天然氧化铜矿与铜制品腐蚀产物区别的探讨

在一些新石器时代的遗址中经常会出现一些铜渣、小块孔雀石等与炼铜有关的遗物。为探究这些孔雀石到底是天然的氧化铜矿还是铜制品的腐蚀产物,本工作对天然氧化铜矿和青铜器腐蚀产物进行岩相分析和元素成分分析。结果表明,天然氧化铜矿大都具有一些特殊的结构构造,而在铜制品的腐蚀产物中却很难发现这些结构构造;同时,二者在元素成分上也有显著不同,Bi、Sb、As、Fe、Mo、Co、Mn等微量元素可以作为区分天然氧化铜矿和青铜器腐蚀产物的一个判别标志。结合岩相分析和成分分析,可以确定一个遗址出土的孔雀石或蓝铜矿是天然氧化铜矿还是铜制品的腐蚀产物;同时,可进一步判断是红铜的腐蚀产物还是青铜的。这一结论对探讨铜冶金的起源有重要意义。     

青铜器锈蚀结构组成及形态的比较研究

采用X射线衍射(XRD)、扫描电镜(SEM)、X射线电子能谱(EDS)和金相显微镜(OM)等方法,分析比较了染有“粉状锈”与未染“粉状锈”的典型青铜残片的锈蚀产物的矿物组成、腐蚀层分层结构及金相组织。结果发现,未染有“粉状锈”的青铜样品腐蚀层一般分为二层,外层是二价铜化合物,合金组织中未见α (α δ)组织,锈蚀产物中不含碱式氯化铜;而染有“粉状锈”的青铜样品都含有碱式氯化铜,其断面腐蚀层分三至四层,且每层锈体的结构和元素组成各不相同,在靠近合金基体层的锈层中发现了大量的CuCl存在。结果表明,青铜文物表面锈蚀覆盖层的致密性、空气中的湿度及锈层中CuCl层状分布的存在,是青铜器表面“粉状锈”形成和发展的根本原因。     

应用电位活化理论研究青铜器的腐蚀与保护

应用电位活化理论分析和阐述了青铜器腐蚀的观点和防护理念。对青铜器腐蚀的全过程提出了致密膜保护期、保护膜破坏局部腐蚀期和小孔腐蚀粉状锈加速期三个阶段的看法。用高效钝化保护剂对处于不同腐蚀阶段的青铜器保护膜进行修复和改性 ,结果表明 ,理论腐蚀电阻RC 从 10 5Ω提高到 10 7Ω ,并具有可间断涂覆、可回复的特点 ,可应用于青铜文物的保护试验。     

Investigating archaeological site formation processes on the battleship USS Arizona using finite element analysis

Scientists from the National Institute of Standards and Technology (NIST) worked in a collaborative partnership with archaeologists from the National Park Service's (NPS) Submerged Resources Center (SRC) to develop a finite element model (FEM) of the battleship USS Arizona. An FEM is a computer-based engineering model that calculates theoretical stresses, propagation of force, and shape changes to a structure under loads using thousands or even millions of individual elements whose individual responses are well understood. NIST researchers created an FEM of an 80 ft. (25 m) midships section of the Arizona site to analyze archaeological site formation processes on the sunken battleship, in particular to determine the current condition of the wreck and predict its future strength and structural integrity as it continues to corrode. The NIST's FEM study is one aspect of a larger project under the direction of the NPS, the USS Arizona Preservation Project, whose goal is to determine the nature and rate of corrosion affecting USS Arizona, and to model its long-term structural deterioration. The FEM incorporates findings from other key components of the USS Arizona Preservation Project, such as steel hull corrosion rates, structural surveys of the vessel, sediment compaction studies, and analysis of the concretion that covers the ship's hull, into a single tool that is being used to predict how the wreck will degrade in the future.     

Numerical Investigation of Residual Strength and Energy Dissipation Capacities of Corroded Bridge Members Under Earthquake Loading

Recent damage examples of aged steel bridge infrastructures around the world are so alarming. They intensified the importance of careful evaluation of existing structures for the feasibility of current usage and to ensure public safety. Corrosion and fatigue cracking may be the two most important types of damages in aging structures. Furthermore, recent earthquakes demonstrated potential seismic vulnerability of some types of steel bridges. Corrosion and its effects can trigger the damages caused by earthquakes, and it will be vital to understand the behavior of existing steel bridges which are corroding for decades in future severe seismic events as well. This article comprises the results of nonlinear FEM analysis of many actual corroded plates with different corrosion conditions and proposes a simple and reliable methodology to estimate remaining seismic strength and energy dissipation capacities by measuring only the minimum thickness of a corroded surface, which can be used to make rational decisions about the maintenance management plan of steel infrastructures.     

X射线显微CT成像技术在金属文物制作工艺研究与腐蚀状态评估中的应用

金属腐蚀过程不仅受环境等外部因素的影响,制作工艺、合金组成及缺陷等内部因素同样起着重要作用。为实现金属文物制作工艺和内部腐蚀状态的可视化研究,运用X射线显微CT对铜镜文物碎片以及出土、海洋出水铁质文物样品进行扫描探测,并结合X射线荧光、X射线衍射等检测手段,开展金属文物材质、工艺及矿化程度的综合分析。结果表明,在显微CT影像重建基础上,通过设定不同的阈值,可实现文物内部缺陷、腐蚀矿化程度等内部信息的测量统计。该方法可为金属文物材质、制作工艺研究和腐蚀状态评估提供无损的研究手段。     

Seismic Behaviors of RC Frame Beam-Column Joints under Acid Rain Circle: A Pilot Experimental Study

This research was carried out to investigate the seismic performance of RC beam-column joints under acid rain circle via comparison of energy dissipation behavior and failure mechanism of joints with different corrosion levels and axial compression ratio. At the initial corrosion level, the strength, ductility, and energy consumption of RC beam-column joints improved slightly; at a later stage, the bearing and deformation capacity decreased as the corrosion rate of steel rebars increased. The test shows that with the increasing of the axial compression ratio, the initial stiffness and ultimate bearing capacity of the joints will increasing if the corrosion levels are the same, but the ductility of that will decrease.     

在SO2存在下青铜腐蚀与相对湿度的关系

采用光度法和亚硫酸氢钢静态分解法研究了不同相对湿度0．1％SO2存在条件下,仿古铜-锡-铝合金的腐蚀情况。在无可溶性氯离子存在下,青铜腐蚀的第一和第二临界相对湿度值分别为50％和65％左右;在有可溶性氯离子存在下,其两个临界相对湿度值均有所降低。从而给出了青铜保存的最佳湿度范围。     

银器处理的一种新方法

巯基苯基四氮唑(PMTA)是近年来发现的优良的防银变色剂。本文采用了甲酸并添加了少量的 PMTA 对银器表面的锈垢进行了处理,效果较为满意。从一批墨西哥银元的试验中可以证明,这种处理方法对银器具有抗变色作用,其效果 PMTA 比苯骈三氮唑(BTA)好,因 BTA 与银形成的配合物膜是呈线型或网状型的结构,而 PMTA 与银形成致密的配合物膜,这膜具有面型的结构,它能更有效地阻断各种腐蚀介质与银的反应。     

Metallurgical findings from a Viking Age chieftain’s farm in Iceland

The metalworking, metal import, and use of metal in medieval Iceland is still little understood. When the Scandinavian settlers colonized Iceland in the 9th c. AD, the island was found to contain no useful metal deposits save for bog iron, and the deforestation that followed the settlement resulted in a scarcity of wood. Only in the last decades have archaeological excavations begun to unravel how the first Icelanders dealt with this lack of resources. This paper presents the metallurgical findings from a Viking Age chieftain's farmstead at Hrísbrú in the Mosfell valley, located just outside Iceland’s present-day capital Reykjavik. The excavated metal objects had all been crafted with good workmanship employing technology similar to that used in mainland Scandinavia. However, most excavated metal finds show evidence of re-use, which together with the second-grade metal in some of the objects indicates a shortage of raw material that prompted the Icelandic colonizers to improvise and make do with whatever material was at hand.