ARCHAEOLOGICAL AMBERS FROM NORTHERN ITALY: AN FTIR–DRIFT STUDY OF PROVENANCE BY COMPARISON WITH THE GEOLOGICAL AMBER DATABASE*

European geological ambers of five different localities and types, and Italian geological ambers from seven different deposits have been studied with Fourier transform infrared spectroscopy (FTIR) and diffuse‐reflectance infrared Fourier transform (DRIFT). Ambers from several localities have been characterized for the first time. The research aims to create a database of European ambers, containing both FTIR and DRIFT data. The FTIR spectra are easily comparable with the data commonly available in the literature, whereas DRIFT analyses are shown to be more useful to characterize the archaeological finds. The provenance of several archaeological ambers from northern and southern Italy, dating from the Middle Bronze Age to the Iron Age, is assessed on the basis of the developed database. Of the 35 analysed archaeological objects, all but five are composed of Baltic succinite amber.     

A microarchaeological approach for the study of pits

Abstract

The study of the technology underlying pre-industrial storage structures has an interest from an anthropological and archaeological perspective, in terms of the evolution of key cultural and cognitive capabilities, often related to the transition to food production.

Microarchaeological techniques offer a unique perspective on the study of pre-industrial storing technologies. In this work, examples are presented from two archaeological contexts in different climatic and socio-ecological situations during the Holocene in S Asia and SW Europe. Microarchaeological techniques used in this study include micromorphology, Fourier transform infrared spectroscopy and phytolith analyses. The comparative study of two pits highlights key aspects of the decision-making process involved in technological solutions of storage: ? The choice of a location for the construction of a given storage facility is highly affected by contextual climatic, microclimatic, soil and bioturbative factors

? The time taken to consume stored foodstuffs seems to affect technological investment as much as the intrinsic conservation requirements of the stored taxa

? The use of fire to hygienise pits implies that such structures were not conceived for single use

? Pre-industrial storage systems can be seen as modular structures, which components (e.g. topographical location, sediment type, lining type, hygienisation techniques and cover) can be recombined to improve storage performance for different climatic settings and foodstuffs.

     

Mineralogical and Chemical Characterization of Roman Slag from the Archaeological Site of Castra (Ajdovščina,Slovenia)

This study deals with the mineralogical and chemical characterization of archaeometallurgical material from the Roman archaeological site of Castra (Ajdov??ina, western Slovenia). Samples were initially analysed via optical microscopy and X‐ray powder diffraction, with the composition of individual phases then determined using scanning electron microscopy coupled with electron‐dispersive spectroscopy, and Raman microspectroscopy. Chemical investigation was carried out by using inductively coupled plasma atomic emission spectroscopy to measure the major element content. The results showed that the slag originated from iron smithing operations, with calcium‐rich olivines, as well as wuestite and leucite, the most abundant phases. The investigated slags were also found to be characterized by significantly high lime levels, which probably promoted the formation of the calcium‐rich olivines.     

Compositional characterization of Etruscan earthen architecture and ceramic production

This study presents the results of new research into Etruscan technology for earthen architecture as well as ceramic production in the upper Tiber Valley in central Italy, using as a case study the Etruscan settlement of Col di Marzo (Perugia). It determines the compositional differences of the raw material employed as building material and for ceramic production by X-ray powder diffraction (XRD), thermogravimetric analysis and differential thermal analysis (TG-DTG), Fourier-transform infrared analysis (FTIR) and geotechnical analyses. The research also advances the knowledge of ceramic manufacturing technology, with a focus on impasto production, at Col di Marzo between the fifth and mid-third centuries bce and the surrounding territory on the left bank of the River Tiber. The compositional analysis of building material compared with the ceramics provides answers to questions related to their sourcing and deepens the understanding of the exploitation of natural resources .     

The rarest blue: An exceptional find of lapis lazuli in the polychromy of a funerary portrait from ancient Palmyra

The current interdisciplinary study of a funerary portrait has provided the first identification of a blue pigment on Palmyrene sculpture. The exceptional attestation of lapis lazuli on the examined portrait confirms the use of this highly valuable semiprecious stone in ancient polychromy, which was previously thought to be a later addition to the painter's palette. Considering that the archaeological record contains numerous minor objects carved from lapis lazuli, there are astonishingly few known instances of its use as a pigment. This Palmyrene discovery is only the third known example from Antiquity.     

南唐二陵壁画历史保护修复材料的分析

为了确定南唐二陵壁画已有保护修复材料的种类,使用多光谱摄影技术分别对钦陵和顺陵壁画保护修复材料的分布区域进行探查,在紫外荧光图像中确定了保护修复材料的位置,通过红外光谱和热裂解-气质联用技术对材料进行了成分分析。结果表明二陵壁画所使用的保护修复材料主要为苯乙烯-甲基丙烯酸甲酯共聚物和聚醋酸乙烯酯,还发现少量多糖类物质,为调和地仗石灰层所使用的糯米汁。该研究表明通过多光谱摄影技术提供线索,使用红外光谱、热裂解-气质联用确定成分是一种可靠的墓葬壁画保护修复材料分析方法体系,为墓葬壁画保护修复材料的鉴别提供借鉴,也为保护修复材料在墓葬壁画中的应用效果评价和劣化机理研究提供参考。     

Variscite source and source analysis: testing assumptions at Pico Centeno (Encinasola,Spain)

The analysis of trade and their implications for understanding social interaction is a major research question of prehistoric research in Europe. Variscite is a rare mineral that offers an excellent opportunity to study trade and exchange patterns in prehistoric Europe through proveniencing of source material.     

Examination of some pigments,grounds and media from Egyptian cartonnage fragments in the Petrie Museum,University College London

A number of cartonnage fragments from the collections of the Petrie Museum, UCL, were examined to identify pigments, media and grounds. The different types of cartonnage made in ancient Egypt are reviewed. Special attention was paid to green pigments, which were shown to be of green earth, or a mixture of Egyptian blue and a yellow, usually goethite or orpiment. Green earth was found in one artefact, dated to the 9th century BC: all other examples were from the Graeco-Roman period. No copper-organometallic greens were present in the examples studied, or Egyptian green, or malachite. Binding media was identified both by ELISA and by GC/MS. A pink colourant was identified as madder, while lead white was used as a white in one example, showing the influence of Roman and Greek pigments on Egyptian art in these later periods. Plant gum, egg, and animal glue were found in different fragments, with mixed media in a few cases. Moganite was found associated with quartz in some preparatory layers by X-ray diffraction, which has not been reported previously as a constituent of ground layers in Egyptian artefacts.     

An Etruscan ointment from Chiusi (Tuscany,Italy): its chemical characterization

This paper focuses on the chemical characterization of the original contents of an Egyptian origin alabaster unguentarium, found in an Etruscan burial in Chiusi (Tuscany, Italy) and dated 150/125–100 B.C. The unguentarium, found in an intact tomb belonging to a noble woman of Chiusine society, preserved a good part of its original contents owing to a protective layer of clay. The chemical characterization was carried out using a combination of two analytical procedures based, respectively, on Fourier transform infrared spectroscopy (FTIR) and gas chromatography–mass spectrometry (GC–MS).     

Microarchaeology of a collective burial: cova des Pas (Minorca)

FTIR and phytolith analyses have been used to understand the exceptional preservation of the organic remains at the burial cave of Cova des Pas (Minorca), and to obtain high-resolution data of the plant remains present in the sediments. The presence of sodium nitrate and gypsum suggests a relatively dry environment that has enabled the preservation of the organic material, and contributed to the natural mummification. The dry conditions also favored phytolith preservation. Grass inflorescence phytoliths are abundant all over the site suggesting that phytolith accumulations might have an anthropogenic origin and are related to the burial ritual.