Small angle neutron scattering study of ancient pottery from Syracuse (Sicily,Southern Italy)

This paper is focused on a spectroscopic study of some pottery shards from an archaeological site in Syracuse (Sicily, Southern Italy), dating back to the Hellenistic–Roman period. Structural characterization was performed at different scales of observation, i.e. from macroscopic to mesoscopic. The main goal was to point out the potentiality of the small angle neutron scattering (SANS) technique as a non-invasive analytical tool in archaeometry, also in conjunction with other, more usual, methodologies. Correlation of experimental data, i.e. macroscopic typology and texture, obtained from petrographic analysis, and radius of gyration and fractal dimension of the interfaces of the mesoscopic aggregates obtained using SANS, together with mineralogical X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis, allowed hypotheses to be made on the production technology of the investigated samples.     

Exploring Nonlinear Spatial Dependence in the Tails

In many instances it is of interest to measure the degree of similarity between neighboring regions. Spatial autocorrelation measures are the most popular means of doing it. However, such measures only capture a global linear relationship between regions, whereas in many circumstances a more general instrument is required. For instance, in economic poverty analysis or environmental applications (and in other cases where we are interested in extreme events and threshold exceedances) we should be more interested in the spatial pattern in the tails of the joint distributions. In this article we introduce some exploratory tool that focuses on the bivariate joint tails behavior to detect a pattern of spatial regularities. The method will be illustrated with reference to simulated environmental data.     

Integrated geophysical surveys at the archaeological site of Tindari (Sicily,Italy)

The results of geophysical survey carried out at the archaeological site of Tindari, located 70 km west-north-west of Messina (Sicily, Italy), are presented and discussed. The site is one of the most important archaeological sites, about 90 ha large, on the north-eastern side of Sicily and it was one of the last Greek settlements in Sicily. Keeping in mind the vastness of the site, according to the archaeologists an area, of about 1200 m² was selected, for a geophysical survey. Electrical resistivity tomography (ERT), including induced polarization (IP) measurements, and seismic refraction tomography were applied in the course of geophysical exploration in the area. The objective of this preliminary geophysical investigation was to verify the effectiveness of the technique for a spatial definition of the buried archaeological structures (mostly walls, columns, etc.) to determine their characteristics and to study the presence of collapsed columns within the zone of archaeological interest, in view of their application in the rest of the site, that, for obvious reasons, could not be entirely excavated in brief times. The geophysical data, visualized in 3D space, revealed a distribution of low-contrast shallow anomalies that indicate the presence of different types of buried structures in the surveyed area. Also, the probable accumulations of collapsed columns could be determined. These results confirm the hypothesis of a large northern extension of the archaeological site and provide useful information to design a more efficient excavation plan.     

Geophysical investigation of the Temple of Apollo (Hierapolis,Turkey)

The ruins of Hierapolis are located a few kilometres North of Laodicea in the Lycus Valley (western Turkey). This area is characterised by a large geothermic field that produces several hot water springs along tectonic structures (fractures and faults).     

Three-dimensional image of seismic refraction tomography and electrical resistivity tomography survey in the castle of Occhiolà (Sicily,Italy)

A geophysical survey was carried out at the ruins of Occhiolà Castle (Sicily, Italy), a medieval village located at the north-western part of a hill named “Terravecchia” at 491 m asl. In order to map the archaeological structures (such as walls and burrows), Electrical resistivity tomography (ERT) and seismic-refraction tomography methods were used. The resistivity variations are known to correlate quite well with the lithology, thus providing important information for identifying the buried archaeological remains. On the other hand, seismic velocity variations provide information about the geometrical features of the remains. The two geophysical methods are used in an enjoined way to better aid the interpretation and evaluate the significance and reliability of the results obtained with each single method. The electrical and seismic data are displayed in three dimensions by using the iso-resistivity and iso-velocity surfaces, respectively. This allows us to effectively define the location of the anomalies present in the single electrical and seismic sections. The results obtained in the survey highlight the presence of structures of regular shape, probably due to features of archaeological interest.     

Integrating radar and laser-based remote sensing techniques for monitoring structural deformation of archaeological monuments

Ground-Based Synthetic Aperture Radar Interferometry (GBInSAR) and Terrestrial Laser Scanning (TLS) were purposely integrated to obtain 3D interferometric radar point clouds to facilitate the spatial interpretation of displacements affecting archaeological monuments. The paper describes the procedure to implement this integrated approach in the real-world situations of surveillance of archaeological and built heritage. Targeted tests were carried out on the case study of the Domus Tiberiana sited along the northern side of the Palatino Hill in the central archaeological area of Rome, Italy, and displacements of the monument were monitored over almost one year of acquisition. The GBInSAR – TLS integration provided updated information about the condition of the archaeological structures in relation to their history of instability mechanisms, and did not highlighted a general worsening for the stability of the entire monument. Point-wise and prompt detection of displacement anomalies and/or sudden changes in displacement trends proved the suitability of the method to support early warning procedures, also to evaluate effects on the masonry due to human activities.     

Protocol for lapis lazuli provenance determination: evidence for an Afghan origin of the stones used for ancient carved artefacts kept at the Egyptian Museum of Florence (Italy)

Despite that the Badakhshan Province (Afghanistan) remains the most plausible hypothesis for the lapis lazuli used in antiquity, alternatives proposed in literature are worth to study to confirm or disprove their historical reliability. In this work, a protocol for determining the provenance of lapis lazuli rocks used for carved artefacts is described. Markers for the univocal attribution of the raw material to a source were identified analysing 45 rocks of known provenance (among which 15 georeferenced) from 4 quarry districts. To the best of our knowledge, this reference database is the widest in provenance studies on lapis lazuli. All the markers are recognisable by means of Ion Beam Analysis (IBA) techniques, in particular micro-proton-induced x-ray emission (PIXE) and micro-ionoluminescence (IL). These techniques are non-invasive and applicable in air, allowing to analyse artworks and rocks of practically any shape and dimension without sample preparation.The protocol was applied to determine the provenance of raw material used for carved lapis lazuli artefacts kept at the Egyptian Museum of Florence, the second most important Egyptian museum in Italy, second only to the museum of Turin. The collection in Florence has a great historical value and includes several lapis lazuli pendants, scarabs, small statuettes and amulets ascribable mainly to the first millennium BC. Following the protocol, 11 of these artefacts were analysed by means of IBA techniques. Results ascribe the raw material to the Afghan quarry district.     

Analysis of rock samples collected from rock hewn churches of Lalibela,Ethiopia using laser-induced breakdown spectroscopy

With the aim to study alteration processes of the rock hewn churches from Lalibela (Ethiopia), we applied Laser Induced Breakdown Spectroscopy (LIBS) technique to measure the elemental composition both of the bulk rock materials and their external layers, exposed to the environmental factors. The analytical plasma was generated by nanosecond pulses of an Nd: YAG laser emitting at 1064 nm. Different major and minor sample constituents were detected, including Ca, Mg, Na, Fe, Ti, Al and K. The detected O emission originates both from air surrounding and the sample, while the intensity of N lines, coming exclusively from air, was used for the LIBS signal normalization. By depth profiling of the weathered basalt rock, we observed a lower presence of K in the external layers, corresponding to the first 5 laser shots. The emission from this element is anti-correlated with the line intensities from O, and this was attributed to the variations in relative abundances of clay minerals and K-feldspar. The analogue measurements were performed on the tuff rock, and compared to the spectra from powder samples containing only the external soft material, scratched from the rocks. These analyses show an abundance of H in the weathered, wetted layers and suggest that cations are lost from the constituent primary minerals and replaced by H⁺; this process disrupts the lattice structure and causes a marked loss of strength. The studies presented here demonstrate that LIBS is a useful technique for studying the alteration processes in the rocks, caused by environmental factors.