ARCHAEOLOGICAL AMBERS FROM NORTHERN ITALY: AN FTIR–DRIFT STUDY OF PROVENANCE BY COMPARISON WITH THE GEOLOGICAL AMBER DATABASE*

European geological ambers of five different localities and types, and Italian geological ambers from seven different deposits have been studied with Fourier transform infrared spectroscopy (FTIR) and diffuse‐reflectance infrared Fourier transform (DRIFT). Ambers from several localities have been characterized for the first time. The research aims to create a database of European ambers, containing both FTIR and DRIFT data. The FTIR spectra are easily comparable with the data commonly available in the literature, whereas DRIFT analyses are shown to be more useful to characterize the archaeological finds. The provenance of several archaeological ambers from northern and southern Italy, dating from the Middle Bronze Age to the Iron Age, is assessed on the basis of the developed database. Of the 35 analysed archaeological objects, all but five are composed of Baltic succinite amber.     

A MULTIDISCIPLINARY APPROACH TO THE CHARACTERIZATION OF ROMAN GRAVESTONES FROM AQUILEIA (UDINE,ITALY)*

The results of an archaeometric study on gravestone production in Aquileia (northeastern Italy) during Roman Republican times are reported here. The artefacts are made of limestone, quarried from the sedimentary sequence of the Trieste Karst (Carnican Alps, northeastern Italy), as testified by historical sources which refer to the ‘Roman Quarry’ at Aurisina. The rock types used for the gravestones are petrographically, geochemically and geochronologically homogeneous, and display similar faunal assemblages. In addition, their age is restricted to the Santonian – Lower Campanian. Comparisons between archaeological finds and rock specimens from various active and inactive quarries in this area suggest that quarrying during Roman Republican times was limited to a specific stratigraphic horizon of the sedimentary sequence, corresponding to the higher part of the ‘Roman Quarry’.     

LOCALIZING HISTORICAL CLUES USING IRT AND PETROGRAPHIC ANALYSES AT VILLA MIRABELLO,MONZA (ITALY)*

The rebuilding of Villa Mirabello started in 1666. Built on designs of Gerolamo Quadrio, the project refurbished and enlarged a smaller 16th century country house (‘casa da nobile e da massaro’). Archival documents report on the remodelling, which consisted of selective demolition of portions of the structure, re‐using most of the masonry as the core of the new building, and the reinforcement of retained masonry by insertion of ‘ceppo’ stone quoins to update new exteriors. The aim of Quadrio was to create an elegant and sumptuous mansion, suitable for noble owners such as Giuseppe Durini and his family. The plan and a small part of original finishing (‘marmorino’ plaster decoration) are recognizable nowadays. Nevertheless, there are many questions in interpretation when one compares the documents and the building. That is, Cardinal Angelo Durini made a major modification in the 18th century, and further minor changes were made in the 19th century. Although these latter modifications did not alter the plan, they changed the distribution of rooms and masked both decoration and finishing. After over 20 years of neglect, Villa Mirabello is now close to being restored. Architects in charge ordered a preliminary set of diagnostics to assess damage and study the historical evolution of the building. Integration of IR thermography (IRT) and endoscopy allowed restorers to detect the structure's texture underneath the plaster, and to detect openings filled with masonry. Moreover, archive documents confirmed these results and, above all, defined a date for the use of specific building techniques. This research constitutes a reference for buildings set in the same time and location that do not have significant archival documentation. Active IRT provided useful information for structural assessment (such as location of arches, chimney stacks, different thickness of wall, wooden elements, voids, beams etc.) and for crack pattern evaluation. This information directs design professionals working on this conservation project, and helps define the costs of intervention.     

THE APPLICATION OF TIME‐OF‐FLIGHT SECONDARY ION MASS SPECTROMETRY (ToF‐SIMS) TO THE CHARACTERIZATION OF OPAQUE ANCIENT GLASSES*

Time‐of‐flight secondary ion mass spectrometry (ToF‐SIMS) has been used, for the first time, for the characterization of opaque ancient glasses. Isotope‐specific chemical imaging with sub‐micron resolution enabled the separate analysis of opacifiying inclusions and the surrounding glass matrix. Phase identification has been demonstrated and quantification of the matrix composition has been investigated by use of Corning Glass Standard B as a model. Trace element detection limits are typically in the range 0.5–5.0 ppm atomic—in favourable cases down to 0.01 ppm. For the analysis of inclusions in particular, this has the potential to provide new information of use in establishing provenance and trade routes by ‘fingerprinting’ as well as the investigation of manufacturing techniques, as demonstrated by comparisons between glasses and with EDX data from the same samples.     

Inductively coupled plasma emission spectroscopy and Postclassic Petén slipped pottery: an examination of pottery wares,social identity and trade*

ICP–ES analysis of the clay pastes of Postclassic (c. ad 850–1524) slipped pottery from the central Petén lakes region establishes chemical composition groups that provide information concerning manufacturing traditions and trading patterns. These data demonstrate that manufacturing traditions and trading patterns change throughout the Postclassic period, reflecting possible socio‐political alliances as different ethnic groups migrated to and from the Yucatán peninsula into the central Petén lakes region. The chemical composition groups also demonstrate that some manufacturing traditions imitate those from the Late Classic period and that some clay sources were used throughout the Postclassic period for multiple ceramic groups.     

INVESTIGATION ON ROMAN LEAD GLAZE FROM CANOSA: RESULTS OF CHEMICAL ANALYSES*

Five sherds of green glazed pottery excavated at Canosa (Apulia) in Italy have been analysed by scanning electron microscopy. The aim of the investigation was to determine the chemical composition of the glazes and thus obtain information on the methods used in their production. The glazes were all of the high‐lead type, coloured green by the addition of copper. Intermediate layers, observed at the interface between the glaze and body and giving the appearance of an applied white slip, were the result of the crystallization of lead feldspar from the molten glaze. Non‐calcareous clays were used in the production of the pottery bodies. Concentration profiles from the glaze exterior to the body suggested that the glazes were produced by applying a suspension consisting of lead oxide plus silica to the bodies. On the basis of the glaze and body compositions, it is suggested that the Canosa glazed pottery was produced locally.     

STONES FROM MEDIEVAL GLASSMAKING: A SUITABLE WASTE PRODUCT FOR RECONSTRUCTING AN EARLY STAGE OF THE MELTING PROCESS IN THE MT LECCO GLASS FACTORY*

The Mt Lecco glass factory was one of the most important production centres in Liguria (Italy) during the 14th and 15th centuries. Archaeological evidence indicates that the whole production cycle took place here. During the glassworking process, production defects such as ‘stones’ were identified and discarded. Stones are partially melted, glass‐coated relics of raw materials or fragments of crucible. The study of the microtexture of stones together with microprobe analyses of phases provides a key for understanding the glassmaking procedure carried out in the Mt Lecco glass factory. The melting rate can be inferred from the compositional variability of glass, which suggests fractional melting of the batch. Glass composition indicates that the Mt Lecco production was a mixed‐alkali one, probably made of quartz‐bearing material as vitrifying agents, plant ashes as fluxing agents and dolomitic limestones as stabilizing agents.     

A QUANTITATIVE FABRIC ANALYSIS APPROACH TO THE DISCRIMINATION OF WHITE MARBLES*

Quantitative fabric analysis was applied in order to discriminate better among white marbles from various quarries of archaeological interest. This method provides an effective complementary tool to a characterization based upon petrography, cathodoluminescence microscopy and stable isotopes. Very good discrimination of marbles is achieved with the help of simple variables such as major axis and the shape-specific PARlS-factor. Using quantitative fabric analysis, marbles with similar cathodomicrofacies, as, for example, the Naxian quarries of Apiranthos, Koronos, Flerio and Kinidaros and the quarry of St. Beat (French Pyrenees), can be distinguished from each other. Marbles collected within one quarry may display dissimilar cathodomicrofacies. The common origin of such specimens can be determined with the aid of quantitative fabric analysis, as shown for the quarries of Kinidaros as well as St. Béat.     

COLOURED OPAQUE GLASS BEADS OF THE MEROVINGIANS*

Monochrome coloured opaque glass beads of the Merovingians have been examined by different analytical methods. A large number of mostly unprepared beads have been measured by X‐ray fluorescence analysis. X‐ray diffraction was used for the identification of the crystalline colouring and opacifying pigments, and electron probe micro‐analysis as well as scanning electron microscopy were applied to study the composition and the microstructure of a white, brown, green, orange and yellow glass bead. After subtracting the content of colouring oxides of the glass beads and normalizing the residual values to 100% an identical soda‐lime‐glass matrix was obtained. The origin of the colouring metal oxides is discussed.     

SHAFT‐HOLE AXES FROM CAPUT ADRIAE MADE FROM AMPHIBOLE‐RICH METABASITES: EVIDENCE OF CONNECTIONS BETWEEN NORTHEASTERN ITALY AND CENTRAL EUROPE DURING THE FIFTH MILLENNIUM BC

Here we show the results of a study concerning a small group of shaft‐hole axes found in northeastern Italy, made from amphibole‐rich metabasites, fine‐grained and free of phenoblasts. The main mineral phases are amphibole, ranging from actinolite to hornblende, and plagioclase (An_10–15 and An_70–77). The amphiboles generally show a needle shape and are often radially arranged. Quartz is present in thin veinlets, while ilmenite is widespread in small patches. The petrographic and geochemical features suggest that the axes originate from the southern thermal aureole of Tanvald granite in northern Bohemia. In accordance with this provenance, the typology of the tools shows similarities with the perforated shoe‐last axes spread across Central Europe during the fifth millennium bc and made from similar raw material. For the first time, these axes give evidence of long‐distance (about 800 km) contacts between northeastern Italy and Central Europe during the Neolithic.