Geoarchaeological investigations at Diepkloof Rock Shelter,Western Cape,South Africa

The sedimentary sequence at Diepkloof Rock Shelter formed through a complex interaction of depositional and post-depositional processes and was variously influenced by biogenic, geogenic, and anthropogenic agents. Here, we present the results of a micromorphological study of the sediments at Diepkloof, focusing in particular on the numerous anthropogenic inputs and modifications recorded within the sequence. By applying the microfacies concept, we were able to identify hearth burning and maintenance, bedding construction and burning, and surface modification by trampling as major processes that contributed to the formation of the site. The human activities recorded within the sediments show a marked change throughout the sequence, implying a shift in the use of the site over time. The present study also provides a context for evaluating other classes of artifacts and data collected from the site.     

Characterization of prehispanic cosmetics found in a burial of the ancient city of Teotihuacan (Mexico)

The present paper reports the chemical data obtained on samples of pigmenting materials contained in 31 miniature vessels found in a burial found in Teopancazco, a multiethnic neighborhood center located in the southeastern sector of the archaeological site of Teotihuacan (Central Mexico) and the analytical protocol established for the complete characterization of these archaeological materials. For this purpose a multi-technique approach based on the combination of several non destructive and micro-destructive instrumental techniques, namely, light microscopy (LM), scanning electron microscopy-X-ray microanalysis (SEM-EDX), transmission electron microscopy (TEM), voltammetry of microparticles (VMP), X-ray microdiffraction (μXRD), X-ray diffraction (XRD), UV-Vis spectrophotometry, FTIR spectroscopy and gas chromatography-mass spectrometry (GC-MS) has been developed in an attempt to completely characterize these materials. These instrumental techniques provide reliable and complementary data including elemental and mineralogical composition, identification of functional groups as well as speciation studies of electroactive species. Among the most relevant findings, volcanic pyroclastic rocks and clayey soils, most probably, from the Teotihuacan valley as well as galena, jarosite and mica from other provenances in Mesoamerica, have been identified. Charcoal and Ocote resin have also been identified. The chemical composition of the samples is discussed with a view to the possible function as cosmetic materials and their use in funerary rites. The results have been critically compared with those others obtained in other ancient civilizations. The study carried out on the materials found in the burial 105 is especially relevant insofar it represents the first evidence, scientifically characterized, of the use of cosmetics in Mesoamerica at this early period (AD 200-550).     

居延遗址T129烽燧出土纺织品分析

居延遗址与汉代丝绸之路兴盛密切相关,是历代丝绸之路开拓与畅通的重要历史见证。在人迹罕至的居延遗址T129烽燧附近的地面发现了纺织品残片,伴随发现的有汉代木简和五铢钱。为了了解织物成分和编织工艺,进行了相关的科学分析。使用红外光谱分析确定了纺织材料为丝,通过视频显微镜和扫描电镜观察,确定纺织品采用平纹织法,未经染色,根据织做工艺可定名为汉代常见的绡。该纺织品可作为汉代戍边士卒衣装的标本之一,对于研究汉代西北地区的丝绸之路物质交流和文化传播具有一定的意义。     

Infrared and Isotopic Evidence for Diagenesis of Bone Apatite at Dos Pilas, Guatemala: Palaeodietary Implications

The use of stable carbon isotopic analysis of bone apatite to reconstruct prehistoric diets is hindered by the possibility of diagenetic alteration of carbonate during burial. We examine apatite preservation in Classic Period Maya skeletal remains from Dos Pilas, Guatemala, using Fourier transform infrared spectroscopy (FTIR). We use weight % CO₂evolved from apatite, FTIR carbonate/phosphate absorbance ratios, phosphate peak splitting crystallinity indices, fluoride peaks, and stable oxygen isotopic ratios to identify diagenetic change in apatite chemistry. Isotopically light carbon taken up from burial soil is adequately removed from most Dos Pilas bone by treatment with dilute acetic acid, but more severe alteration cannot be reversed by standard preparation methods. Infrared criteria identify recrystallized apatite in a subset of Dos Pilas burials, that is accompanied by isotopic exchange, and that no longer preserves biogenic δ¹³C. These results illustrate that comparatively recent bone may be diagenetically altered and demonstrate a need for systematic evaluation of mineral integrity in all archaeological bone prior to interpreting paleodiets with apatite δ¹³C.     

New data on relevant ancient Egyptian wooden artifacts: Identification of wooden species and study of the state of conservation with multidisciplinary analyses

Wood species identification and characterization of its weathering processes are crucial steps in the scientific approach of conservation of wooden cultural heritage. Many precious wooden objects of ancient Egypt are largely present in museums, nevertheless relatively little information is available concerning the nature of timber used and on their status of conservation. To address this gap, the wooden species of three relevant archaeological wood objects (statue, box, and coffin) arising from different Egyptian archaeological sites dated from the Old Kingdom (2,686–2,181 BC) to New Kingdom (1,550–1,069 BC) were deeply studied. Five hardwood and softwood species were identified belonging to Tamarix mannifera, T. gennessarensis, Ficus sycomorus, Vachellia nilotica, and Cedrus sp. Such data confirmed the recurrence of Vachellia and Tamarix among the most common timbers found in ancient Egypt. Scanning electron microscope, Fourier transform spectroscopy, and synchrotron x-ray radiation diffraction were conducted to evaluate the archaeological wood deterioration. The formation of microcracks, biological degradation patterns (fungal colonization), or chemical characterization (accumulation of salts on and in-between wooden cells) were detected. SEM micrographs showed the presence of fungal hyphae and conidial spores on the wooden cells. Significant changes in the chemical wood composition and decrease in the crystallinity index were detected.     

The manufacturing process of 3rd millennium BC bone based incrusted pottery decoration from the Middle Guadiana river basin (Badajoz,Spain)

The aim of this study is to present the manufacturing process developed on 3rd millennium BC white incrusted pottery from the middle Guadiana River basin (Badajoz, Spain), alongside the analytical procedure developed to determine the nature of these incrustations. The analytical procedure developed in this paper will assess the nature of these incrustations as burnt bone and in fewer cases as calcium carbonate, turning upside down the usual tendency for the Iberian Peninsula, where calcium carbonate has been the only kind of incrustation identified up until now. The analytical facilities used are: SEM-EDX, XRF microprobe, XRD and FTIR. The assessment of the nature of the incrustations as burnt bone has been a hazardous task and it has been necessary to develop a procedure using several analytical techniques and reference materials.     

THE CHARACTERIZATION OF PAINTS AND WATERPROOFING MATERIALS FROM THE SHIPWRECKS FOUND AT THE ARCHAEOLOGICAL SITE OF THE ETRUSCAN AND ROMAN HARBOUR OF PISA (ITALY)*

This work presents the results of a diagnostic survey on the shipwrecks from the archaeological site of the ancient harbour of San Rossore (Pisa, Italy). The original waterproofing, caulking and painting materials were characterized by Fourier transform infrared spectroscopy (FTIR), gas chromatography – mass spectrometry (GC–MS), energy‐dispersive X‐ray microanalysis (EDX) and X‐ray diffraction (XRD). The major constituents of the waterproofing and caulking materials detected on the planks were tricyclic abietanes showing a high degree of aromatization. These compounds are indicative of a pitch obtained from the wood of trees of the Pinaceae family. The analysis of the organic components of the paint samples revealed diterpenoid acids characteristic of Pinaceae resins together with linear long‐chain alcohols and fatty acids, highlighting the presence of beeswax. Noticeably, the characteristic odd carbon number alkanes that are normally present in beeswax were not detected. The EDX and XRD analyses showed that hematite, calcite, cerussite and kaolinite were employed as pigments to paint the ships’ hulls.     

An integrated approach to reconstructing primary activities from pit deposits: iron smithing and other activities at Tel Dor under Neo-Assyrian domination

Secondary pit deposits in historical occupations of Near Eastern mounds are usually regarded as uninteresting and are seldom analyzed. We used an integrated approach to study all the artifacts as well as the sediments in a pit at Tel Dor, on Israel's Carmel coast, dating to the 7th c. BCE – a period when the site served as an Assyrian administrative center. This pit was unusually large, had a peculiar ceramic assemblage, and many macroscopic metallurgical wastes. A detailed excavation and analysis revealed that the pit served intermittently as a waste disposal site for an iron smithy and for pottery that was presumably involved in maritime trading. On two occasions the area was also used for animal penning. Despite the obvious importance of the iron industry to the Neo-Assyrian Empire, actual workshops are rare in its archaeological record. Hence the new information regarding an Iron Age iron smithy in the southern Levant contributes to the study of this industry, and also to the history of Dor in this period.     

FIELD AND LABORATORY MULTI‐TECHNIQUE ANALYSIS OF PIGMENTS AND ORGANIC PAINTING MEDIA FROM AN EGYPTIAN COFFIN (26TH DYNASTY)

This paper describes the physico‐chemical analyses performed on an Egyptian wood coffin on the occasion of its restoration in the hall of the National Archaeological Museum of Parma (Italy), with the aim of investigating the pigments and organic materials originally used. Pigment determination was performed both in situ by a portable energy‐dispersive X‐ray fluorescence (EDXRF) spectrometer and in the laboratory using a micro‐Fourier‐transform‐infrared (micro‐FTIR) and a Fourier‐transform (FT) Raman spectrometer. The identification of organic materials was performed through gas chromatography – mass spectrometry (GC–MS) and micro‐FTIR analysis. Amongst the pigments, special attention was paid to the green, which appeared to be severely degraded and was examined using powder X‐ray diffraction (XRD) and scanning electron microscopy – energy‐dispersive X‐ray (SEM–EDX) in addition to the above‐cited techniques. Other materials used in the polychromatic decorations are Egyptian blue, cinnabar and possibly orpiment, while calcium carbonate was used for the ground layer. The organic materials were identified as beeswax, mastic and gum arabic, sometimes as mixtures.     

TEMPLAR JOINT REPOINTINGS: MATERIALS,TECHNIQUES AND PAINT DECORATION IN MIRAVET CASTLE,SPAIN

The medieval repointings, with incised and painted decoration, observed on the walls of Miravet Castle, Spain, which was built during the 12th century by the Knights Templar, are described, analysed and characterized by X‐ray powder diffraction, SEM–EDS and FTIR. The results demonstrate that the painted decoration preserved on the inner walls of the dining room is original and contemporary with the outer joint repointings. This feature is of great interest as, in this particular case, repointing not only comprised a structural necessity in order to render the wall impermeable to run‐off water, but also played a decorative role.