CORRELATION BETWEEN SPECTRAL,SEM/EDX AND ELECTROCHEMICAL PROPERTIES OF MAYA BLUE: A CHEMOMETRIC STUDY*

Visible spectra, composition from SEM/EDX and solid‐state electrochemical data are correlated for a set of 12 Maya Blue samples from different archaeological sites of Campeche and Yucatán (Mexico). In addition to indigo and dehydroindigo, indirubin and other possibly indigo‐type compounds can be detected in Maya Blue samples. Application of hierarchical cluster analysis techniques allows similarity relationships to be established between samples from different sites, confirming prior results which suggest that the preparation of Maya Blue pigment evolved with time during the Maya culture following a ramified scheme.     

DIAPHRAGM ACTION OF SANDWICH PANELS IN PIN-JOINTED STEEL STRUCTURES: A SEISMIC STUDY

The paper focuses on the seismic response of steel pin-jointed frames braced by lightweight cladding panels. In particular, with the aim to investigate the performance of such a structural scheme when acting as a dissipative system, a wide numerical study has been developed. It is based upon available shear tests on screwed sandwich panels, whose experimental cyclic responses are properly incorporated into a scope-oriented, computer program. The goal is firstly to check the possibility of using cladding panels as shear diaphragms in seismic areas and then to assess an appropriate design behaviour factor, accounting for their actual hysteretic response. Key findings from the nonlinear dynamic analyses are: (1) a portal frame steel building in a low-medium seismicity zone may be braced by common cladding panels, completely avoiding the use of other bracing systems; (2) this structural solution, if compared with a conventional one, appears to be more efficient and cost-effective, giving rise to a weight saving which, in the case under examination, reaches a value of about 20%; (3) on the basis of the numerical study a design behaviour factor q _d =2 seems to be realistic for such a structural typology.     

PETROGRAPHIC AND CHEMICAL CHARACTERIZATION OF POTTERY PRODUCTION OF THE LATE MINOAN I KILN AT HAGHIA TRIADA,CRETE*

Pottery from the Late Minoan I kiln at Haghia Triada in the Mesara Plain, southern Crete, was analysed by a range of techniques, comprising thin‐section petrography, scanning electron microscopy, X‐ray diffraction, X‐ray fluorescence and neutron activation analysis. The project characterizes the ceramic fabrics and probable raw materials, correlates paste recipes with shape, reconstructs the firing conditions of the kiln and establishes a chemical reference group, taking into account post‐burial alteration and contamination. Comparison of the reference group formed with that from the neighbouring, broadly contemporary, kiln at Kommos shows an unexpected differentiation of the two kilns.     

AN EVALUATION OF ANALYTICAL AND INTERPRETATIVE METHODOLOGIES FOR THE EXTRACTION AND IDENTIFICATION OF LIPIDS ASSOCIATED WITH POTTERY SHERDS FROM THE SITE OF SAGALASSOS,TURKEY*

Three lipid analysis methods were applied to extracts of archaeological potsherds from the ancient city of Sagalassos, south‐west Turkey. In the fatty acid methyl ester fraction, obtained by selective transesterification of acylglycerols, the ratio of methyl palmitate to methyl stearate was determined. Secondly, by means of gas chromatography– combustion–isotope ratio mass spectrometry (GC–C–IRMS), stable carbon isotope ratios were measured for the same methyl esters. Finally, triglyceride composition was determined via high‐performance liquid chromatography–mass spectrometry (HPLC–MS). All three methods can be used to trace the origin of animal fat. Agreement between them is reasonable, especially in recognizing ruminant adipose fat. One sample was found to be of dairy origin using both GC–C–IRMS and HPLC–MS. The advantages of the various methods are discussed. Variations in lipid composition were observed between samples from different periods and excavated in diverse areas within the city of Sagalassos.     

DISCRIMINATION BETWEEN ETRUSCAN POTTERY AND RECENT IMITATIONS BY MEANS OF THERMAL ANALYSES

Black bucchero and red pottery of Etruscan production (Cerveteri, seventh-fifth century B.C.), made from the local Pliocene clay, acquire the property of quickly adsorbing and releasing water after heating up to 300°C. Thermal analysis thus allows easy discrimination between ancient artefacts and recent imitations found to be impervious to water.