IDENTIFICATION AND DIFFERENTIATION OF OPAQUE CHINESE OVERGLAZE YELLOW ENAMELS BY RAMAN SPECTROSCOPY AND SUPPORTING TECHNIQUES*

Using Raman spectroscopy, energy-dispersive X-ray fluorescence and X-ray diffraction, the Pb–Sn–Sb triple oxide yellow and lead–tin yellow have been identified on two pieces of cloisonné enamel (Falangcai) porcelains. Lead–tin yellow and lead antimonate yellow have been identified on famille rose porcelains manufactured before and after 1911, respectively. The replacement of the Pb–Sn–Sb triple oxide yellow by lead–tin yellow and that of the lead–tin yellow by lead antimonate yellow are discussed.     

LEAD ISOTOPE ANALYSES OF BRONZE AGE COPPER‐BASE ARTEFACTS FROM AL‐MIDAMMAN,YEMEN: TOWARDS THE IDENTIFICATION OF AN INDIGENOUS METAL PRODUCTION AND EXCHANGE SYSTEM IN THE SOUTHERN RED SEA REGION*

The results of the lead isotope analysis (LIA) of 15 copper‐base artefacts from the Bronze Age site of al‐Midamman, Yemen, are reported. The LIA data suggest the existence of an indigenous Bronze Age metal production and exchange system centred on the southern Red Sea region, distinct from those in neighbouring regions of Arabia and the Levant. These preliminary results are highly significant for the archaeology of the region, suggesting that local prehistoric copper extraction sites have thus far gone unrecorded, and highlighting the need for systematic archaeometallurgical fieldwork programmes in the countries surrounding the southern Red Sea.     

COMPOSITIONAL VARIATION IN ROMAN COLOURLESS GLASS OBJECTS FROM THE BOCHOLTZ BURIAL (THE NETHERLANDS)*

We investigated the major and trace element composition and Pb and Sr isotope characteristics of a series of about 20 colourless glass objects from a single high‐status Roman burial from the Netherlands (Bocholtz). The major elements show a relatively homogeneous group, with one outlier. This is corroborated by the Sr isotopes. Based on the Sb and Pb content, three major groups can be discerned, with two other outliers. This grouping is corroborated by the contents of the trace elements Bi, Sn, Ag, As and Mo, and by variations in lead isotopic ratios. On the basis of these results, we conclude that the glass of all objects was probably made with sand and lime from the same source. The variation in trace elements and lead isotope composition is most likely the result of variations in the composition of the sulphidic antimony ore(s) that were used to decolourize the glass. The composition of the Bocholtz glass is compared with that of other Roman glass, and implications for production models, trade and use of colourless glass objects are discussed. On the basis of isotopic and major element variation, we conclude that the antimony ore presumably originated from different mines.     

DETECTING CHANGES OF CELTIC GOLD SOURCES THROUGH THE APPLICATION OF TRACE ELEMENT AND Pb ISOTOPE LASER ABLATION ANALYSIS OF CELTIC GOLD COINS*

This project follows on from an initial study of Celtic gold coins from the Middle Rhine/Moselle region, which was based on material found at the Martberg, a Late Iron Age/Roman sanctuary and settlement (River Moselle, western Germany; Bendall 2003 ). The earlier work was expanded to encompass over 100 examples of various other regional Celtic gold coinages from the collection of the Römisch‐Germanisches Zentralmuseum, Mainz. The alloy (Au–Ag–Cu) and trace element compositions (in particular Ni, Sb and Pt) were determined by EPMA and LA–ICP–MS, respectively, and their Pb isotope signatures were measured by LA–MC–ICP–MS. Of the 28 trace elements measured, only Ni, Sb and Pt were found to show meaningful variations and so only they are presented here. In particular, differences in the Pt/Au ratios between various groups of earlier coinage (imitations of Philippus and Alexander/Nike staters, Sch. 23 and some early Boian coins) on the one hand, and the majority of the Boian and the southern rainbow cup coinages on the other, indicate a significant difference in the gold sources exploited for these regional coinages. The Pb isotope data confirm previous conclusions that the contribution of gold to the total lead in the Au–Ag–Cu coin alloys can be detected, especially for coins with over 70% gold, and show that possible gold sources include both eastern Mediterranean and Alpine sources. Combining the Pb isotope data with the Pt/Au ratios allows the potential gold sources to be further differentiated.     

STUDY OF ROMAN ANCHOR FROM THE DEAD SEA SHORE*

A wooden Roman anchor was discovered at the retreating shore of the Dead Sea, north of Ein Gedi. The anchor's wood material was coated by a thick veneer of aragonite and gypsum crusts. The wood was dated by radiocarbon to the early Roman time in the Levant. Lead isotope analyses carried out on the Pb–Fe–Cu anchor material (remains of the anchor's metal parts) yielded ratios that indicate origin of the metal in Italian ores (maybe Tuscan). For the wooden part of the anchor a local tree was used.     

ANTIMONATE OPAQUE GLAZE COLOURS FROM THE FAIENCE MANUFACTURE OF LE BOIS D’ÉPENSE (19TH CENTURY,NORTHEASTERN FRANCE)*

Three types of antimony‐based, opaque ceramic colours were used in the faience workshop of Le Bois d’Épense during the first decades of the 19th century; that is, yellow, tawny and green. Yellow is generated by lead antimonate crystals (Naples Yellow), which are incorporated into an uncoloured glass matrix. According to SEM–EDS measurements, these pigments contain iron. The tawny colour is the optical result of the combined presence of similar yellow, iron‐bearing lead antimonate particles in a Fe‐rich, brownish glass matrix. The green opaque colour is produced by the combination of a blue cobalt glass and yellow Pb–Sn–Fe‐antimonate crystals. Cores of zoned pigments lighten the recipes, according to which the pigments were produced. First, they were synthesized by calcination, ground and then mixed with a colourless, brown or blue glass powder. The resulting powder mixture was added to a liquid agent and used as high‐temperature ceramic colour.     

LEAD ISOTOPIC ANALYSIS OF COPPER ORES FROM THE SIERRA EL ARAMO (ASTURIAS,SPAIN)*

This study presents the first ever lead isotope ratio data for copper ore samples (malachite and azurite) from the Sierra El Aramo (Asturias, northwestern Spain). The aim of this study was to supplement information in the existing reference database on the lead isotopic composition of Spanish ores. The Sierra El Aramo is particularly important because, while no data for the Asturian ores have been published so far, this northern province of Spain has played a significant role in terms of copper exploitation and metallurgy since the Copper Age.     

OXYGEN AND CARBON ISOTOPE ANALYSIS OF HUMAN DENTAL ENAMEL FROM THE CARIBBEAN: IMPLICATIONS FOR INVESTIGATING INDIVIDUAL ORIGINS

This study explores the potential of carbon and oxygen isotope data from human enamel carbonate (n = 50) to contribute to mobility studies in the Caribbean. Most oxygen and carbon isotope results display limited variation, with substantial overlap between islands. However, a few individuals from El Chorro de Maíta, Cuba possess relatively low δ¹⁸O and high δ¹³C. Two of these individuals were previously identified as possible non‐Antillean immigrants on the basis of strontium isotopes, and bioarchaeological and mortuary evidence. The carbon and oxygen isotope results provide additional evidence supporting the proposed non‐local origins of these individuals and contribute to explorations of their potential natal origins.     

The Possibility of Provenancing A Series of Bronze Punic Coins Found At Tharros (Western Sardinia) Using the Literature Lead Isotope Database

A sample set of 42 bronze Punic coins dating from the third century bc and excavated in the Phoenician, Punic and then Roman town of Tharros (western Sardinia) has been used to test the performance of the literature lead isotope database and to establish a well defined provenancing procedure. A selection from the available database, including Cypriot, Sardinian and Spanish ore deposits, has been used. The complete assignment has been carried out twice, using both statistical methods (linear discriminant analysis) and the conventional raw data plots. Three major and one minor disagreements have been found, suggesting that the two procedures, when properly employed, may be acceptably compatible. Almost one third of the coins exhibit a characteristic Cypriot signature, whereas only very few samples are compatible with Sardinian ores. However, the majority of the coins (c. 60%) cannot be associated with any known source, which suggests the possibility of extensive metal recycling.     

TECHNOLOGY AND PROVENANCE OF A COLLECTION OF ISLAMIC COPPER‐BASED OBJECTS AS FOUND BY CHEMICAL AND LEAD ISOTOPE ANALYSIS*

Chemical and lead isotope analyses were utilized to determine the composition, technology and origin of a collection of Islamic copper‐based objects found in Jordan. The atomic absorption spectrometry results show that the objects were made of different types of copper‐base alloys that contain various amounts of zinc, tin and lead. The use of brass, highly leaded brass and quaternary alloys of Cu‐Zn‐Sn‐Pb in the manufacture of everyday, household objects strongly points to Islamic traditions. The lead isotope compositions of the objects match very well that of the copper ore mined from the Dolomite‐Limestone‐Shale unit of the Arabah copper mines.