CHARACTERIZATION AND PROVENANCE OF LIME PLASTERS FROM THE TEMPLO MAYOR OF TENOCHTITLAN (MEXICO CITY)

In this work, we present the results of the analyses of 20 lime plaster samples taken from the Templo Mayor (Great Temple), the main pyramid of Tenochtitlan (Mexico), the ancient capital of the Mexicas. The samples were analysed to recover information on the mixtures used in the fabrication of the plasters and for the provenance of the raw materials (in particular, limestone) used to make the plasters. The characterization of the samples was done by OM, SEM/EDS, XRF and LA–ICP–MS analyses, while the identification of the provenance of raw materials was done by studying the lumps present in the samples with LA–ICP–MS. The objective of the study was to establish if there was a relationship between changes in the construction techniques employed in the pyramid over time and if there were changes in the provenance of the raw materials. Six different construction phases of this pyramid are analysed, showing the similarities and differences among them, mainly based on differences in the sieving of the aggregates and in the raw materials employed. The provenance studies of the limestone used to make the plasters demonstrated that all the limestone comes from the Tula region.     

Radiocarbon method in monitoring of fossil fuel emission

The traditional radiocarbon method widely used in archaeology and geology for chronological purposes can also be used in environmental studies. Combustion of fossil fuels like coal, natural gas, petroleum, etc., in industrial and/or heavily urbanized areas, has increased the concentration of carbon dioxide in the atmosphere. The addition of fossil carbon caused changes of carbon isotopic composition, in particular, a definite decrease of ¹⁴C concentration in atmospheric CO₂ and other carbon reservoirs (ocean and terrestrial biosphere), known as the Suess effect. Tree rings, leaves, as well as other annual growing plants reflected the changes of radiocarbon concentration in the atmosphere due to processes of photosynthesis and assimilation of carbon from the air. By measuring radiocarbon concentration directly in atmospheric CO₂ samples and/or biospheric material growing in industrial and/or highly urbanized areas where high emission of dead carbon is expected, it is possible to estimate the total emission of dead CO₂. Based on equations of mass balance for CO₂ concentration, stable isotopic composition of carbon and radiocarbon concentration it is possible to calculate CO₂ con-centration associated with fossil fuel emission into the atmosphere. The procedure use differences between the radiocarbon concentration and stable isotope composition of carbon observed in clean areas and industrial or/and highly urbanized areas.     

Geography and Economic Preferences as Cultural Markers in a Border Town: The Faunal Remains from Tel Beth‐Shemesh,Israel

We present a zooarchaeological analysis of the faunal remains at Tel Beth‐Shemesh, a site located in the Shephelah region of Israel, which has been dated to the Late Bronze Age and Iron Age I. The site, identified as the biblical city of Beth‐Shemesh, was a Canaanite border town between Philistine and Israelite settlements and of great importance in our attempts to understand the social and cultural transformations that occurred in the southern Levant during those periods. This study contributes to a more accurate understanding of the cultural identity of the site's inhabitants by exploring the cultural differences between populations as reflected in their different dietary preferences. We analysed the subsistence economy at the site, the general exploitation patterns, herd management strategies and consumption practices, all of which are based mostly on domestic livestock. We determined the cultural identity at the site mainly by comparing the representation of pig remains with that found at other sites in the region, and offer various explanations for the differences. The comparisons revealed clear differences between Tel Beth‐Shemesh and other known nearby Philistine sites. This site appears to have possessed a self‐contained production and consumption economy with similarities in the general pattern of animal exploitation between the two periods. These similarities constitute evidence for the continuation of the local population and of its culture at the site during the period of turmoil that swept the region during the transition to the Iron Age. Copyright © 2013 John Wiley & Sons, Ltd.     

A PROVENANCE STUDY OF TANG SANCAI FROM CHINESE TOMBS AND RELICS BY INAA*

In order to group specimens of Tang Sancai of unknown provenance to the different kilns according to their chemical compositions, we studied the elemental abundance patterns of Tang Sancai body samples from different tombs, relics and kilns by instrumental neutron activation analysis (INAA). Our results indicated that the development process of Tang Sancai in the Prospering Tang period could be divided into at least two phases, with ad 705 or so as the boundary between them. The results of factor analysis showed that the red‐bodied samples were more likely to be produced near Xi’an, whereas the white‐bodied Tang Sancai wares dating to before ad 705 were most probably produced at Huanye Kiln (also known as ‘Gongxian’ Kiln), and the figures were very likely made at an undiscovered kiln near Luoyang or an undiscovered part of Huangye Kiln. Among the white‐bodied samples dated from ad 705 to ad 755, both types of figures and wares were mainly produced near Xi’an and Luoyang.     

Pore‐scale investigation on stress‐dependent characteristics of granular packs and the impact of pore deformation on fluid distribution

Understanding the effect of changing stress conditions on multiphase flow in porous media is of fundamental importance for many subsurface activities including enhanced oil recovery, water drawdown from aquifers, soil confinement, and geologic carbon storage. Geomechanical properties of complex porous systems are dynamically linked to flow conditions, but their feedback relationship is often oversimplified due to the difficulty of representing pore‐scale stress deformation and multiphase flow characteristics in high fidelity. In this work, we performed pore‐scale experiments of single‐ and multiphase flow through bead packs at different confining pressure conditions to elucidate compaction‐dependent characteristics of granular packs and their impact on fluid flow. A series of drainage and imbibition cycles were conducted on a water‐wet, soda‐lime glass bead pack under varying confining stress conditions. Simultaneously, X‐ray micro‐CT was used to visualize and quantify the degree of deformation and fluid distribution corresponding with each stress condition and injection cycle. Micro‐CT images were segmented using a gradient‐based method to identify fluids (e.g., oil and water), and solid phase redistribution throughout the different experimental stages. Changes in porosity, tortuosity, and specific surface area were quantified as a function of applied confining pressure. Results demonstrate varying degrees of sensitivity of these properties to confining pressure, which suggests that caution must be taken when considering scalability of these properties for practical modeling purposes. Changes in capillary number with confining pressure are attributed to the increase in pore velocity as a result of pore contraction. However, this increase in pore velocity was found to have a marginal impact on average phase trapping at different confining pressures.     

Direct inversion of Young's and Poisson impedances for fluid discrimination

Seismic inversion with prestack seismic data such as amplitude variation with offsets (AVO) inversion is an important tool in the estimation of elastic parameters for predicting lithology and discriminating fluid in conventional or unconventional hydrocarbon reservoirs. The product of Young's modulus and density (Young's impedance, YI) and the product of Poisson ratio and density (Poisson ratio impedance, PI) show great potential in lithology prediction and fluid discrimination of unconventional resources such as shale gas or oil. The high quality requirements for prestack data in density inversion render the estimation of YI and PI arduous and inaccurate with a conventional prestack inversion approach. In this study, a direct AVO inversion approach is proposed to estimate YI, PI, and density directly from P‐wave seismic data. The linearized P‐wave reflectivity approximate equation in terms of YI, PI, and density is initially derived. Five models, including four typical AVO classes, are utilized to verify the accuracy of the derived linearized P‐wave reflectivity equation in comparison with the exact P‐wave reflectivity equation and the frequently used linearized reflectivity approximate equation involving P‐ and S‐wave velocities and density. Parameter sensitivity analysis illustrates that YI and PI can reasonably be estimated from P‐wave reflectivity if a decorrelation scheme is utilized in the inversion algorithm. In addition, a pragmatic AVO inversion using a Bayesian scheme is suggested for the direct inversion of YI and PI from prestack seismic data. Synthetic and field data examples demonstrate the feasibility of the proposed inversion approach in the estimation of YI and PI and show the potential of this approach in fluid discrimination.     

First note on marine-like cementation of Late Holocene beachrock,Iznik Lake (Turkey)

Micro-fabric characteristics and optically stimulated luminescence (OSL) dating results are presented to discuss the controlling agents and timing of beachrock cementation on the fresh-water Iznik Lake shoreline. The beachrocks are made up of grain-supported polygenic conglomerate containing 20.42% carbonate with encrusted grains, basically as micrite coatings, isopachous aragonite rims, cryptocrystalline void fills and meniscus bridges. The optical ages of twelve samples yielded ages that range from 4.226±0.569 ka on the lowermost beds to 0.706±0.081 on the uppermost. This is the first report of precipitation of marine-like cements in Iznik Lake. The abundant aragonite-dominated cement is likely indicative of precipitation-prone dry evaporative conditions from the climatic optimum to the last millennia.