The Effect of NAFTA on Energy and Environmental Efficiency in Mexico

Prior to Mexico's entry to the North American Free Trade Agreement (NAFTA), predictions of the consequent impact on the environment in that country ranged from the dire to very optimistic. This article investigates NAFTA's outcomes in terms of energy use and the emission of atmospheric pollutants. Specifically, has entry into NAFTA led to a convergence or divergence in indicators of emissions, environmental efficiency, and emissions‐specific technology in Mexico, the United States, and Canada? A battery of tests is applied to these indicators for energy use and carbon, sulfur, and NOx emissions in the three countries. The results show that the extreme predictions of the outcomes of NAFTA have not materialized. Rather, trends that were already present before the introduction of NAFTA continue and, in some cases, improve post‐NAFTA, but not yet in a dramatic way. There is strong evidence of convergence across the three countries toward a lower intensity of energy use and emissions per unit of GDP. Although intensity is rising initially for some variables in Mexico, it eventually begins to fall post‐NAFTA. Per capita emissions of sulfur and NOx also show convergence, but this is not the case for energy and carbon, and the latter variables also drift moderately upwards. The state of technology in energy efficiency and sulfur abatement is improving in all countries, although there is little, if any, sign of convergence and NAFTA has no effect on the rate of technology diffusion. However, total energy use and carbon emissions increase both pre‐ and post‐NAFTA and total NOx emissions increase in Mexico. Only total sulfur emissions are stable and falling in all three NAFTA partners.     

Bone diagenesis in the European Holocene II: taphonomic and environmental considerations

We have applied cluster analysis to mercury intrusion porosimetry data from 219 archaeological bones (121 human and 98 animal) and soil chemistry data from 219 accompanying soil samples (1 per bone sample), to investigate the influence of soil chemistry on bone preservation. The samples chosen for the study were obtained from sites ranging in time from the pre-modern to the Mesolithic and were representative of burial environments across Europe (from the Baltic to the Mediterranean). These results represent the single largest database for archaeological bone preservation in the European Holocene to date and demonstrate the potential for large-scale diagenetic studies to help develop long term preservation strategies for our European heritage. Despite the variety of sites and environments, bones could be categorised into only four main diagenetic types. Furthermore, soil chemistry appears to significantly affect only one type of preservation, the pathway characterised by loss of mineral. In neutral to basic soils, taphonomy and in particular the differences between the treatment of human and animal remains, becomes the dominating factor in determining preservation. Using these results, strategies for heritage management of archaeological sites can be suggested; grouping sites into those requiring immediate excavation and those where in situ preservation is viable.     

Hybrid finite element–finite volume discretization of complex geologic structures and a new simulation workflow demonstrated on fractured rocks

The generation of computational meshes of complex geological objects is a challenge: their shape needs to be retained, resolution has to adapt to local detail, and variations of material properties in the objects have to be represented. Also mesh refinement and adaptation must be sufficient to resolve variations in the computed variable(s). Here, we present an unstructured hybrid finite element, node‐centred finite‐volume discretization suitable for solving fluid flow, reactive transport, and mechanical partial differential equations on a complex geometry with inhomogeneous material domains. We show that resulting meshes accurately capture free‐form material interfaces as defined by non‐uniform rational B‐spline curves and surfaces. The mesh discretization error is analysed for the elliptic pressure equation and an error metric is introduced to guide mesh refinement. Finite elements and finite volumes are represented in parametric space and integrations are conducted numerically. Subsequently, integral properties are mapped to physical space using Jacobian transformations. This method even retains its validity when the mesh is deformed. The resulting generic formulation is demonstrated for a transport calculation performed on a complex discrete fracture model.