Opacifiers in Late Bronze Age glasses: the use of ToF-SIMS to identify raw ingredients and production techniques

Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) is applied to the study of four samples of opaque glass of Late Bronze Age date. The technique is uniquely capable of identifying compositional heterogeneity at a sub-micron resolution within the crystalline opacifiers dispersed through homogeneous glass matrices. It is shown that this provides crucial information on the possible raw ingredients of the opacifying inclusions used, and has the potential for highlighting regional variations in the production technology involved in creating different colours of opaque glass.     

Provenance of Zhangzhou export blue-and-white and its clay source

Trace element compositions of 25 shards of Chinese Late Ming export blue-and-white porcelain from Zhangzhou and Jingdezhen kilns are analysed by Inductively Coupled Plasma Mass Spectrometry. Principle components analysis and REE distribution curves are used to establish method for provenance unknown Chinese export blue-and-white porcelain which may have originated from Zhangzhou or Jingdezhen kilns. By matching the REE distribution curves of Zhangzhou kiln samples and parent rocks of the possible clay sources used to make Zhangzhou blue-and-white, and comparing it with previous results of geological, geochemical and archaeological researches, the clay used for producing Zhangzhou export blue-and-white has been identified as having been collected from the weathered shells of a nearby potassium feldspar miarolitic granite outcrop.     

First comprehensive peat depositional records for tin,lead and copper associated with the antiquity of Europe's largest cassiterite deposits

Tin, as a constituent of bronze, was central to the technological development of early societies, but cassiterite (SnO₂) deposits were scarce and located distantly from the centres of Mediterranean civilizations. As Britain had the largest workable ore deposits in the ancient Western world, this has led to much historical speculation and myth regarding the long-distance trading of tin from the Bronze Age onwards. Here we establish the first detailed chronology for tin, along with lead and copper deposition, into undisturbed ombrotrophic (rain-fed) peat bogs located at Bodmin Moor and Dartmoor in the centre of the British tin ore fields. Sustained elevated tin deposition is demonstrated clearly, with peaks occurring at 100–400 and 700–1000 calendar years AD – contemporaneous with the Roman and Anglo-Saxon periods respectively. While pre-Roman Iron Age tin exploitation undoubtedly took place, it was on a scale that did not result in convincingly enhanced deposition of the metal. The deposition of lead in the peat record provides evidence of a pre-Roman metal-based economy in southwest Britain. Emerging in the 4th century BC, this was centred on copper and lead ore processing that expanded exponentially and then collapsed upon Roman colonization during the 1st century AD.     

The Eleventh- and Twelfth-century Waterfront and Settlement at Queenhithe: Excavations at Bull Wharf,City of London

Evidence for the development of London’s riverside settlement c. AD 1000–1200 was found on the east edge of an important dock known successively as Æthelred’s hithe and Queenhithe. A sequence of embankments and tree-ring dated revetments advanced the waterfront nearly 40 m into the Thames and small inlets provided access to the foreshore. Building and rebuilding took place on a row of properties, with up to a dozen buildings identified; after c. 1150, passages were created for two narrow lanes connecting Thames Street with the quays and foreshore. Important reused building and ships’ timbers and dated groups of metalwork and other artefacts were recovered from the waterfronts.     

Reflections on Collaborative Archaeology and Large-Scale Online Research Infrastructures

ABSTRACT

The Archaeology Data Service (ADS) is an archive working at a national level in the UK, ensuring that archaeologists have access to high quality and dependable digital resources, including openly licensed legacy data for reuse. The ADS acts as a metadata aggregator for archaeological data held by larger heritage agencies and smaller regional organizations and participates in international aggregation infrastructure projects such as ARIADNE, which allows users to access archaeological resources held in many countries from a single interface. Large-scale infrastructures can facilitate the building of long-term, complex relationships and active collaborations, not just technical solutions. This paper reflects on the roles of stewardship and equity within ARIADNE and the ADS, two large-scale online research infrastructures, and how these types of infrastructures may help to create a more collaborative archaeology, including lessons learned, challenges and opportunities, and thoughts for the future.     

Different glassmaking technologies in the production of Iron Age black glass from Italy and Slovakia

This study presents the results of an archaeometrical investigation performed on 75 black glass beads dated to the ninth–fifth century BC coming from Bologna, Cumae, and Pozzuoli (Italy), and Chotin (Slovakia). The analyses of the major, minor, and trace elements—as well as that of Sr and Nd isotopes performed on a selection of samples coming from Bologna—provided evidence for two different production technologies in Iron Age black glass found in Italy (natron glass, probably produced in Egypt) and Slovakia (wood ash glass, probably produced in Europe). In both cases, the glasses derive their black colouration from the high presence of iron (around 12 % FeO), introduced into the glass batches through the intentional choice of dark sands. The production model appears to be small-scale and experimental, characterised by the use of non-sorted raw materials and poorly defined formulae, producing glass with a high chemical variability. The wood ash technology appears to have dropped out of use in Europe until the Medieval period, while natron production spread quickly, becoming predominant throughout the Mediterranean.