Evidence of early medieval soda ash glass in the archaeological site of San Genesio (Tuscany)

The early medieval period marks an important turning point in the history of glassmaking, since it comprises the transition period between the mineral-based silica-soda-lime glass of the Roman tradition and the plant ash-based glass. With the aim of expanding the knowledge on the glass recipes and technologies of this period, 37 glass samples were analyzed, originating from the archaeological excavations of San Genesio (Tuscany) and dated from the fourth to the eleventh century. The major and minor element concentrations were measured with SEM-EDX, while the trace elements were quantified with LA-ICP-MS. The results were compared with published compositions of glass samples of similar age in order to highlight differences and similarities. The results offer a very interesting view on the glass circulation in the religious/residential/manufacturing center of San Genesio in the early medieval period. Most of the glass has a typical late-Roman composition, but some glass fragments are identified as soda ash glass. These are among the earliest medieval ash-fluxed glasses ever found in the Italian peninsula.     

Obsidian hydration dating by infrared spectroscopy: method and calibration

Low temperature (90–190 °C) hydrothermal experiments have been conducted on seven obsidians where composition of the glass varies significantly in the concentration of structural water within the unhydrated bulk material. Infrared transmission spectroscopy was used to track the diffusion of molecular water into the glass surface as a function of time and temperature. Long-term (60–360 days) hydration sequences at 90 °C show a t^0.6 time dependence for the mass uptake of molecular water that forms the hydration layer. The structural water concentration of the unhydrated bulk obsidian is highly correlated with the pre-exponential and activation energy and may be used to estimate the Arrhenius constants. In addition, secondary ion mass spectrometry (SIMS) hydrogen profiling of Napa Glass Mountain obsidian hydrated at 90 °C reveals that the early stages of diffusion exhibit a dynamic behavior that includes a fluctuating hydrogen concentration and a changing diffusion coefficient that slows with time.     

北周武帝孝陵出土玻璃珠的科学分析与研究

1993年8月,位于咸阳市底张镇陈马村东南约1000米处的一座古墓葬被盗掘,其后陕西省考古研究所于1994～1995年进行了发掘,根据出土的墓志石、印章以及墓室中发现的两套棺     

Investigations of Byzantine glass bracelets from Nufăru,Romania using external PIXE–PIGE methods

The chemical composition of twenty glass bracelet fragments found in Nuf?ru, a Byzantine site from 10th–13th centuries A.D., nowadays located on Romania's territory, has been determined using Particle Induced X-ray Emission (PIXE) and Particle Induced Gamma-ray Emission (PIGE) in external beam mode. Most of the Byzantine bracelet fragments were identified as “mixed natron-plant ash” soda-lime-silica glasses. The obtained chemical compositions indicated that the manufacturing of these finery items was performed using similar raw materials and techniques, in most of the cases involving colored glass recycling. PIXE–PIGE results highlighted the glass chromophores (cobalt, manganese, copper and iron ions) and provided hints about the mineral pigments used to paint the external surface of some bracelets.     

声频应力波法检测土遗址加固用玻璃纤维锚杆锚固质量初探

土遗址锚杆锚固质量一直是土遗址加固工程中关注的重点问题。目前,土遗址领域均采用具有破坏性的拉拔试验对其进行检测。基于土遗址的文物属性,本研究尝试利用无损检测技术评价土遗址加固用玻璃纤维锚杆的锚固质量。通过锚杆无损检测仪与拉拔仪分别对甘肃省红沙堡遗址与永泰城址加固工程中的玻璃纤维锚杆锚固系统进行检测。比较实际测量杆长与仪器测量杆长结果,得出杆长指标可以判断无损检测仪所测结果的真实性。无损检测仪得出的检测波形衰减规律显著,对比相应锚杆的拉拔试验的评价结果,证实了声频应力波法在土遗址玻璃纤维锚杆锚固系统无损检测中的适用性。本研究结果将为评价土遗址加固用玻璃纤维锚杆锚固质量提供可靠的依据。     

青海大通县出土汉代玻璃的研究

本文共对12件玻璃样品进行化学组成分析.其中,部分样品还进行了密度测定,X 射线衍射分析和显微镜观察.此外,还对一颗黄色玻璃珠的表面层进行 SEM-EDX 分析.结果表明,该玻璃珠表面有金箔涂层.根据分析结果,青海大通县出土玻璃的基础成分可归为三类,即铅钡玻璃(Na_2O-PbO-BaO-SiO_2系统玻璃),钠钙玻璃和钾硅玻璃(K_2O-SiO_2系统)。此外,还对玻璃的来源进行了探讨.     

北齐韩祖念墓出土玻璃杯考--兼论魏晋南北朝时期波斯玻璃器之东传

1982年太原北齐韩祖念墓出土了一件玻璃高足杯,我们用X射线荧光光谱对其进行了无损分析。检测结果表明:这件玻璃杯是典型的萨珊草木灰类型玻璃。结合器形、纹饰和文献记载,推测其应为波斯萨珊使者向北齐进献的贡品,为萨珊玻璃沿丝绸之路传播提供了新的证据。本文还对魏晋南北朝外来玻璃检测结果进行了总结,并系统划分了这一时期舶来玻璃的类型及其在中国分布的地域和时代特征。     

新疆宋元时期也木勒遗址出土玻璃的工艺与成分研究

也木勒遗址位于新疆维吾尔自治区塔城地区额敏县,是北方丝绸之路上的重镇,考古发掘确定其为宋元时期的大型遗址。为探讨该遗址出土玻璃的成型工艺和来源,本研究以该遗址中的9个玻璃碎片作为对象,通过观察成型工艺,并利用激光剥蚀电感耦合等离子体原子发射光谱(LA-ICP-AES)技术分析样品的化学成分。结果显示,这批素面透明的玻璃片为无模吹制而成的日常实用器皿,成分上属于钠钙玻璃体系,Na_2O含量低,K_2O含量较高,并含有P_2O_5,助熔剂可能是含有草木灰的混合碱,成分特征与同时期葱岭以西中亚地区、新疆地区生产的玻璃器相似。结合新疆同时期玻璃器发现,多是装饰简洁,出土地点等级一般的普通实用性器皿,说明玻璃器已进入平民的日常生活之中,反映出新疆地方民族政权较中原地区先融合了中西亚将玻璃器作为日常生活用具的文化,形成了与中原玻璃器功用的差异之处。研究结果为丰富国内宋元时期新疆玻璃器的研究资料,揭示新疆地区玻璃器的使用面貌,探讨宋元时期少数民族地方政权的文化交流提供重要信息。     

Variable Selection in Artefact Compositional Studies

In artefact compositional studies, the selection of variables to use in analysis is unavoidable. Given this ubiquity, surprisingly little attention has been paid to ways in which variables might be selected. After arguing the case for the importance of variable selection, two systematic approaches to making a choice, which have had little or no application in archaeometry, are discussed and illustrated. One, based on the use of principal components, is appropriate if structure in the data is not known. The other, based on the use of classification trees, is applicable when there are known or assumed groups in the data.     

LA-ICP-MS analysis of Late Bronze Age blue glass beads from Gurob,Egypt

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis was undertaken on 37 blue glass beads excavated from a tomb in the southern Faiyum region of northern Egypt. The tomb was undisturbed, contained the remains of seven females and two children, and dated between the reigns of Amenhotep I (1525–1504 bce ) and Tuthmosis III (1479–1425 bce ). The glass beads were coloured by copper and the trace element concentrations were compositionally consistent with glasses from Mesopotamia rather than from Egypt. Therefore, these glass beads represent a rare example of Mesopotamian glass to be discovered in Egypt, in addition to being some of the earliest glass found. Gurob is known to have been the site of a ‘harem palace' established in the reign of Tuthmosis III, the implication being that these beads represent luxury items transported to Egypt by high-ranking foreign women, possibly in connection with the harem palace.