Identifying biomolecular origins of solid organic residues preserved in Iron Age Pottery using DTMS and MVA

The chemical characterisation of solid organic residues found in ceramic vessels, can provide archaeologists with valuable information about ancient diets. Although several selective analytical techniques have been applied to the analysis of specific classes of compounds, such as extractable lipids, waxes, terpenoids and protein fragments, a non-selective analytical technique is required to characterise and categorise complete solid organic residues. In this study, Direct Temperature-resolved Mass Spectrometry (DTMS) is used for the characterisation of 34 solid residues situated on vessels recovered from an indigenous settlement from the Roman period at Uitgeest – Groot Dorregeest (The Netherlands). Sample preparation is limited to grinding very small samples (5–10 μg) and suspending them in water. DTMS analysis of aliquots (1–2 μL) of this suspension gave information about a broad range of organic compounds, such as lipids, polynuclear aromatic hydrocarbons, markers for residual proteins and polysaccharides, and for newly formed complex condensed polymers. Multivariate analysis of the DTMS spectra identified five different chemotypes: groups of residues with comparable chemical characteristics. The biomolecular origin of each of these chemotypes is identified by comparison with experimentally charred reference materials. The chemotypes A₁ and A₂ consist of charred residues identified as starch-rich foods (mixed with animal or plant products), chemotype C consists of protein-rich charred animal products without starch, chemotype B contains smoke condensates from wood fires, and chemotype D consists of special protein-rich and lipid-free foods or non-food products.     

Stone technology at the Middle Pleistocene site of Mata Menge,Flores, Indonesia

The stone technology from Mata Menge on Flores, Indonesia, is described, providing the first detailed analysis of the largest stone artefact assemblage from a stratified and securely dated Middle Pleistocene site in Southeast Asia. Technological analysis indicates a reduction sequence based on the centripetal, or “radial”, reduction of transported blanks. The implications for early hominin behaviour on Flores are considered.     

Numerical Modeling of a Church Nave Wall Subjected to Differential Settlements: Soil-Structure Interaction,Time-Dependence and Sensitivity Analysis

ABSTRACT

Historic masonry structures are particularly sensitive to differential soil settlements. These settlements may be caused by deformable soil, shallow or inadequate foundation, structural additions in the building and changes in the underground water table due to the large-scale land use change in urban areas.

This paper deals with the numerical modeling of a church nave wall subjected to differential settlement caused by a combination of the above factors. The building in question, the church of Saint Jacob in Leuven, has suffered extensive damage caused by centuries-long settlement. A numerical simulation campaign is carried out in order to reproduce and interpret the cracking damage observed in the building.

The numerical analyses are based on material and soil property determination, the monitoring of settlement in the church over an extended period of time and soil-structure interaction. A sensitivity study is carried out, focused on the effect of material parameters on the response in terms of settlement magnitude and crack width and extent. Soil consolidation over time is considered through an analytical approach. The numerical results are compared with the in-situ observed damage and with an analytical damage prediction model.