The October 2008 Nový Kostel earthquake swarm and its gas geochemical precursor

A gas geochemical precursor anomaly was identified prior to the October 2008 Nový Kostel (Czech Republic) earthquake swarm with a peak magnitude M_L of 3.8. This anomaly was observed as a deviation of CO₂ concentrations from the long‐term annual CO₂ concentration trend in the gas extracted from the scree at the Nový Kostel and Old?i?ská gas monitoring stations, which are directly above the Plesná valley‐Po?átky and Mariánské Lázně fault systems. Both sites are located within the major focal zone of the NW Bohemian swarm earthquake region at the northern edge of the Cheb Basin. A decrease in CO₂ concentration started at Nový Kostel in September 2008, 17 days before the swarm, opposite to the usually increasing annual trend in the autumn period, and ended with a nearly coseismic drop immediately prior to the onset of the first swarm. The CO₂ concentrations at Old?i?ská, deviating from the annual trend, did not further increase after August 2008. The calculated horizontal strain field, based on the data of two permanent Global Navigation Satellite Systems stations, proved there was horizontal compression in this period. The increasing compression along the Plesná valley‐Po?átky and Mariánské Lázně fault systems during the stress build‐up reduced the fault permeability prior to this earthquake swarm as indicated by the decrease in CO₂ concentration. The 17‐day duration of the earthquake precursor at Nový Kostel and about 65 days at Old?i?ská lie within the range of the precursor times that are hypothesized worldwide for an M_L = 3.8 earthquake. The nature of earthquake precursors and their origin are discussed, for example, as an indication of changed fault permeability by stress build‐up in the case of the Nový Kostel swarm earthquake precursor or as fault opening in other cases.     

Chemical evolution of metamorphic fluids in the Central Alps,Switzerland: insight from LA‐ICPMS analysis of fluid inclusions

The chemical evolution of fluids in Alpine fissure veins (open cavities with large free‐standing crystals) has been studied by combination of fluid inclusion petrography, microthermometry, LA‐ICPMS microanalysis, and thermodynamic modeling. The quartz vein systems cover a metamorphic cross section through the Central Alps (Switzerland), ranging from subgreenschist‐ to amphibolite‐facies conditions. Fluid compositions change from aqueous inclusions in subgreenschist‐ and greenschist‐facies rocks to aqueous–carbonic inclusions in amphibolite‐facies rocks. The fluid composition is constant for each vein, across several fluid inclusion generations that record the growth history of the quartz crystals. Chemical solute geothermometry, fluid inclusion isochores, and constraints from fluid–mineral equilibria modeling were used to reconstruct the pressure–temperature conditions of the Alpine fissure veins and to compare them with the metamorphic path of their host rocks. The data demonstrate that fluids in the Aar massif were trapped close to the metamorphic peak whereas the fluids in the Penninic nappes record early cooling, consistent with retrograde alteration. The good agreement between the fluid–mineral equilibria modeling and observed fluid compositions and host‐rock mineralogy suggests that the fluid inclusions were entrapped under rock‐buffered conditions. The molar Cl/Br ratios of the fluid inclusions are below the seawater value and would require unrealistically high degrees of evaporation and subsequent dilution if they were derived from seawater. The halogen data may thus be better explained by interaction between metamorphic fluids and organic matter or graphite in metasedimentary rocks. The volatile content (CO₂, sulfur) in the fluid inclusions increases systematically as function of the metamorphic grade, suggesting that the fluids have been produced by prograde devolatilization reactions. Only the fluids in the highest grade rocks were partly modified by retrograde fluid–rock interactions, and all major element compositions reflect equilibration with the local host rocks during the earliest stages of postmetamorphic uplift.     

Polychromy Analysis on Cypriot Archaic Statues by Non‐ and Micro‐Invasive Analytical Techniques

The polychromy of limestone and terracotta statues from Cyprus attributed to the sixth to fifth centuries bc is analysed using non‐ and micro‐invasive techniques in order to shed light on the use of pigments during the studied period. The strengths and limitations of these methods for the present application are discussed. The identified pigments are iron‐containing compounds (red, yellow, green earths and iron–manganese black). No copper‐containing compounds were detected on the studied objects, despite the wide availability of copper minerals in Cyprus.