DETERMINATION OF PIGMENTS AND BINDERS IN POMPEIAN WALL PAINTINGS USING SYNCHROTRON RADIATION – HIGH‐RESOLUTION X‐RAY POWDER DIFFRACTION AND CONVENTIONAL SPECTROSCOPY – CHROMATOGRAPHY

The employment of synchrotron techniques complemented by conventional laboratory systems has allowed us to deepen and improve our knowledge of Roman wall painting procedures. The palette identified in wall paintings from Pompeii and Herculaneum from the second century bc includes goethite, hematite, cinnabar, glauconite, Egyptian blue, and other components such as calcite and aragonite. Proof of the use of organic binders is provided by FTIR and PY–GC/MS. Therefore, the possibility of the use of ‘a secco’ techniques cannot be ruled out. Pigments in wall paintings are usually found in small percentages and conventional X‐ray diffractometers do not detect them. Synchrotron radiation – high‐resolution X‐ray powder diffraction has allowed identification with only a few micrograms of sample.     

COMPOSITIONAL VARIATION IN ROMAN COLOURLESS GLASS OBJECTS FROM THE BOCHOLTZ BURIAL (THE NETHERLANDS)*

We investigated the major and trace element composition and Pb and Sr isotope characteristics of a series of about 20 colourless glass objects from a single high‐status Roman burial from the Netherlands (Bocholtz). The major elements show a relatively homogeneous group, with one outlier. This is corroborated by the Sr isotopes. Based on the Sb and Pb content, three major groups can be discerned, with two other outliers. This grouping is corroborated by the contents of the trace elements Bi, Sn, Ag, As and Mo, and by variations in lead isotopic ratios. On the basis of these results, we conclude that the glass of all objects was probably made with sand and lime from the same source. The variation in trace elements and lead isotope composition is most likely the result of variations in the composition of the sulphidic antimony ore(s) that were used to decolourize the glass. The composition of the Bocholtz glass is compared with that of other Roman glass, and implications for production models, trade and use of colourless glass objects are discussed. On the basis of isotopic and major element variation, we conclude that the antimony ore presumably originated from different mines.     

LEAD ISOTOPIC ANALYSIS OF COPPER ORES FROM THE SIERRA EL ARAMO (ASTURIAS,SPAIN)*

This study presents the first ever lead isotope ratio data for copper ore samples (malachite and azurite) from the Sierra El Aramo (Asturias, northwestern Spain). The aim of this study was to supplement information in the existing reference database on the lead isotopic composition of Spanish ores. The Sierra El Aramo is particularly important because, while no data for the Asturian ores have been published so far, this northern province of Spain has played a significant role in terms of copper exploitation and metallurgy since the Copper Age.     

SYNCHROTRON FTIR MICRO‐SPECTROSCOPY APPLIED TO THE STUDY OF POLISHED SERPENTINITE ARTEFACTS: A NON‐DESTRUCTIVE ANALYTICAL APPROACH

In prehistory, serpentinite was one of the most frequently used raw materials to produce polished stone artefacts. Several conventional analytical techniques can be applied to identify the serpentine minerals, but their application generally requires a powdered sample. This implies that the artefacts to be analysed must be damaged, and the possibility of analysing a mixture of different serpentine polytypes is high. The use of spatially resolved techniques is therefore a necessity to overcome this problem. Several thin sections of serpentinitic rocks and prehistoric axes have been analysed by synchrotron radiation Fourier transform infrared micro‐spectroscopy. The spectra were acquired directly on specific points of polished stone artefacts and this allowed the recognition of the different polytypes of serpentine minerals without causing any damage to the objects. The results show the infrared micro‐spectroscopy technique to be a useful tool for the characterization of archaeological lithic material.     

NEUTRON TOMOGRAPHIC ASSESSMENT OF INCISIONS ON PREHISTORIC STONE SLABS: A CASE STUDY FROM WONDERWERK CAVE,SOUTH AFRICA*

This study presents the application of neutron tomography to the analysis of ironstone slabs found in a late Earlier Stone Age context (Fauresmith industry) at the back of Wonderwerk Cave, Northern Cape Province, South Africa. These slabs have markings on the surface that might be anthropogenic, and thus significant to understanding the emergence of human symbolic behaviour. Neutron tomography proved to be an effective tool for distinguishing surface incisions from lines that are the expression of internal fissures in the rock.     

DNA FROM HUMAN ANCIENT BACTERIA: A NOVEL SOURCE OF GENETIC EVIDENCE FROM ARCHAEOLOGICAL DENTAL CALCULUS

We report a molecular methodology to obtain and analyse ancient bacterial DNA from archaeological dental calculus. Recent and archaeological DNA samples, as old as 4000 bp , were successfully extracted and amplified with species‐specific PCR primers. We propose this approach in order to: detect the presence of specific bacterial species infecting past human populations; compare the composition of ancient oral microbiomes among human populations; and analyse the genetic variability and covariation of bacteria and human host populations. Genomic analysis of bacteria from dental calculus is a promising source of evidence for palaeopathological and micro‐evolutionary studies, focused either on micro‐organisms or their human hosts.     

WHITE,VEINED MARBLE FROM ROMAN AMMAIA (PORTUGAL): PROVENANCE AND USE

A multimethod approach using petrography and strontium (Sr) isotopic analysis was applied to determine the geological source of 17 marble artefacts from the Roman town of Ammaia (Portugal). All samples are calcitic, with dolomite, quartz and muscovite as accessory minerals. The marbles are characteristically medium‐grained with a maximum grain size (MGS) between 0.98 mm and 1.82 mm, have a heteroblastic texture, and have curved to embayed calcite grain boundaries. ⁸⁷Sr/⁸⁶Sr values of marble leachates range from 0.708488 to 0.708639. Comparison with Hispanic and Mediterranean marbles suggests the Estremoz Anticline as the most likely source for the Ammaia marble, especially for architectural marble. This hypothesis is supported by the geographical proximity of the Estremoz marble district and the long and expensive overland transport required for other marbles to reach Ammaia.     

SEISMIC BEHAVIOUR OF PERIMETER AND SPATIAL STEEL FRAMES

The present study deals with the seismic performance of partial perimeter and spatial moment resisting frames (MRFs) for low-to-medium rise buildings. It seeks to establish perimeter configuration systems and hence the lack of redundancy can detrimentally affect the seismic response of framed buildings. The paper tackles this key issue by com-paring the performance of a set of perimeter and spatial MRFs, which were “consistently designed”. The starting point is the set of low-(three-storey) and medium-rise (nine-storey) perimeter frames designed within the SAC Steel Project for the Los Angeles, Seattle and Boston seismic zones. Extensive design analyses (static and multi-modal) of the perimeter frame buildings and consistent design of spatial frame systems, as an alternative to the perimeter configuration, were conducted within this analytical study. The objectives of the consistent design are two-fold, i.e. obtaining fundamental periods similar to those of the perimeter frames, i.e. same lateral stiffness under design horizon-tal loads, and supplying similar yield strength. The seismic behaviour of perimeter and spatial configuration structures was evaluated by means of push-over non-linear static analyses and inelastic dynamic analyses (non linear time histories). Comparisons be-tween analysis results were developed in a well defined framework since a clear scheme to define and evaluate relevant limit states is suggested. The failure modes, either local or global, were computed and correlated to design choices, particularly those concerning the strength requirements (column overstrength factors) and stiffness (elastic stability indexes). The inelastic response exhibited by the sample MRFs under severe ground motions was assessed in a detailed fashion. Conclusions are drawn in terms of local and global performance, namely global and inter-storey drifts, beam and column plas-tic rotations, hysteretic energy. The finding is that the seismic response of perimeter and spatial MRFs is fairly similar. Therefore, an equivalent behaviour between the two configurations can be obtained if the design is “consistent”.