The effect of pore size on cementation in porous rocks

Halite cementation in porous sandstone from the Lower Triassic Bunter Formation in North‐West Germany has been studied using measurements of porosity and permeability, before and after salt extraction, as well as from petrographic observations. The results show that in cemented sandstones there is a clear tendency for the larger pores to be halite‐filled while the smaller pores, which are responsible for the residual porosity, are left empty. Observations on cemented ‘pin‐stripe’ aeolian sandstones, in which laminations of fine and coarser sand grains alternate on a millimetre scale, indicate that this selective cementation is not due to differences in the brine composition in the pores. The implication, which is also supported by other observations, is that fluids in small pores can maintain a higher supersaturation with respect to crystallization.     

Transit Access for Americans: A Proposal for the Next Stage of Implementing the Americans With Disabilities Act of 1990

Formany Americans with disabilities, transit is the only path to real opportunities. An open society for them depends upon increased transit services for all Americans. Many transit professionals, however, daunted by transit needs and worn down by their critics, wallow in cost issues, ignoring transit's real value to their communities. The key to improvement is to measure transit benefits that are intuitively obvious to most taxpayers. Empirically, accessible transit proves to be the most valuable transit to passengers and to other taxpayers as well.     

Raman Spectroscopic Analysis of Ancient Egyptian Pigments

The application of FT‐Raman spectroscopy and visible Raman microscopy to the non‐destructive analysis of pigment specimens excavated from Tell el Amarna by Flinders Petrie in the 1890s has provided information about the chemical composition of the materials used by XVIIIth Dynasty artists in the New Kingdom at the time of King Akhenaten, c. 1340 bc. Comparison of the Raman spectra of the samples labelled ‘red and yellow ochre’ with documented, archival material from geological collections provided a clear indication of the materials used in the iron(III) oxide/hydroxide system, including α‐hematite, goethite, maghemite, magnetite and lepidocrocite. The yellow–orange specimen labelled ‘realgar’ proved to be a mixture of realgar and pararealgar; since the specimen had been sheltered from light since its excavation, this could indicate that the ancient Egyptian artists recognized the colour variation and may have used this to effect in their decorations. A specimen of yellow ochre contained goethite, α‐FeO.OH, with particles of crystalline, highly ordered graphite; in contrast, the red ochre specimens contained amorphous carbon particles.     

The influence of temperature on rehydroxylation [RHX] kinetics in archaeological pottery

Almost all archaeological ceramics undergo slow, progressive rehydroxylation by chemical combination with environmental water. The reaction is accompanied by an expansion, and also by the small but measurable mass gain that provides the basis of the RHX dating method. The rate of the RHX reaction increases with increasing temperature. Here we describe comprehensively the effects of temperature on the RHX process in relation to the dating methodology. We deal in turn with the kinetic model of the RHX reaction, the temperature dependence of the RHX rate, and the influence of varying environmental temperature on the RHX mass gain. We define an effective lifetime temperature and show how this is calculated from an estimated lifetime temperature history. Historical meteorological temperature data are used to estimate the lifetime temperature history, and this can be adjusted for long-term climate variation. We show also how to allow for the effects of burial in archaeological sites on the temperature history. Finally we describe how the uncertainties in estimates of RHX age depend on the estimates of temperature history and effective lifetime temperature.     

DNA analysis in charred grains of naked wheat from several archaeological sites in Spain

In the present work we attempt to recover endogenous ancient DNA from cereal grains preserved under different conditions: charred, partially charred and waterlogged. A total of 126 grains from naked wheat and 18 from barley from different sites on the Eastern Iberian Peninsula ranging from the beginning of agriculture in the region to the turn of the Common Era, were studied. Two different extraction protocols were used, a standard phenol–chloroform method and a silica-based DNA extraction procedure implemented for artificially charred seeds. Amplifications were directed to three markers: the large subunit of ribulose 1,5 biphosphate carboxylase (rbcL) and the microsatellite WCT12 in the chloroplast genome and the x and y subunits of the high molecular weight glutenin gene (Glu-1) in the nucleus. The first two were used to assess the preservation status of the samples, while with the third we tried to identify the wheat grains at species level. It was possible to obtain eleven positive amplifications in 8 partially charred seeds but only two amplifications of the Glu-1 gene from a single sample of the Early Bronze age were genome-specific. Different contamination sources were identified and reported. Cloning and alignment of sequenced clones showed a correspondence of the amplified fragment to modern wheat D genome haplotypes. This result suggests that the sample corresponds to hexaploid wheat (Triticum aestivum L.), thus being the first ancient DNA evidence to date for the cultivation of hexaploid wheat in the prehistoric agriculture of the Iberian Peninsula. Moreover, obtained results highlight contamination problems associated to the study of ancient archaeobotanical charred seeds suggest that the combination of a silica-based extraction method together with the amplification of specific targets is a good strategy for recovering endogenous ancient DNA from this kind of material.     

Palynological study of a Mi'kmaw shell midden,Northeast Nova Scotia,Canada

Before now, no palynological studies were made on shell midden deposits in Nova Scotia, despite a long history of archaeological research. A test study of samples taken from the shell midden at Maligomish (Indian Island) on the Northumberland Strait was conducted to determine if sufficient pollen, fern and moss spores, and other non-pollen palynomorphs (NPP's, including fungal remains, algal spores) could be recovered to allow interpretation of environmental conditions at the time of deposition. Several pollen processing methods were tested: sieving and swirling, chemical treatment with cold HCl, 5% KOH and brief exposure to 5% NH₄OH, and treatment with acetolysis solution. We recovered variable amounts of pollen, spores and NPP's from samples taken at 3–5 cm, 5–15 cm and 15–25 cm below surface. Abundant microcharcoal fragments prevented effective use of the swirling technique, but sufficient palynomorphs were recovered by chemical treatments to allow assessment of down-section changes in assemblages. Three radiocarbon ages from Mya arenaria and Crassostrea sp., and measurements of sediment grain size, moisture, organic and inorganic carbon, provide a framework for analysing palynological assemblage changes and context for interpreting differential palynomorph preservation. Despite some oxidation and microbial degradation of palynomorphs in the time interval (ca. 380–1600 cal yr BP), the midden assemblages correlate with pollen zones from marine and lake core sites within ca. 50 km of Maligomish. Shifts in abundances of algal spores, testate amoebae and aquatic plant pollen also indicate changes in depositional conditions during the time of midden use. The study provides the first reference for archaeologists attempting to use palynology for analysis of samples from Nova Scotian shell-bearing contexts.