Polyphasic hydrothermal and meteoric fluid regimes during the growth of a segmented fault involving crystalline and carbonate rocks (Barcelona Plain,NE Spain)

A polyphasic tectonic‐fluid system of a fault that involves crystalline and carbonate rocks (Hospital fault, Barcelona Plain) has been inferred from regional to thin section scale observations combined with geochemical analyses. Cathodoluminescence, microprobe analyses and stable isotopy in fracture‐related cements record the circulation of successive alternations of hydrothermal and low‐temperature meteoric fluids linked with three main regional tectonic events. The first event corresponds to the Mesozoic extension, which had two rifting stages, and it is characterized by the independent tectonic activity of two fault segments, namely southern and northern Hospital fault segments. During the Late Permian‐Middle Jurassic rifting, these segments controlled the thickness and distribution of the Triassic sediments. Also, dolomitization was produced in an early stage by Triassic seawater at shallow conditions. During increasing burial, formation of fractures and their dolomite‐related cements took place. Fault activity during the Middle Jurassic–Late Cretaceous rifting was localized in the southern segment, and it was characterized by hydrothermal brines, with temperatures over 180°C, which ascended through this fault segment precipitating quartz, chlorite, and calcite. The second event corresponds to the Paleogene compression (Chattian), which produced exhumation, folding and erosion, favouring the percolation of low‐temperature meteoric fluids which produced the calcitization of the dolostones and of the dolomite cements. The third event is linked with the Neogene extension, where three stages have been identified. During the syn‐rift stage, the southern segment of the Hospital fault grew by tip propagation. In the relay zone, hydrothermal brines with temperature around 140°C upflowed. During the late postrift, the Hospital fault acted as a unique segment and deformation occurred at shallow conditions and under a low‐temperature meteoric regime. Finally, and possibly during the Messinian compression, NW‐SE strike‐slip faults offset the Hospital fault to its current configuration.     

Role of compressive tectonics on gas charging into the Ordovician sandstone reservoirs in the Sbaa Basin,Algeria: constrained by fluid inclusions and mineralogical data

Structure‐ and tectonic‐related gas migration into Ordovician sandstone reservoirs and its impact on diagenesis history were reconstructed in two gas fields in the Sbaa Basin, in SW Algeria. This was accomplished by petrographical observations, fluid inclusion microthermometry and stable isotope geochemistry on quartz, dickite and carbonate cements and veins. Two successive phases of quartz cementation (CQ1 and CQ2) occurred in the reservoirs. Two phase aqueous inclusions show an increase in temperatures and salinities from the first CQ1 diagenetic phase toward CQ2 in both fields. Microthermometric data on gas inclusions in quartz veins reveal the presence of an average of 92 ± 5 mole% of CH₄ considering a CH₄‐CO₂ system, which is similar to the present‐day gas composition in the reservoirs. The presence of primary methane inclusions in early quartz overgrowths and in quartz and calcite veins suggests that hydrocarbon migration into the reservoir occurred synchronically with early quartz cementation in the sandstones located near the contact with the Silurian gas source rock at 100–140°C during the Late Carboniferous period and the late Hercynian episode fracturing at temperatures between 117 and 185°C, which increased in the NW‐direction of the basin. During the fracture filling, three main types of fluids were identified with different salinities and formation temperatures. A supplementary phase of higher fluid temperature (up to 226°C) recorded in late quartz, and calcite veins is related to a Jurassic thermal event. The occurrence of dickite cements close to the Silurian base near the main fault areas in both fields is mainly correlated with the sandstones where the early gas was charged. It implies that dickite precipitation is related to acidic influx. Late carbonate cements and veins (calcite – siderite – ankerite and strontianite) occurred at the same depths resulting from the same groundwater precipitation. The absence of methane inclusions in calcite cements result from methane flushing by saline waters.     

Isotopic Composition of Lead in Copper Ores and a Copper Artefact from the La Profunda Mine (León,Spain)

This paper continues the characterization of the lead isotopic fingerprint of ancient copper mines in the north‐west of Spain. In this work, the lead isotopic compositions found in copper ores from the La Profunda mine are presented. Azurites and malachites sampled from this deposit were subjected to lead isotope analysis by multicollector ICP–MS. The results showed a clear radiogenic lead signature compatible with the presence of uranium‐rich minerals (such as zeunerite) in the same mining complex. Moreover, a rare copper artefact, found in the galleries of the mine during its modern exploitation, was also analysed and showed that local mineral was used for its manufacturing.     

Prisons and incarceration in fourteenth-century Venetian Crete

Though the evolution of prisons and the prison system in medieval Europe is a well-developed field in the history of law, little attention has been paid to prisons and incarceration on the frontiers of Latin Christendom. The present study makes use of archival and literary sources in order to examine how prisons functioned in Venice's most important colony, the island of Crete. As there has been no previous study of prisons and incarceration in medieval Greece, the article's first aim is to establish some basic facts about the prisons of Crete, such as their locations, their organization and their system of administration. More importantly, however, the study investigates the role that incarceration played in the legal system of the Venetian colony and attempts to set this role within the context of the juridical developments of the Late Middle Ages. Of particular interest is the question of how closely the legal system of the Venetian colony followed the judicial practice of the metropolis and whether it was influenced by the pre-existing legal institutions of Byzantium. Finally, the study also examines how the jurisprudence of the colonial regime dealt with offenders of different ethnic background and legal status.     

ANALCIME CRYSTALLIZATION AND COMPOSITIONAL PROFILES—COMPARING APPROACHES TO DETECT POST‐DEPOSITIONAL ALTERATIONS IN ARCHAEOLOGICAL POTTERY*

The approaches of comparative studies and profile measurements, often used in order to detect post‐depositional alterations of ceramics, have been applied simultaneously to two sets of Roman pottery, both of which include altered individuals. As analytical techniques, Neutron Activation Analysis and X‐Ray Diffraction have been used. Both approaches lead to substantially different results. This shows that they detect different levels of alteration and should complement each other rather than being used exclusively. For the special process of a glassy phase decomposition followed by a crystallization of the Na‐zeolite analcime, the results suggest that it changes high‐fired calcareous pottery rapidly, and so fundamentally that the results of various archaeometric techniques can be severely disturbed.     

THE PROVENANCE AND TECHNOLOGY OF NEAR EASTERN GLASS: OXYGEN ISOTOPES BY LASER FLUORINATION AS A COMPLEMENT TO STRONTIUM*

The ability to make rapid measurements on small samples using laser fluorination enhances the potential of oxygen isotopes in the investigation of early inorganic materials and technologies. δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values are presented for glass from two primary production sites, four secondary production sites and a consumer site in the Near East, dating from Late Antiquity to the medieval period. δ¹⁸O is in general slightly less effective than ⁸⁷Sr/⁸⁶Sr in discriminating between sources, as the spread of measured values from a single source is somewhat broader relative to the available range. However, while ⁸⁷Sr/⁸⁶Sr is derived predominantly from either the lime‐bearing fraction of the glass‐making sand or the plant ash used as a source of alkali, δ¹⁸O derives mainly from the silica. Thus the two measurements can provide complementary information. A comparison of δ¹⁸O for late Roman – Islamic glasses made on the coast of Syria–Palestine with those of previously analysed glasses from Roman Europe suggests that the European glasses are relatively enriched in ¹⁸O. This appears to contradict the view that most Roman glass was made using Levantine sand and possible interpretations are discussed.