Uranium-series dating rock art in East Timor

At many sites throughout the world rock art paintings have been covered by naturally deposited calcite laminations, which we demonstrate can be individually dated by recently improved uranium-series methods. Here we report the application of multi-collector inductively coupled plasma mass spectrometry to measure the ages for carbonate coatings that bracket red pigment at Lene Hara cave, East Timor, which could be evidence of human painting. These analyses establish the feasibility of dating milligram samples of finely layered calcite deposits associated with archaeological evidence of human occupation. In addition to confirming an age of less then 6300 years for the visible red paintings on the carbonate surface we also report a substantially older age of 24,000 to 29,300 years for a similar, older red pigment lamination providing possible evidence for an earlier painting episode.     

An analytical study, using inductively coupled plasma (ICP) spectrometry, of samian and colour-coated wares from the Roman town at Colchester together with related continental samian wares

Over 200 sherds of samian and colour-coated pottery of late 2nd or early 3rd century date have been analysed by inductively coupled plasma (ICP) emission spectrometry. Most of this material was excavated at Colchester, England; the remainder is related East Gaulish material. Some clay samples were also analysed. The material divides, after multivariate statistical analysis, into 11 clusters. These accord well with known archaeological evidence and suggest assignments of origin where these are uncertain. In particular, the archaeological evidence for a link between Colchester and the Sinzig potters is supported.     

The persistence of caffeine in experimentally produced black drink residues

Black drink is a native North American caffeinated tea produced from the leaves of Ilex vomitoria. The beverage was an important part of prehistoric Southeastern culture, as it was the only native source of caffeine in North America. The leaves of I. vomitoria were, therefore, a potentially valuable trade resource during the period. As such, the ability to identify archaeological black drink residues is useful to Southeastern archaeologists. In order to determine the plausibility of detecting I. vomitoria in residues, black drink was repeatedly produced in experimental unglazed pottery. The resulting potsherds were buried in several environmental contexts, recovered, and underwent absorbed pottery residue analysis. After two months of burial in three different soil types, plus a control stored in the freezer, caffeine was well-preserved in all sherds, suggesting that caffeine is a potentially useful biomarker for the detection of black drink.     

Historical Survey and Chronology of Bonajuto Chapel in Catania,Italy

Located in the historical center of Catania, Italy, in the Civita district, the Bonajuto Chapel is one of the oldest and best-conserved buildings of the city, which has survived the numerous earthquakes that struck eastern Sicily during the medieval and the modern ages, such as those particularly devastating in 1169 and 1693. However, both the date of this small monument, as well as its original use, still remain uncertain, as literary and documentary evidence are scarce and fragmentary. Most historians, analyzing prevalently the stylistic and constructive aspects, interpreted the chapel as a place of worship and assigned its construction to a rather long period of the early Middle Ages, from the 5th or 6th centuries ad to the 8th or 9th centuries ad—the phase during which the island was under the Byzantine domination. The excavations carried out in 1930 to 1939 and the last restoration works (in 2003) have not provided explicit chronological data. Its age determination is considered essential for a better knowledge of the real influence of this domination on the architecture of the Island. Therefore, a multidisciplinary and accurate analysis of the building using the existing bibliography has been carried out also in order to understand the functional and morphological transformations of the chapel during its long life. The thermoluminescence absolute dating methodology applied to some brickwork elements of the construction, has placed the monument chronology in a period of time that is notably shorter than that previously noted here. These new data, with the study of the architectural structure, have made a significant step forward in the knowledge of the chapel history.     

张家川马家塬战国墓地M21墓葬中铁器表面纺织残留物的鉴定

马家塬战国墓地是研究西戎文化以及秦戎文化交流的重要考古遗址。在M21墓葬发现了一些附着于铁器表面的矿化纺织品残片。这些矿物外壳保留了比较完整的纺织品形态,是研究早期纺织技术的宝贵资料。为此,本研究采用扫描电子显微镜(SEM)和高效液相色谱-质谱联用技术(HPLC-MS)对矿物纺织品残片的纤维原料进行了鉴定与分析:1)矿物外壳内部的纤维空洞结构形态与桑蚕丝的纤维形态特征相同;2)样品中检出了3组蚕丝蛋白的特征多肽片段。研究结果表明,M21墓葬中的纺织品残片的原料为蚕丝纤维(Bombyx mori)。丝绸的发现表明中原的丝绸成品或者纤维原料已经进入西戎地区,西戎与中原文明的交流更加密切。使用丝绸包裹铁器则表明西戎文化已经受到了一些中原风俗的影响。这一发现填补了马家塬遗址中纺织品研究的空白,不仅为研究秦戎地区的织造工艺和文化交流提供了重要资料,也为矿化纺织遗存中的桑蚕丝残留的鉴定提供了技术支持。     

Application of lipid biomarker analysis to evaluate the function of ‘slab-lined pits’ in Arctic Norway

Gas chromatography–mass spectrometry (GC–MS) and bulk carbon isotope determinations have been performed on samples (‘cemented organic residues’, charcoal, sediment and fire-cracked rock) excavated from 12 slab-lined pits from various locations in Arctic Norway to test the premise that these archaeological features were used for the extraction of oil from the blubber of marine mammals, such as seal, whale and walrus. A wide range of lipid compound classes were detected especially in the cemented organic residues and in the charcoal samples. The presence of long-chain unsaturated and isoprenoid fatty acids together with oxidation and thermal alteration products of unsaturated acids such as dicarboxylic acids, dihydroxyfatty acids and ω-(o-alkylphenyl)alkanoic acids suggests that these features were used for marine oil extraction at elevated temperatures. Notably the location of the hydroxyl groups in the dihydroxyfatty acids provides a record of the positional isomer of the precursor fatty acid and allows confirmation that 11-docosenoic (cetoleic) acid, the most abundant C_22:1 isomer in marine oil, was a major component of the original lipid. Further information was provided by the presence of long-chain fatty acyl moieties in surviving triacylglycerols and the presence of cholesterol. A fungal metabolite, mycose (trehalose), was found in all samples apart from a fire-cracked rock and points to microbiological activity in the pits. Bulk isotope analysis conducted on the ‘cemented organic residues’ is consistent with modern reference samples of blubber and oil from seal and whale. These data provide clear analytical evidence of the function of slab-lined pits in the archaeological record and suggest widespread exploitation of marine mammals for producing oil for heating, lighting and myriad other uses in the past.     

Re-examining the Egyptian colonial encounter in Nubia through a compositional,mineralogical, and textural comparison of ceramics

Textural, mineralogical, and X-Ray fluorescence (XRF) analyses are used as a cost effective method to distinguish for the first time ancient Egyptian and Nubian-style ceramics found in Nubia. Textural and mineralogical data suggest that Nubian-style sherds are mixtures of sand, silt, and clay sediment that is generally finer grained and poorer in quartz than is the sediment mixture used to produce Egyptian-style pottery. Chemical data also establish a significant difference in the amount of chemical variation found within each style population, but nonetheless supports a considerable overlap in the possible provenance of both styles. Observations and data obtained during this study indicate that standardized, Egyptian-style manufacturing was introduced into Nubia under colonialism, without substantially altering the diversity of native methods of production.     

Colour in Minoan faience

The microstructures and chemical compositions of some 15 faience objects from Crete spanning the period from Middle Minoan IIIA through to Late Minoan IA are determined using analytical scanning electron microscopy. The Minoan faience is compared with replicate faience beads produced in the laboratory using various combinations of manganese, copper and iron as colorants. The alkali contents of the replicate beads are varied so that the colorants are present both as ions in a glass phase and as particulate oxides. These data are then used to try to infer the original colour of the Minoan faience, the great majority of which has suffered severe weathering during burial. The results suggest that instead of the present day “hallmark greys and browns” and “subtle greens and blues”, Minoan faience originally exhibited a wide range of colours, including bright turquoise blue, purple and violet, and pale yellow-green and greenish turquoise.     

AMS C dating of early human occupation of southern South America

The time of appearance of a persistent and demographically-viable hunter-gatherer population in late Pleistocene southern South America must be determined by evaluating evidence from as large as possible a sample of candidate archaeological sites in the region. We co-ordinated the AMS dating of multiple bone and charcoal samples from previously-excavated strata at the following sites: Arroyo Seco 2, Paso Otero 5, Piedra Museo, and Cueva Tres Tetas (all in Argentina), and Cueva del Lago Sofia 1 and Tres Arroyos (both in Chile). With one possible exception, we did not obtain new results to confirm earlier observations of pre-Clovis-age cultural activity at any of the sites considered in this study. The possible exception, Arroyo Seco 2, is considered in detail elsewhere [Politis G., Gutierrez M.A., Scabuzzo, C. (Eds), in press. Estado actual de las Investigaciones en el sitio 2 de Arroyo Seco (región pampeana, Argentina). Serie Monográfica INCUAPA 5. Olavarría]. However, our results for the samples which were the most preferred indicators of cultural events (hearth charcoal and cut-marked bone) confirm that people were in the southern cone of South America at or soon after 11,000 BP (13,000 cal BP). Considered alongside recent age estimates for the Clovis culture in North America, these results imply the contemporaneous emergence of a consistent and archaeologically-robust human occupation signal at widely-separated locations across the Western Hemisphere. Such findings suggest that Palaeoindian demic expansion may have involved more than one terminal Pleistocene dispersal episode.     

Indications of embalming in Roman Greece by physical,chemical and histological analysis

The partially mummified remains of a high-status female (ca. 1700 BP, Thessaloniki, Greece) were found inside a Roman-type marble sarcophagus containing a lead coffin. The individual was positioned on a wooden pallet, wrapped in bandages, and covered with a gold-embroidered purple silk cloth. Besides the clothes, remnants of soft tissue as well as the individual's original hair style and eyebrows were exceptionally well preserved. In addition to the macroscopic examination, microscopic and biochemical analyses were undertaken. Scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, and gas chromatography/mass spectrometry (GC/MS) were applied to examine the tissue preservation and probable mechanisms of mummification. The presence of chemical components, such as sesquiterpenes, triterpenoids, and diterpenoids, originating from coniferous and pistacia resins, myrrh, and other spices, verify ancient information on preparation methods of the dead in Greek and Roman times. These chemical components are thought to have played a prominent role in the mummification mechanism in this particular case. The potential effect of the lead coffin in the mummification process was also examined. Energy-dispersive X-ray analysis failed to detect lead penetration into the tissues, suggesting that the coffin played a limited role in the preservation of soft tissue.