Recent Hydrological Changes in the Avoca River Catchment,Victoria

Since the early 1970s the Avoca River catchment has experienced a marked increase in all discharges, particularly high magnitude ones. This results from a change in the rainfall/runoff relationship, which is probably due to rising groundwater tables. Since 1973 the frequency of flooding in the lower Avoca, Loddon and Avon-Richardson catchments has increased markedly, placing pressure on downstream flood mitigation and irrigation works, as well as contributing to the degradation of environmentally sensitive wetlands. It also has the potential to exacerbate rising groundwater/salinity problems of the lower catchments. Human interference and changes in the rainfall regime are assessed to explain the nature of the apparent change in streamflows of the Avoca River catchment.     

THE BLUE ENAMELS IN THE BAROQUE DECORATIONS OF THE CHURCHES OF PALERMO,SICILY: FE2+‐COLOURED GLASSES FROM LIME KILNS*

Deep blue glasses coloured by octahedral Fe²⁺ cations are often reported as textbook examples of blue pigmentation. However, despite the possibility of laboratory synthesis under reducing conditions, to date there are no well‐reported occurrences of their production and use in the past. A thorough historical, ethnographic, mineralogical, and chemico‐physical investigation of the ‘smaltini di calcara’ from several baroque churches in Palermo, Sicily, has revealed that the blue enamels widely used for altar decorations in the 17th and 18th centuries are actually a unique case of ancient blue glasses pigmented by divalent iron cations in distorted octahedral coordination. This mixed‐alkali glass was accidentally produced under severely reducing conditions in the local kilns during production of lime.