuragic oxhide ingots and copper alloy artefacts. While we confirm the consensus assumption that the oxhide ingot fragments found on Sardinia are isotopically consistent with Cypriot copper ores (although we see no isotopic reason to favour only Apliki, as originally suggested), we also show that there is evidence for mixing between local and ingot copper in some objects, which was previously not detected. More broadly, we suspect that the apparent mismatch between some source allocations for copper drawn from isotope geochemistry and the rest of the archaeological data in some cases might be due to mixed isotopic signals being incorrectly assigned to a specific source, and suggest that the method presented here will reduce the chances of this happening.