The key role of zinc,tin and lead in copper-base objects from medieval Talgar in Kazakhstan

Metallurgical examination of brass and bronze objects from the medieval (AD 9th–13th century) site at Talgar in Kazakhstan shows that they were mostly cast from the quaternary copper–zinc–tin–lead system with some exceptions that were forged from binary copper–zinc alloys. Evidence is found that brass was produced in the cementation process and that the addition of tin and lead to the parent brass was considered beneficial in casting but was strictly avoided in forging. The mutual effect of zinc, tin and lead for better casting and the advantages of the binary copper–zinc alloys in forging seem to have been the major factors driving the establishment of this unique brass tradition in a society with probably limited access to tin.     

Fortifications and Enclosures in European Prehistory: A Cross-Cultural Perspective

This article reviews recent research into the archaeological interpretation and investigation of fortifications and enclosures during the Neolithic and Bronze Age in Europe. Recent methodological, technological, and cultural developments have expanded our understanding of the temporal, spatial, and formal variability of these features on the landscape. Interpretations of this variability also have varied with different theoretical trends in the discipline. We advocate a cross-cultural approach that focuses on the occurrence of enclosures and fortifications over the long term at the continental scale. Such a macroscalar approach complements interpretive frameworks at the regional and microregional scales. The geographic and temporal distribution of these features indicates that social institutions associated with principles of segmentation and substitutability became formalized and tethered to the landscape during the Neolithic.     

A New Method For Combining Lead Isotope and Lead Abundance Data to Characterize Archaeological Copper Alloys*

We present a new methodology for interpreting lead isotope data from archaeological copper alloy objects. It is not based on the conventional isotope ratio biplots, which were originally devised to allow the calculation of the geological age of the lead mineralization, but is derived from isotope mixing models, more often used for presenting strontium isotope data. We illustrate the method by reworking published data on Sardinian Nuragic oxhide ingots and copper alloy artefacts. While we confirm the consensus assumption that the oxhide ingot fragments found on Sardinia are isotopically consistent with Cypriot copper ores (although we see no isotopic reason to favour only Apliki, as originally suggested), we also show that there is evidence for mixing between local and ingot copper in some objects, which was previously not detected. More broadly, we suspect that the apparent mismatch between some source allocations for copper drawn from isotope geochemistry and the rest of the archaeological data in some cases might be due to mixed isotopic signals being incorrectly assigned to a specific source, and suggest that the method presented here will reduce the chances of this happening.     

The Use of Copper and Lead Sheathing in VOC Shipbuilding

Much has been written on the use of lead and copper sheathing in post mediaeval shipbuilding, yet evidence for such hull protection by Dutch shipwrights in the 17th and 18th centuries has received little attention. A discussion of the archaeological and historical evidence pertaining to the application of copper and lead sheathing by the Dutch long‐distance trading companies outlines the argument for the innovative character, experimental use—on ships’ hulls—and standardization—on sternposts—as early as 1602. Archaeological evidence presented mainly comes from the Dutch East Indiamen Nassau (1606), Mauritius (1609), Batavia (1629), Vergulde Draak (1656), and Buitenzorg (1760).     

黄河流域早期铜器演进初探

黄河流域是中国早期铜器起源与发展的关键区域,早期铜器的演进受社会复杂化程度制约。在文明化进程的视野下,本文通过用铜遗存的考古信息与社会经济背景,将黄河流域早期铜器的演进分为早期用铜的萌芽、发展初期及区域化特征形成三个阶段,初步阐释铜制品从出现到规模化使用的过程。人群流动、定居农业、手工业生产、城市与权力的集中是影响黄河流域早期铜器演进模式的重要因素。大体在公元前2300年至前1400年的文明进程中,黄河上游铜器的制作与使用具有相似的风格及开放共融的特征,而黄河中下游地区防御性城市与权力的发展,推动了铜器技术与社会功用的本土化转变。     

The smelting quarter of Valencina de la Concepción (Seville,Spain): the specialised copper industry in a political centre of the Guadalquivir Valley during the Third millennium BC (2750–2500 BC)

The first specialized copper industry of the Iberian Peninsula was developed at the start of the Third millennium BC with the appearance of mining-metallurgical settlements in its main mining district (the Pyrite Belt of the south-western). Between 2750 and 2500 BC, however, and right at the centre of the Guadalquivir Valley, the great farming settlements that ranked the territory developed a new level of metallurgic intensification with the creation of the first industrial quarters. As a way of explaining this new situation, we present the results of the systematic research (microspatial analysis; radiocarbon dating; petrologic, geochemical, metallographic and isotopic study of minerals, slag and products, …) carried out in one of them, the one developed in the main and largest political centre of the Guadalquivir Valley during the first half of the Third millennium BC: Valencina de la Concepción (Seville, Spain).     

Dental evidence of biological affinity and environmental conditions in prehistoric Trentino (Italy) samples from the Neolithic to the Early Bronze Age

The use of teeth in anthropological analyses has always provided valuable information on the subsistence patterns of human communities, as well as the biological relationships among them. The present study analyses the permanent dentition of several diachronically continuing samples from the Trentino alpine region of Italy from the Neolithic to the Early Bronze Age. The study of both metric and non‐metric dental traits show a strong level of homogeneity from the earlier to the later samples, indicating little external biological influence from surrounding areas. However, the evidence of oral pathology and linear enamel hypoplasia highlights a trend of increase in defects, particularly between the Neolithic and the Copper Age. This has been ascribed to a shift towards more intense agricultural activities and pastoralism, that led to a change in diet and to an increased sedentism. Copyright © 1999 John Wiley & Sons, Ltd.     

川陕省苏维埃铜元金属成分及相关问题分析

川陕省苏维埃铜元是第二次国内革命战争时期遗留下来的重要革命文物，它承载着中国共产党与川陕苏区人民英勇奋斗的光辉历程，本工作通过能量色散型X射线能谱(EDS)技术对二种面值、三个种类、九个版类的川陕省苏维埃铜元成分进行了研究，结合川陕省苏维埃铜元产地的历史变迁及版类的生产顺序，发现川陕省苏维埃铜元的含铜量整体上远高于晚清、民国典型黄铜元的铜含量，而稍低于典型红铜元的铜含量。随着生产时期向后推移，川陕省苏维埃铜元的含铜量逐渐增加并达到95%左右，而锌、铅、锡的含量则呈现出较明显的降低趋势。分析表明，川陕省苏维埃政府早期生产的大二百文铜元，中后期生产的部分无齿类小二百文铜元和繁体联五百文铜元极可能是采用红铜元、杂铜混合重铸的方式制造，而鼎盛时期生产的有齿类小二百文铜元和简体联五百文铜元则是合格的红铜元。这一动态变化趋势说明，苏维埃造币机构在铜元生产过程中，其原材料筛选标准逐渐明确并日趋严格，反映了苏维埃政府在铜资源管理与使用上逐渐趋于合理化。     

Precision in the X-ray fluorescence analysis of sixty-one Augustan quadrantes

Sixty-one Augustan quadrantes were analysed for calcium, iron, nickel, copper, silver, tin, antimony, and lead by X-ray fluorescence. Most coins contained about 99·7% copper with the other seven elements present as trace impurities. Significant differences in composition were found for the three different issues of quadrantes minted in c. 9 BC indicating that these issues were not minted exactly contemporaneously. Quadrantes minted in c. 4 BC have trace element concentrations in ranges that differ from those of the 9 BC quadrantes. The precision is very good for all trace elements (the precision of calcium was not calculated): average standard deviations are 0·0021% for Fe, 0·0026% for Ni, 0·0038% for Ag, 0·0014% for Sn, 0·0031% for Sb, and 0·015 for Pb.