锶同位素分析技术在考古学中的应用研究

在考古化学这个新领域内,考古学家们经过努力,成功地将锶同位素分析技术运用于考古学领域,通过对遗址中人类骨骼的锶同位素分析来对古代人类的迁移情况进行研究。由于考古材料间存在着差别,各个实验室所采用的方法和实验步骤间也存在一些差异,因此还没有统一的分析方法和步骤,至今仍处于进一步的探索之中。在我国的考古学研究中,这项技术还处于起步阶段,迄今为止还未见到相关的研究成果。本文主要对这项技术在考古学上应用的原理及研究中注意事项进行了较为详细的论述,并且计划今后进行这方面的实验研究,希望能为国内同仁进行这方面的研究时提供些许借鉴。     

Severe lead contamination among children of samurai families in Edo period Japan

This paper presents evidence for severe lead contamination among children of samurai families living in a castle town in Edo period Japan (1603–1867). Excavated rib bones were analyzed by atomic absorption, and soft X-ray roentgenograms of long bones were taken. The median values of lead concentration in the bones of children 3 years of age and under(1241.0 μg Pb/g dry bone) and 4–6 years of age (462.5 μg Pb/g dry bone) were significantly higher than those of adult males (14.3 μg Pb/g dry bone) and females (23.6 μg Pb/g dry bone) (p < 0.001). In addition, that of children over 6 years of age (313.0 μg Pb/g dry bone) was significantly higher than those of adult males (p < 0.01) and adult females (p < 0.05). The median value of lead in the bones of children 3 years of age and under was over fifty times higher than that of their mothers (adult females). Hypertrophy was seen in the long bones of five samurai children. In this area, lead lines or lead bands were distinguished by soft X-ray roentgenogram. Samurai children suffered from severe lead contamination in Edo period Japan. When the mothers were nursing their children, the children might have ingested their mother’s white lead non-selectively.     

The marbles of two early Christian churches at Latrun (Cyrenaica,Libya)

The provenance of twenty-seven architectural marbles from the two 6th century AD Christian churches of Latrun (Cyrenaica, Libya) has been established by discriminant function analysis of twelve isotopic, EPR and petrographic/morphological variables. Sixteen samples (59%) originate from Proconnesos, while 8 samples (30%) are assigned to the calcitic quarries of Thasos and 1 to the Docimium quarries near Afyon. The last two samples are of uncertain provenance and might be Proconnesian as well. These results demonstrate that the suggestion made long ago by Ward-Perkins that the presence on non-Proconnesian, possibly Thasian, marbles at Latrun was well founded. Particularly interesting is the strong correlation found between provenance and type of the architectural element sampled. Thasian marbles at Latrun were used exclusively for the manufacture of chancel screens. Seven out of nine screens sampled have this provenance, suggesting that the use of different materials is related to issues of work organisation and specialisation in different marble production centres.     

Pliny the Elder and Sr–Nd isotopes: tracing the provenance of raw materials for Roman glass production

In Roman and Byzantine times, natron glass was traded throughout the known world in the form of chunks. Production centers of such raw glass, active from the 4th to 8th century AD, were identified in Egypt and Syro-Palestine. However, early Roman primary glass units remain unknown from excavation or scientific analysis. The ancient author Pliny described in 70 AD that besides Egyptian and Levantine resources, also raw materials from Italy and the Gallic and Spanish provinces were used in glass making. In this study, the primary provenance of 1st–3rd century AD natron vessel glass is investigated. The use of combined Sr and Nd isotopic analysis allows the distinguishing and characterizing of different sand raw materials used for primary glass production. The isotope data obtained from the glass samples are compared to the signatures of primary glass from known production centers in the eastern Mediterranean and a number of sand samples from the regions described by Pliny the Elder as possible sources of primary glass. Eastern Mediterranean primary glass has a Nile dominated Mediterranean Nd signature (higher than −6.0 ? Nd), while glass with a primary production location in the western Mediterranean or north-western Europe should have a different Nd signature (lower than −7.0 ? Nd). Most Roman glass has a homogeneous ⁸⁷Sr/⁸⁶Sr signature close to the modern sea water composition, likely caused by the (intentional) use of shell as glass raw material. In this way, strontium and neodymium isotopes now prove that Pliny's writings were correct: primary glass production was not exclusive to the Levant or Egypt in early Roman days, and factories of raw glass in the Western Roman Empire will have been at play.     

Hydrogen isotope systematics of hair: archeological and forensic applications

The hydrogen isotope systematics of hair have been explored and several applications demonstrate the type of information that can be recovered from archeological and forensic hair samples. Experiment with modern hair demonstrate that sources of protein-based hydrogen in keratin are food and water. On the basis of a deuterium-enriched drinking study, it was found that 31% of hydrogen in human hair is derived from ingested water. At least 9% of total hydrogen in human hair is isotopically exchangeable with water or water vapor at 25 °C. Nearly complete exchange occurs in a matter of hours. The δD value of body water is approximately 17±10‰ (n=7) more negative than human hair, although there is much scatter in data for modern hair, which is clearly related to variability of the isotopic composition of ingested food and water. Archeological hair samples were analyzed from (i) a 370 year old Incan mummy sacrificed at 5300 m altitude in Argentina (Geoarchaeology 14 (1999) 27) and (ii) from a Woolly Mammoth from Siberia. High spatial resolution data along the length of hair from the mummy indicate seasonal variations in carbon, nitrogen and hydrogen isotope ratios. No hydrogen isotope anomalies are seen in the youngest hair at the base of the scalp, indicating that the individual probably lived at 1600 m, and spent less than a week at high altitudes before death. The mammoth also preserves a seasonal signal, suggesting hair growth rates of 33 cm/year, faster than human hair, but slower than horse tail hair. The limited isotopic range across seasons for the mammoth is consistent with a north-south migration on the order of 1000 km.     

夏家店下层文化遗址出土铜器的矿料来源分析

为进一步了解夏家店下层文化铜器的物料信息,探讨其矿料来源,采用多接收电感耦合等离子体质谱仪(MC-ICP-MS)对4处夏家店下层文化遗址和1处高台山文化遗址出土的部分铜器进行了铅同位素比值测定,并将测定结果同辽西地区几处金属矿的铅同位素数据进行了对比。结果表明:这4处夏家店下层文化遗址出土铜器的原料可能是使用辽西当地的大井多金属矿的矿石冶炼而成,而大山前遗址出土铜器的铅料有可能来自辽宁桓仁的多金属矿,二道井子遗址所出红铜器的铜料则可能另有来源。所属高台山文化的湾柳遗址铜器的铅同位素数据具有高放射性成因铅特征,表明其与同期其他考古学文化存在某种联系。