Fracture mineralization and fluid flow evolution: an example from Ordovician–Devonian carbonates,southwestern Ontario,Canada

Petrography, geochemistry (stable and radiogenic isotopes), and fluid inclusion microthermometry of matrix dolomite, fracture‐filling calcite, and saddle dolomite in Ordovician to Devonian carbonates from southwestern Ontario, Canada, provide useful insights into fluid flow evolution during diagenesis. The calculated δ¹⁸O_fluid, ΣREE, and REE_SN patterns of matrix and saddle dolomite suggest diverse fluids were involved in dolomitization and/or recrystallization of dolomite. The ⁸⁷Sr/⁸⁶Sr ratios of dolomite of each succession vary from values in the range of coeval seawater to values more radiogenic than corresponding seawater, which indicate diagenetic fluids were influenced by significant water/rock interaction. High salinities (22.4–26.3 wt. % NaCl + CaCl₂) of Silurian and Ordovician dolomite–hosted fluid inclusions indicate involvement of saline waters from dissolution of Silurian evaporites. High fluid inclusion homogenization temperatures (>100°C) in all samples from Devonian to Ordovician show temperatures higher than maximum burial (60–90°C) of their host strata and suggest involvement of hydrothermal fluids in precipitation and/or recrystallization of dolomite. A thermal anomaly over the mid‐continent rift during Devonian to Mississippian time likely was the source of excess heat in the basin. Thermal buoyancy resulting from this anomaly was the driving force for migration of hydrothermal fluids through regional aquifers from the center of the Michigan Basin toward its margin. The decreasing trend of homogenization temperatures from the basin center toward its margin further supports the interpreted migration of hydrothermal fluids from the basin center toward its margin. Hydrocarbon‐bearing fluid inclusions in late‐stage Devonian to Ordovician calcite cements with high homogenization temperatures (>80°C) and their ¹³C‐depleted values (approaching ?32‰ PDB) indicate the close relationship between hydrothermal fluids and hydrocarbon migration.     

In situ decarboxylation of acetic and formic acids in aqueous inclusions as a possible way to produce excess CH4

Accurate reconstruction of diagenetic P‐T conditions in petroleum reservoirs from fluid inclusion data relies on valid measurements of methane concentration in aqueous inclusions. Techniques have been developed (Raman spectrometry) to provide sufficiently accurate data, assuming measured methane concentration has not been modified after aqueous inclusion entrapment. This study investigates the likelihood that organic acids derived from petroleum fluids and dissolved in formation water might suffer decarboxylation upon postentrapment heating within the fluid inclusion chamber, thereby generating excess CH₄ in the inclusions. Four different experiments were conducted in fused silica capillary capsules (FSCCs), mimicking fluid inclusions. The capsules were loaded with acetic (CH₃COOH) or formic (HCOOH) acid solution and were heated to 250°C for short durations (<72 h) in closed‐system conditions, with or without applying a fixed P_H2. Reaction products were characterized by Raman and FT‐IR spectrometry. Results indicate that decarboxylation reactions did take place, at variable degrees of progress, and that measurable excess CH₄ was produced in one experiment using acetic acid. This suggests that methane may be produced from dissolved organic acids in natural aqueous inclusions in specific situations, possibly inducing errors in the thermodynamic interpretation.     

Railway development as Symbolising ideas of social construction: (With Special Reference to Railway Development in Australia)

The townscape of “old” Lerwick reflects its traditional focus on the sea for its economic base. The major elements in this cohesive visual character are the closely clustered houses in the steep hillside district of the Lanes, the narrow, winding principal commercial street, and the lodberries projecting out into the harbour. The latter were constructed to meet the needs of the prosperous expanding trade period of the latter half of the 18th century and first half of the 19th century. Harbour improvements in the final quarter‐century of the 1800s ended their commercial usefulness. After a century of declining use and of neglect they are being restored as part of the renewal of “old town” Lerwick.     

The deserts of the Kashmir‐Tibetan frontier

Abstract

Semi-arid landscapes are vulnerable to cultivation, overgrazing and climate variability, although it is difficult to identify the relative significance of these three factors. In the South African Karoo, the ‘desertification debate' seeks to explain a change to more shrubby vegetation in heavily grazed areas. We examine these issues in catchments where farm reservoirs provide sediment stores with 137Cs, 210Pb, geochemical and mineral magnetic signatures. Rainfall data and stocking numbers are reported and current erosion rates are estimated. Sediment accumulation in the reservoirs increases between 1935 and 1940, probably due to rises in the frequency of rainfall events of >25mm day. Significant increases in sedimentation rates (×8) occur during rain-fed wheat cultivation. In an uncultivated catchment, sediment yields remain relatively high and reflect increases in erosion from hillslopes, colluvial storage, and cultivated land sources. Gully systems have acted as transport routes rather than sediment sources over the last ～70 years. Badland erosion rates average ca. 50t ha^?1 yr^?1. At Ganora, their development in the 1920s strongly influences peak sedimentation between 1970 and 1980. Any delay between badland initiation and increased sediment yield appears to be a function of landscape connectivity. Recovery following disturbance is occurring slowly and is likely to take >100 years. De-stocking and better management systems are reducing erosion rates but may be offset by increases in rainfall intensity.     

Study of the Climatic Resources of the USSR and their Economic Utilization

A combination of cheap natural gas and hydroelectric power resources makes Central Asia a promising site for the development of energy- oriented industries such as chemicals and light metals. The author shows that it is more economical to produce power-consuming products in Central Asia than to transmit cheap gas and electricity to other parts of the USSR.     

Review and Discussion of V. A. Anuchin'S Book on Theory of Geography

Following are a review and a discussion of V. A. nuchin's controversial book Teoreticheskiye problemy geografii (Theoretical Problems of Geography), Moscow: Geographical Publishing House, 1960, 264 pp. The table of contents of this book was translated in Soviet Geography, March 1961, p. 88.     

Moisture Circulation and its Role in Natural Processes

Because of defects of the present land-inventory system in the USSR, a more comprehensive land-cadastre system is proposed, making possible an economic appraisal of lands based on soil, geobotanical and agricultural-capability maps and other land data. Such a cadastre would enable authorities to judge the economic effectiveness of any given land use on the basis of costs and yields. The paper was prepared with the assistance of K. V. Zvorykin, P. A. Letunov and staff members of Gosplan USSR, the Moscow Land-Organization Institute, and the Soil Institute named for V. V. Dokuchayev.