Middle Bronze Age Arsenical Copper Alloys in Southern Portugal

In the Iberian Peninsula, the copper metallurgy from the Chalcolithic to the Middle Bronze Age (MBA) was mostly characterized by low arsenic contents. A collection of 53 MBA artefacts from southern Portugal was analysed by micro‐EDXRF, optical microscopy, SEM–EDS and Vickers to investigate the metal composition and manufacture. No technological distinction was found between artefacts from domestic and funerary contexts, which were radiocarbon‐dated to 2000–1500 cal bc . The arsenic contents of almost 100 MBA artefacts from this region, including the above‐mentioned set, have a Gaussian distribution with a high average (3.9 wt% As). Possible explanations are discussed for this distinctive metallurgy at the south‐western end of the Iberian Peninsula.     

Characterization of a Historical Cannonball from the Fortress of San Juan De Ulúa Exposed to a Marine Environment

Metallurgical analyses and chemical characterizations were carried out on historical cannonballs from the Fortress of San Juan de Ulúa, Veracruz, México. Cannonballs dating from the 18th and 19th centuries share metallurgical characteristics similar to those of material coming from a shipment of ammunition found in the wreck of a sunken French ship from the battle of Trafalgar. The analyses show that the base material is grey cast iron with a carbon equivalent of 4.94 and a ferritic–perlitic matrix, in which the high phosphorus content has led to the formation of iron phosphide compounds in conjunction with a homogeneous distribution of carbon graphite flakes of Type C. In addition, corrosion products from samples revealed the presence of various crystalline iron compounds (X‐ray diffraction), mostly highly chlorinated iron compounds identified as akaganeite. X‐ray fluorescence identified various characteristics of the corrosion products as a function of the sampling depth. FT–IR spectroscopy revealed that the main difference between the corrosion products (internal and external) is determined by the number of organic species. Differential scanning calorimetry corroborated that these corrosion products are thermally stable compounds at elevated temperatures.     

A Box Containing Carpenter's Accessories from The Akko 1 Shipwreck,Israel: Archaeometallurgical Analysis of Surviving Ironwork

The Akko 1 shipwreck was an Egyptian armed vessel, built at the beginning of the 19th century. A wooden saw handle and a box containing iron nails and two split pins were discovered towards the stern. Given their function, location and context, these were part of the ship's carpenter's tools and accessories. A methodology was developed for conducting systematic metallurgical analysis in order to understand the manufacturing process of the surviving ironwork items, as well as to enlarge our knowledge regarding ironworking technologies during the early 19th century. Such methodology may assist in the future understanding of the technological evolution of similar wrought‐iron objects. The results demonstrated that the artefacts have a wrought‐iron heterogeneous microstructure and were manufactured by hot‐working prior to surface hardening by pack carburization.     

ARRIVAL OF COURTLY LOVE: MOVING IN THE EMOTIONAL SPACE

Courtly love appeared in twelfth‐century Europe as a dissent from the emotional regime established by the Gregorian Reform, by setting the lady, instead of God, as the object of worship. From a game‐theory perspective, courtly love and hedonism correspond to Nash equilibria, in contrast to Christian marriage, whose stability is threatened by sex‐as‐appetite on one side and devotion to God on the other, and whose maintenance depends on moral control. The Church developed fear and shame, which are counter‐emotions to desire‐as‐appetite. Courtly love restored the thrill of forbidden adventure. It also shared traits common to innovations in the natural world: it added complexity (by increasing costs, emphasizing courtship, self‐restraint, and extremes of suffering); it was made possible by the plasticity of mating relationships; it introduced a small disorder in the ordered regime of Christian marriage; it demanded an adaptive effort, requiring the man to face ever more perilous trials and the woman to appear ever more attractive. Though obtained as a small deviation from the existing emotional regime, it had thoroughgoing and long‐lasting consequences for social control and for the political power of the Church. It also deeply modified the dynamic of longing in ego's representation. By taking the temporal form of a capture, it contrasts with twelfth‐century Bengal, where love was characterized by maintenance in an indefinitely repeating worship, by the absence of a here‐now versus target‐later dualism. It also contrasts with eleventh‐century Heian Japan, where love was intermingled with the melancholy of an impossible return, which is the antithesis of the concept of capture.     

LOCALIZATION AND INDUSTRY CLUSTERING ECONOMETRICS: AN ASSESSMENT OF GIBBS MODELS FOR SPATIAL POINT PROCESSES

The objective of this paper is to assess an approach to statistical modeling of point referenced establishment data that permit inclusion of “environmental” or establishment‐specific covariates and specific forms of interestablishment interaction. Gibbs models are used to decompose the conditional intensity of the spatial point process into trend and interaction components. The trend is composed of access measures (primarily different classes of roads) and three different interaction processes are tested: Geyer, area interaction, and Strauss hard core. While the models used have proved to be useful in ecology, we are unaware of any applications to establishment or firm data. In empirical application, the models yield intuitively appealing results for the trend component, and the ability to specify the interaction component gives deeper insights into interestablishment spatial dynamics than any previously published methods.     

COMMUTING TIME AND HOUSEHOLD RESPONSIBILITIES: EVIDENCE USING PROPENSITY SCORE MATCHING

We examine the relationship between individual commuting behavior and household responsibilities, with a focus on gender differences in that relationship. Using the Dutch Time Use Survey for the years 2000 and 2005, we analyze the relationship between commuting time, home production, and childcare. To deal with reverse causality, we use Propenstity Score Matching techniques to obtain imputed data for individuals. We find that the effect of home production on commuting time for women is more than double that for men, while childcare time has an effect on women's commuting behavior only. Our results shedding light on the Household Responsibility Hypothesis.     

The history of silver refining in New Spain, 16c to 18c: back to the basics

The refining of silver ores in New Spain was defined by the chemical nature of the silver ore. Argentiferous galena (lead sulphide) could only be refined by smelting (36% silver produced), irrespective of silver content, and amalgamation (64%) could only be applied to the silver sulphide ores. Both processes were transferred from Europe, but amalgamation was transformed by local expertise from a recipe of limited application to an industrial-scale solution for refining sulphidic silver ores. Its implementation shaped the environmental history of colonial silver refining in the New World. Mercury was consumed mainly through its chemical conversion into calomel, with minimal emissions of volatile mercury. Waste silt and liquid mercury in the soil and waterways were its main legacy. Smelting created a greater impact on the environment of New Spain, via lead in lead fumes as the main heavy metal issued to the air, and its depletion of woodlands. This article argues that a technical analysis of period refining practices in New Spain reorients our understanding of Spain’s imperial relations with its New World colonies, of the role of local knowledge in a global economy of silver production, and of environmental issues in colonial history. It thus speaks to the problem of unpacking the complex web of relations that composed early European imperialism, in which were enmeshed commodities such as silver, cotton and sugar.