景德镇历代釉里红和“填红”的研究

永乐、夏德及雍正朝所制的带有红三鱼、红三果或红莲织装饰的白瓷通常都称为釉里红。科学检测的结果表明,这种类型的装饰系用“填红”法制成而不是用釉下彩绘法制成,其图案有凸起感,两种不同的装饰工艺产生不同的艺术外观、显微织构和化学组成。作者对此了系统测试。     

Metallurgical Characterization of A Coated Roman Iron Coin By Analytical Investigations

A coated Roman iron coin from Villa Loig in Salzburg, Austria was investigated. The coating is a copper alloy consisting of Cu, Pb, Sn, Zn and negligible amounts of Ag, a variant of gunmetal known as ‘leaded red brass’. The numismatic term for such a coin is subferratus (Latin). From an archaeometallurgical point of view, information about the chemical composition, the microstructure and the manufacturing technique are of interest. To achieve these objectives, different analytical techniques and metallographic examinations were applied. Droplet‐shaped iron inclusions were observed in the red brass coating, while at the grain boundaries, inside the iron core, copper and lead were detected (liquid metal embrittlement). The dendritic microstructure of the coating, the spheroidal‐shaped iron inclusions in the coating and the liquid metal embrittlement show that the iron coin was plated by immersing it in a molten copper alloy. The iron core is a low‐carbon steel with slag stringers, both of which are characteristic of a bloomery iron. Deformation twins (Neumann lines) were observed in the microstructure of the iron core and indicate that the coining was performed after the flan was cooled.     

Never Judge A Gold Object by Its Surface Analysis: A Study of Surface Phenomena in a Selection of Gold Objects From the Staffordshire Hoard

With the introduction of commercially available handheld XRF analysers, there is a growing problem that the results, simply taken at face value, are regarded as representative of the bulk gold alloys of the objects analysed in museums and used for treasure analysis. It is well known that surface analysis is problematic, and the aim of this study was to test whether non‐destructive surface analysis could be useful in grouping the very large numbers of fragmentary pieces in the Anglo‐Saxon Staffordshire Hoard. Surface and subsurface analyses of 16 objects from the Hoard were carried out by X‐ray fluorescence (XRF) and scanning electron microscopy with energy‐dispersive X‐ray analysis (SEM–EDX). The results indicate that there are significant but inconsistent levels of enrichment of the gold at the surface of many of these objects, due to the loss of both copper and silver. The significant loss of silver (up to 50% relative in some cases) suggests that some form of deliberately induced depletion gilding was carried out during manufacture to remove both silver and copper from the surface. In three cases, an increase in silver at the surface compared to the core metal was detected: this might tentatively be explained by redeposition from contact with silver objects during burial. These results have clear implications for the reliability and interpretation of surface analysis data of gold alloys from this period.     

矿区工业旅游开发研究——以江西德兴铜矿为例

矿区工业旅游在我国还没有得到很好的开发。本文以江西省德兴铜矿为例,探讨了矿区工业旅游开发的条件与旅游产品的特点,并对矿区工业旅游的景观形象设计与空间格局规划进行了讨论。     

Modeling Late Copper Age demographics on the Great Hungarian Plain using ceramic petrography

Ceramic petrography can be an effective method for studying demographic shifts and the possibility of migration into a region. This is based on the principle that ceramic manufacturing technology is resistant to change over time, while form and decoration can change quickly even in times of demographic continuity. As such, sudden shifts in raw material preparation and methods of pottery manufacture may be indicative of the arrival of new people in a region. The manufacturing characteristics indicative of such a demographic change are observable and measurable microscopically. Petrography was used to describe and measure paste characteristics of 114 Middle Copper Age, Late Copper Age, Early Bronze Age, and Middle Bronze Age sherds from the Körös region of the Great Hungarian Plain to determine if changes in manufacturing techniques accompanied changes in ceramic form and decoration at the beginning of the Late Copper Age Baden period (ca. cal. 3500 B.C.). A comparison of the petrographic results from the cultural phases showed that little manufacturing and technology change occurred during the time period covered by the study. Migration of new people into the region is therefore not supported, and changes in ceramic form and decoration associated with the Late Copper Age occurred during an extended period of demographic continuity.     

殷墟1004号王墓出土青铜胄研究

对商晚期都城殷墟遗址的1004号王墓出土的7件青铜胄进行了热电离质谱(TIMS)铅同位素比值分析和电感耦合等离子体发射光谱(ICP-OES)成分分析,数据显示铜胄的合金类型可分为两类——锡青铜和铅锡青铜,且其二者的铅同位素比值均处于高放射性成因铅范围。此研究结果为探索金属矿料的产地来源及此著名王墓的年代等问题提供了重要线索。     

Material evidence for the use of Attic white-ground lekythoi ceramics in cremation burials

White-ground lekythoi ceramics offer important evidence for funeral practices in Ancient Greece (5th century BC). The images painted-on these oil containers provide the best visual narrative for the events surrounding death, including indications that the vessels themselves were used as part of the funerary rites. However, until now, their specific function and treatment within the funeral ceremony was not well understood. We present here material evidence that the vessels were ritually burned, together with the body of the deceased, during cremation, as evidenced by a diffuse purplish-red discolouration found on many white-ground lekythoi. Through EPMA and μXAS studies, we show that: (1) this characteristic purplish-red discolouration is due to the presence of metallic copper nano-particles embedded in a glassy layer; (2) this metal-glass matrix formed as the result of a high temperature reaction between painted-on Cu-based pigments (e.g., Egyptian blue) and the white-ground ceramic slip; and (3) the reaction occurred under a reducing environment. Given the mortuary context for these vessels, we propose the reduction firing to which the vessels were exposed was that associated with the cremation of the body. The observation of discontinuous formation of the purplish-red discolouration along adjoining fragments supports the hypothesis that the vessels were broken prior to being burned. The majority of lekythoi in museum collections lack information on their original archaeological context, and our data suggest the presence of this purplish-red discolouration may serve as a visual marker for cremation. As such, it is expected our findings will provide a new basis for interpreting how this important class of ceramic, and associated iconographic imagery, relates to Athenian funerary practices and the ancient Greek notion of death.     

Making sense out of cents: compositional variations in European coins as a control model for archaeometallurgy

Archaeometallurgy frequently seeks to correlate between the temporal and spatial distribution of ancient metal objects and their chemical composition. In this study, we examined whether and to what extent local or temporal deviations in the content of modern artifacts can be identified as a proxy for archaeological material that is typically less controlled and therefore more difficult to cluster. For this purpose, Euro coins of 10, 20 and 50 cents from Germany, France, Spain, Italy and Belgium, which are made of copper (Cu) with 5% aluminum (Al), 5% zinc (Zn) and 1% tin (Sn), were analyzed using a simple XRF analyzer. The mass ratios Sn/Cu and Zn/Cu were measured with a relative precision c.a. of 5%. The mean content of the coins from each country was then determined for 20–39 of them. The difference of the mass ratio Sn/Cu observed – from 0.0101 to 0.0111. One coin from Luxemburg shows differences in various areas of its surface of up to a factor of 1.5. Thus, the results of this small pilot research show that even in modern metal artifacts we can detect differences in metal content, which can be correlated to their production and utilization places. Therefore, this study can serve as a model for evaluating compositional variations noted in archaeometallurgical studies where the standard deviations are greater and the differences can be linked more readily to spatial and temporal differences.     

Natural preservation mechanisms at play in a Bronze Age wooden shovel found in the copper mines of Alderley Edge

A wooden shovel, dating from the Early Bronze Age, has survived in a remarkable state of preservation in the copper mines of Alderley Edge, Cheshire UK. Other historic timbers recovered from the mines, whilst still intact, have fared less well. An X-ray investigation into the distribution of minerals through the shovel using portable X-ray Fluorescence (PXRF) along with the use of synchrotron-based X-ray Absorption Spectroscopy (XAS) measurements of the copper and arsenic chemical speciations has provided clues to the methods by which metals from the mining environment have entered the wood of the shovel and ensured its survival. The distribution and nature of the minerals so determined suggest that the copper and arsenic, along with a significant lead content, entered the shovel during its original use in working mineral-rich deposits, rather than through the burial environment. The insights gained are expected to be applicable to other wooden artefacts recovered from ancient copper mines in other places.     

Moving metals or indigenous mining? Provenancing Scandinavian Bronze Age artefacts by lead isotopes and trace elements

The aim of this study is to further the discussion as to whether copper was extracted locally or imported to Sweden during the Bronze Age or if both of these practices could have coexisted. For this purpose, we have carried out lead isotope and chemical analyses of 33 bronze items, dated between 1600BC and 700BC. Among these are the famous Fröslunda shields and the large scrap hoard from Bräckan and other items from three regions in southern Sweden which are also renowned for their richness in copper ores. It is obvious from a comparison that the element and lead isotope compositions of the studied bronze items diverge greatly from those of spatially associated copper ores. Nor is there any good resemblance with other ores from Scandinavia, and it is concluded that the copper in these items must have been imported from elsewhere. The results furthermore indicate that there are variations in metal supply that are related to chronology, in agreement with other artefacts from Scandinavia as well as from other parts of Europe. Altogether these circumstances open up for a discussion regarding Scandinavia’s role in the maritime networks during the Bronze Age.