Traces of Fatty Acids from a Byzantine Sounding Lead Recovered off the Israeli Coast

Fatty acids, typical to large herbivores, were isolated from a 7th century Byzantine sounding lead recovered from a shipwreck off Dor, an ancient anchorage in Northern Israel. The fatty acids survived by being sheltered in an anaerobic environment provided through a site formation process induced by the disintegrating wreck. Previously established identification criteria for fatty acids, absorbed in ceramics, were used to show that tallow was used in this navigational instrument in the Eastern Mediterranean during late antiquity.     

IDENTIFICATION OF ANCIENT LACQUER FILM USING TWO-STAGE PYROLYSIS-GAS CHROMATOGRAPHY/MASS SPECTROMETRY*

Oriental lacquer has been used as a surface coating for wood, porcelain and metal, and three different types are known: Japanese (or Chinese) lacquer (urushiol-based), Vietnamese lacquer (laccol-based) and Burmese lacquer (thitsiol-based). Identification of these types in ancient coatings is very important in conservation and restoration studies. A two-stage pyrolysis-gas chromatography/mass spectrometry method is effective for the analysis of lacquer films. This is shown here using an ancient lacquer film sample from medieval material excavated at Tobarikyu (Japan), The sample was identified, by comparison with linseed oil and authentic lacquer films, as an urushiol-based Rhus vernicifera (Japanese) lacquer which includes an added oil component.     

X‐RAY SUB‐MICRON TOMOGRAPHY AS A TOOL FOR THE STUDY OF ARCHAEOLOGICAL WOOD PRESERVED THROUGH THE CORROSION OF METAL OBJECTS

Wood preserved in the corrosion layer of two early medieval iron objects was examined using X‐ray tomography. A state‐of‐the art multi‐resolution X‐ray tomography set‐up ( http://www.ugct.ugent.be ) provided virtual cross‐sections of the archaeological wood samples at sub‐micron resolution. These were compared with scans of samples of similar modern wood. These scans demonstrate the power of sub‐micron X‐ray tomography for wood identification, although the process of mineralization pushes this technique to its limits. Furthermore, this technique facilitated appraisal of the mineral content of the archaeological wood, which is useful in selecting the most appropriate strategy for the (preventative) conservation of the archaeological object.     

THE TRAVERSETTE (ITALIA) ROCKFALL: GEOMORPHOLOGICAL INDICATOR OF THE HANNIBALIC INVASION ROUTE*

Numerous small, low volume rockfalls around the crest of the Italian and French Alps, principally formed from calcareous mica schist and metabasalt, have impeded travel across the major cols for millennia. As documented by Polybius and Livy in the ancient literature, Hannibal's Army was blocked by a two-tier rockfall on the lee side of the Alps, a rubble sheet of considerable volume that delayed his exit into the upper Po River Country. An in-depth study of the possible cols reveals that the only such two-tier landform lies below the Col de la Traversette, at ∼2600 m above sea level. In addition, it represents a problem in applied geomorphology, namely, to accurately determine the nature of the surface rubble sheet in Hannibal's time (218 bc ). A reconstruction of the initial deposit, likely Late Glacial, following the retreat of the Po Glacier, is based upon an analysis of the source rock and geological setting. Further specifications on the geometry of the Neoglacial cover sediment are based on weathering characteristics, lichen cover and soil development. The 'myth' that Hannibal fired the rockfall to comminute boulders is plausible given the vegetation records which support tree growth nearby, but is unsubstantiated by the lack of any carbonized rock.     

BLOOD AS A BINDING MEDIUM IN A CHUMASH INDIAN PIGMENT CAKE

As part of a study of Chumash Indian pigments, some black pigment cakes have been examined. One pigment cake was characterized as soot by polarized light microscopy, and Fourier transform infrared microscopy showed that the binder was proteinaceous. Protein determination was followed by examination using gas chromatography-mass spectrometry analysis which showed a characteristic suite of amino acids to be present, proportionally similar to blood. The blood identification was confirmed by immunological analysis. The binder was shown to be a mixture of human and animal blood, the animal being pronghorn antelope. This is the first successful identification of a binding medium from a Chumash Indian pigment cake.