Salt weathering of sandstone at the Angkor monuments,Cambodia: identification of the origins of salts using sulfur and strontium isotopes

The Angkor monuments in northwestern Cambodia, which are primarily made of sandstone, are suffering from deterioration due to salt weathering. In order to elucidate the sources of the salts and salt weathering process, this paper analyzed bulk chemical compositions and S (sulfur) and Sr (strontium) isotopic ratios for the salts and surrounding environmental materials. At places where bats inhabit the structures, various kinds of sulfate and phosphate salts are formed on the surface of the sandstone. The results of the analysis demonstrate that the S and P (phosphorus) components in the salts are primarily derived from bat guano. Moreover, Ca (calcium), which is the major element in the salts, is suggested to be derived from both bat guano and the sandstone. The isotopic data strongly suggests that bat guano is related to salt weathering. Removal of these animal excrements is essential for future conservation of these monuments. On the other hand, exfoliation of sandstone commonly occurs due to crystallization of calcite (CaCO₃) on platform surfaces of pyramid-type monuments. A large amount of Ca in calcite is suggested to be derived from calcite cement of the building sandstone.     

Early Maya Ritual Practices and Craft Production: Late Middle Preclassic Ritual Deposits Containing Obsidian Artifacts at Ceibal,Guatemala

This article examines Preclassic Maya ritual practices and craft production by means of a study of ritual deposits containing obsidian artifacts dated mostly to the late Middle Preclassic period (700–350 b.c.) at Ceibal, Guatemala. New ritual practices developed at Ceibal during this period, possibly through political interactions and negotiation involving emerging elites and other diverse community members. Common objects in ritual deposits in the public plaza shifted from greenstone celt caches to other artifacts, including those made of obsidian. The inhabitants of Ceibal engaged in various kinds of craft production, including the manufacture of obsidian prismatic blades. They also conducted public rituals in the Central Plaza, depositing exhausted polyhedral obsidian cores and other artifacts with symbolic significance in caches and as offerings in incipient elite burials and interments of sacrificed individuals. These cores clearly demonstrate the use of a sophisticated blade technology. Like greenstone objects, exhausted polyhedral obsidian cores deposited in cruciform arrangements along the east–west axis of the central E-Group plaza were used as symbols and markers of the center and four cardinal directions within the Maya cosmos. Public rituals were important for creating collective identities and for processes of political negotiation within the community. Emerging elites likely came to play an increasingly important role in public rituals as principal performers and organizers, setting the stage for later public events centered on rulers.