A LYONS BRANCH OF THE POTTERY-MAKING FIRM OF ATEIUS OF AREZZO

Fifty-one waster sherds of Terra Sigillata (～20-0 b.c. ) from Arezzo, Italy and Lyons, France have been chemically analysed for twenty-eight elements by neutron activation and seven by X-ray fluorescence. Most of the elemental abundances were measured with high precision and cross-comparisons of the two techniques of measurement (and sample preparation) give added insight as to their relative precision, the calibration differences and the extent to which volatile materials such as carbonate or water influence the results. The sherds from Arezzo formed a homogeneous and distinctive chemical group while all but two of those from Lyons were classified into three such groups. Two of the Lyons groups (MML A and MML B) were from Montée de La Muette and one was from Loyasse. Four additional sherds from houses excavated in Strasbourg and one from Lyons, all of which bore the signature of the famous Anetine pottery-making firm of Ateius, were also analyzed by the same techniques. These signed sherds all had the same composition pattern and it closely matched one of those from Montée de La Muette (MML A) in Lyons. It is therefore suggested that these five sherds bearing the Ateius signature were made in the general vicinity of Lyons and were part of the output of an as yet unknown Gallic branch of the firm of Ateius.     

Looking for Ancient Fish Products Through Invisible Biomolecular Residues in the Roman Production Vats from the Atlantic Coast

As organic materials, fish and its derivative products are perishable and break down rapidly and ultimately disappear. Unless they include bones or scales, the only means of identifying them in the archaeological record is through the identification of the chemical constituents that are left behind after decomposition. Fish flesh mainly consists of proteins and lipids. Since these molecules are unstable they degrade irreversibly after death or discard, losing a significant part of the original chemical elements, consequently hampering or complicating their identification. In this paper, two main types of fish products are considered: raw, salted or cooked fish, and fermented fish-based products. In the first case, the degradation of the native markers results from chemical post-depositional degradation, and eventually thermal degradation during cooking. In the second case, the biochemical processes involve bacteria that cause the rapid decomposition of fish as part of the process of forming fish sauces, such as Roman garum. To detect and identify fish products we combined experimental archaeology and organic analyses. The identification of the degradation products of cholesterol appeared to provide a strong indicator for detecting the presence of fish sauces. Analysis of samples taken from fish-salting vats located along the Atlantic coast (Marsa, Baelo Claudia, Troia, Kerlaz, and Etel) with samples taken from actual experimental garum sauces made from mackerel (Scomber scombrus), sardines (Sardina pilchardus), and/or oysters (Ostreidae), revealed the presence of common markers of fermented fish-based products. The application of the analytical methodology described here to structures involved in ancient fish sauce manufacture and storage has enabled investigation of the production of the sauces by searching directly for the fish markers on the inner sides of the containers. For the first time the addition of molluscs and fruits in the fish product has been identified as part of the process of manufacturing garum.     

Updating Numerical Models of Masonry Arch Bridges by Operational Modal Analysis

This article aims at presenting and discussing the strategies for updating the finite element numerical modeling of stone masonry arch bridges using operational modal analysis. The study comprehended three bridges: two old ones, the St. Lázaro and the Lagoncinha bridges, and a recently constructed bridge in Vila Fria, Portugal. Updating of the bridge models is performed by comparing the numerical and experimental modal parameters. Three-dimensional detailed numerical models are used to perform modal analysis of the bridges. Experimental modal identification of the bridges is based on the measurement of their acceleration responses during normal operation. The assigned material properties are also based on available results obtained from in situ and laboratory tests and on the results of visual inspection and historical research carried out for both old bridges.     

Hydraulic and hydrochemical properties of deep sedimentary reservoirs of the Upper Rhine Graben,Europe

Hydraulic and hydrochemical data from several hundred wells mostly drilled by the oil and gas industry within the four deep carbonate and siliciclastic reservoirs of the Upper Rhine Graben area in France and Germany have been compiled, examined, validated and analysed with the aim to characterize fluids and reservoir properties. Due to enhanced temperatures in the subsurface of the Upper Rhine Graben, this study on hydraulic and hydrochemical properties has been motivated by an increasing interest in deep hydrogeothermal energy projects in the Rhine rift valley. The four examined geothermal reservoir formations are characterized by high hydraulic conductivity reflecting the active tectonic setting of the rift valley and its fractured and karstified reservoirs. The hydraulic conductivity decreases only marginally with depth in each of the reservoirs, because the Upper Rhine Graben is a young tectonically active structure. The generally high hydraulic conductivity of the reservoir rocks permits cross‐formation advective flow of thermal water. Water composition data reflect the origin and hydrochemical evolution of deep water. Shallow water to 500 m depth is, in general, weakly mineralized. The chemical signature of the water is controlled by fluid–rock geochemical interactions. With increasing depth, the total of dissolved solids (TDS) increases. In all reservoirs, the fluids evolve to a NaCl‐dominated brine. The high salinity of the reservoirs is partly derived from dissolution of halite in evaporitic Triassic and Cenozoic formations, and partly from the fluids residing in the crystalline basement. Water of all four reservoirs is saturated with respect to calcite and other minerals including quartz and barite.     

The Multiple Testing Issue in Geographically Weighted Regression

This article describes the problem of multiple testing within a Geographically Weighted Regression framework and presents a possible solution to the problem which is based on a family‐wise error rate for dependent processes. We compare the solution presented here to other solutions such as the Bonferroni correction and the Byrne, Charlton, and Fotheringham proposal which is based on the Benjamini and Hochberg False Discovery Rate. We conclude that our proposed correction is superior to others and that generally some correction in the conventional t‐test is necessary to avoid false positives in GWR.     

Late Bronze Age Copper Smelting Slags from Luserna (Trentino,Italy): Interpretation of the Metallurgical Process

In the Late Bronze Age, the extractive metallurgy of copper in north‐eastern Italy achieved a peak of technological efficiency and mass production, as evidenced by the substantial number of metallurgical sites and the large volume of slags resulting from smelting activities. In order to define the technological features of the Late Bronze Age metallurgical process, more than 20 slags from the smelting site of Luserna (Trentino, Italy) were fully analysed by means of optical microscopy, X‐ray powder diffraction, X‐ray fluorescence spectrometry and scanning electron microscopy. Three different slag types were identified based on mineralogical and chemico‐physical parameters, each being interpreted as the product of distinct metallurgical steps. A Cu‐smelting model is proposed accordingly.