SYNCHROTRON FTIR MICRO‐SPECTROSCOPY APPLIED TO THE STUDY OF POLISHED SERPENTINITE ARTEFACTS: A NON‐DESTRUCTIVE ANALYTICAL APPROACH

In prehistory, serpentinite was one of the most frequently used raw materials to produce polished stone artefacts. Several conventional analytical techniques can be applied to identify the serpentine minerals, but their application generally requires a powdered sample. This implies that the artefacts to be analysed must be damaged, and the possibility of analysing a mixture of different serpentine polytypes is high. The use of spatially resolved techniques is therefore a necessity to overcome this problem. Several thin sections of serpentinitic rocks and prehistoric axes have been analysed by synchrotron radiation Fourier transform infrared micro‐spectroscopy. The spectra were acquired directly on specific points of polished stone artefacts and this allowed the recognition of the different polytypes of serpentine minerals without causing any damage to the objects. The results show the infrared micro‐spectroscopy technique to be a useful tool for the characterization of archaeological lithic material.     

A PROVENANCE STUDY OF FRENCH LIMESTONE BASED ON VARIABLE SELECTION FROM COMPOSITIONAL PROFILES

The present study shows how multivariate analysis and variable selection techniques can be used in archaeological provenances studies to improve classification performances. Neutron activation analysis (NAA), in combination with stepwise linear discrimination analysis (SLDA) (capable of simultaneously performing variable selection and classification), was applied to differentiate among limestone samples from different quarries across the north of France based on their compositional fingerprint. A hierarchical classification approach was followed, aimed at progressively assigning limestone samples to more specific sources of origin, from the broadest classification units (French regions) to the narrowest ones (individual quarries). The application of the stepwise variable selection procedure to extract the most discriminating compositional variables prior to each classification development allowed us to obtain a perfect separation between the limestone categories considered at every classification stage (all samples were correctly classified and predicted in all cases). The high‐quality results obtained were even more remarkable considering the relatively small number of significant variables selected in each case using the SLDA method. An illustrative example was provided in order to demonstrate that the classification strategy proposed can actually allocate an unknown sculpture to a particular quarry of origin.     

NON‐DESTRUCTIVE CHEMICAL ANALYSIS OF OLD SOUTH ARABIAN COINS,FOURTH CENTURY BCE TO THIRD CENTURY CE

Studies on Old South Arabian (OSA) coinage are rare and state‐of‐the‐art materials analysis for them lags far behind that of ancient Greece and Rome. Understandably, numismatists responsible for preserving their collections discourage destructive analyses. We have selected coins of the aesthetically and technically developed Himyarite Royal Raydan series (early first to late second century ce ), so‐called Old and New Style Athenian Imitations, among others to provide a wide spectrum of information on OSA coinage. We used non‐destructive neutron diffraction to ascertain the metal compositions and corrosion products. Density determinations using gas‐pycnometry support these experiments. The results provide detailed information with regard to a small, apparently homogeneous, selection of 10 Himyarite period specimens and first insights into the actual and the original metal compositions of about 90 coins of the three main OSA numismatic groups. The analytical results make clear which OSA coins originally were struck and which ones were cast. The analyses provide not only detailed information concerning the manufacture of the selected representative coins, but also suffice to cast a shadow on the reliability of commonplace macro‐optical classification, which proves often to be inaccurate.     

ASSESSING NATURAL CLAY COMPOSITION IN THE VALLEY OF OAXACA AS A BASIS FOR CERAMIC PROVENANCE STUDIES

The Oaxaca Clay Survey was initiated to provide baseline data on clay composition within the Valley of Oaxaca, Mexico, to assist in provenance determination of prehistoric ceramics. Natural clays were sampled from 135 locations throughout the valley, and analysed using INAA in combination with ceramic petrography. Observed geographical trends in trace‐element and mineralogical composition confirm that while parent material (surficial geology) strongly affects clay composition, a continuum of variation exists within the valley. The study develops and tests a continuous spatial model of clay composition that provides greater resolution in ceramic sourcing than bedrock alone. By establishing a regional framework for Oaxaca Valley clays, the survey will support significant advances in our understanding of pottery production and exchange within the valley, and provide a more robust means for monitoring exchange between the valley and neighbouring regions.     

The notion τὸ πέρας τῆς ἀνακομιδῆς and the location of Ptolemais of the Hunts in the Periplus of the Erythraean Sea

The Periplus of the Erythraean Sea describes the route of a trade ship in the ancient Erythraean Sea following certain reference points. One of these was called τ? π?ρα? τ?? ?νακομιδ??, from which the distance to Ptolemais of the Hunts was given. It was generally understood as the ‘endpoint of return’ and thought to be Berenice. In fact, the phrase is to be understood as ‘the endpoint of sailing/delivery from (Egypt)’ and the place appears to be identifiable with modern Anfile Bay, where the trade ships turned back. The port itself had to be visited on the way back to Egypt. The reason was connected with the primary goal of the establishment of the port: it was much more practical to take elephants aboard on the way back to Egypt. The information on Ptolemais of the Hunts seems to derive from a late Ptolemaic source. The exact route of the ship, referred to by the author of the Periplus, is unknown and even knowledge of the exact distance from the reference point does not allow us to identify a region, where Ptolemais of the Hunts is to be sought.