AN ELEMENTAL AND LEAD‐ISOTOPIC STUDY ON BRONZE HELMETS FROM ROYAL TOMB NO. 1004 IN YIN RUINS

Lead isotope and element composition analyses were performed by thermal ionization mass spectrometry (TIMS) and inductively coupled plasma optical emission spectroscopy (ICP–OES) on bronze helmets from royal tomb No. 1004 at Yin Ruins, the last capital of China's Shang Dynasty (17th to 11th centuries bc ). The data show that the copper‐based alloy helmets can be divided into two categories: tin bronze and leaded tin bronze; and the lead isotope ratios for both categories are in the range of highly radiogenic lead (HRL). This result offers some important clues to answering questions concerning the provenance of raw metal materials, as well as the chronology of this famous royal tomb.     

Monastic diet in Late Antique Egypt: zooarchaeological finds from Kom el-Nana and Tell el-Amarna,Middle Egypt

Abstract

Contemporary literature suggests that meat and fish were not common fare of monastic communities in Egypt during the Late Antique Period (AD 330 to 642). A sizeable assemblage of fishbone from the Monastery at Kom el-Nana has allowed, in conjunction with other zooarchaeological material, a reappraisal of this assumption. In addition, comparative data from the adjacent Pharaonic site at Tell el-Amarna have highlighted distinct cultural differences in the utilisation of the mammal, bird and especially the fish remains between the sites. The difference in size of the catfish Synodontis schall demonstrates that in contrast to the ancient Egyptians the monks were targeting very small fish, most likely for salting in ceramic vessels.     

PANTELLERIAN WARE: A COMPREHENSIVE ARCHAEOMETRIC REVIEW*

Pantellerian ware is a Late Roman cooking ware whose production centre was established on the island of Pantelleria by the pioneering research of Fulford and Peacock almost 20 years ago ( Peacock 1982 ; Fulford and Peacock 1984 ). Archaeological and archaeometric studies carried out by the authors of the present contribution during the past four years have aimed to fully characterize this ceramic class. Recurrent ceramic forms, their distribution over time and space, their petrographic characteristics and their chemical identity, as well as possible raw materials and their technological properties, were considered. The present paper is a comprehensive review of this archaeometric work and aims to establish a ‘reference group’. Using a representative number of samples of Pantellerian ware that were recently discovered in the island through archaeological field surveys or surface and submarine excavations, it was possible to characterize in detail the compositional variability of this ware in terms of chemistry and petrography. Furthermore, the physical properties of this ceramic type have been defined in order to better understand its performance characteristics, mainly in response to induced thermal stress. In the meantime, the experimental mixing and tempering of locally sampled raw materials have shed light on the ancient manufacturing process and have led to an approximation of the original paste.     

NEUTRON ACTIVATION PATTERNING OF ARCHAEOLOGICAL MATERIALS AT THE NATIONAL CENTER FOR SCIENTIFIC RESEARCH ‘DEMOKRITOS’: THE CASE OF BLACK‐ON‐RED NEOLITHIC POTTERY FROM MACEDONIA,GREECE

A short history of the application of NAA in the characterization of archaeological materials at the National Center for Scientific Research ‘Demokritos’, Athens, is presented. NAA was first applied in archaeology in 1974 at the Radioanalytical Laboratory, and since 1989 has been one of the primary analytical techniques of the ‘Demokritos’ archaeometry programme. A case study is also presented, concerning chemical patterning of the black‐on‐red Neolithic pottery class from Macedonia. Four chemical groups were identified, each corresponding to a different area of production. It is shown that this standardized concept of pottery technology and style was spread out within at least eastern Macedonia.     

SCIENTIFIC ANALYSIS OF SEVENTH‐CENTURY GLASS FRAGMENTS FROM THE CRYPTA BALBI IN ROME*

Inductively coupled plasma emission spectroscopy, reflectance spectroscopy and X‐ray diffraction were used to study seventh‐century AD glass fragments from the Crypta Balbi in Rome. All the samples were found to be silica‐soda‐lime glasses. Iron determines the colour of blue‐green, green and yellow‐green transparent glasses; chemical composition suggests deliberate addition of iron and/or manganese in about half the samples. Copper was found as the main colourant in red, pale blue and blue‐green opaque fragments; elemental copper acts as an opacifier in red glass, and calcium antimonate in white, pale blue and blue‐green glasses. Detection of antimony in transparent fragments suggests recycling of opaque mosaic tesserae.     

THE METALLURGY OF THE NAHAL MISHMAR HOARD RECONSIDERED

The Nahal Mishmar hoard, found in a cave in the Judean Desert in 1961, is a key find for the study of Chalcolithic metallurgy in Israel and the Levant. Recent analyses of Chalcolithic metalwork from sites such as Shiqmim in Israel raised doubts about the validity of published analyses from the hoard. Accordingly a programme of re-analysis was established using atomic absorption spectrometry and electron probe microanalysis. The new analyses confirmed the doubts and showed that the metallurgy of Nahal Mishmar was the same as that at the other sites. The alloys used for the cast products in the hoard were generally ternary arsenic-antimony copper alloys with up to 20% alloy content; less common were compositions with arsenic and nickel. The unusual metallography of these alloys is described. Some suggestions are offered as to the mode of manufacture of the alloys.     

PREHISTORIC ANTIGORITE PROCUREMENT IN CYPRUS

The Canadian Palaipaphos Survey Project in the Paphos district of south-western Cyprus investigated extensive areas of the Esouzas, Xero, and Dhiarizos River valleys, locating hundreds of archaeological sites spanning the nine millennia from the aceramic Neolithic period to the recent era (Rupp et al. s1984 and 1986). Antigorite artefacts were recovered from Neolithic, Chalcolithic and Bronze Age settlements. A number of geological sources have been proposed for the material from which these artefacts were manufactured. The results of neutron activation analyses of archaeological and geological specimens suggest that the Troodos ophiolite/Kouris River secondary deposits were the primary source of antigorite for the prehistoric populations of the study area. Extreme care must be taken when analysing antigorite samples to avoid material with grey-black magnetite-rich inclusions. since these have radically different trace element chemistries from the pure antigorite.     

RAMESSIDE GLASS-COLOURING CRUCIBLES*

The preparation of glass in New Kingdom Egypt heavily involved the use of crucibles. Shape, mode of operation and function of these vessels have been reconstructed on the basis of new, stratified material from the excavation at Qantir, eastern Nile Delta. The crucible fabric, the internal layer protecting the vessel from the charge, and the glass melted in the crucibles are characterized by chemical and petrographic studies. The crucibles were apparently employed mainly to add the colourants to the glass. The broader archaeological context strongly suggests that glass production in the Late Bronze Age has been a highly developed, specialized and organized craft, with different factories for glass production, for colouring, and for working, connected by a wide-ranging trade network.     

METHODS OF ENGRAVING MESOPOTAMIAN CYLINDER SEALS: EXPERIMENTAL CONFIRMATION*

Previous observations of the intaglios on quartz cylinder seals from Western Asia suggested that they had been engraved by one or more of four basic techniques, that is, micro-chipping, filing, drilling and wheel-cutting. In this paper we test our earlier observations and interpretations experimentally. Examination and comparison of experimentally engraved features with the seal intaglios was made directly with a binocular microscope and also by examination of impressions with a scanning electron microscope. Successful replication was achieved using tools of flint, chalcedony, copper, bronze and iron together with quartz and emery abrasives.     

STEATITE SOURCE CHARACTERIZATION IN EASTERN NORTH AMERICA: NEW RESULTS USING INSTRUMENTAL NEUTRON ACTIVATION ANALYSIS*

Doubts have recently been cast on the ability to characterize steatite sources using rare earth elements (REEs). By increasing the number of samples and elements examined using instrumental neutron activation analysis (INAA) and multivariate statistics, this study shows that, with unhomogenized samples, transition metals, not REEs, make the greatest contribution in characterizing steatite sources in the Middle Atlantic region of eastern North America. Preliminary results suggest that INAA has the potential to assign provenance to steatite artefacts, at least at a regional level.