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51.
Iulia Concordia is an important Roman settlement known for the production of iron objects and weapons during the Roman Empire. A huge number of well-preserved styli were found in the bed of the main channel of the city. In order to shed light on the production processes used by Roman for stylus manufacturing and the conservation state of the finds, a neutron tomography analysis was performed on NEUTRA beamline in Switzerland. SEM-EDS analyses were performed on few selected objects in order to identify the composition of metal decorations. Here, we present results from our investigation conducted on 91 styli, disclosing, in a non-invasive way, the morphological characterization related to the ancient Roman working techniques.  相似文献   
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El Chichón is an active volcano located in the north‐western Chiapas, southern Mexico. The crater hosts a lake, a spring, named Soap Pool, emerging from the underlying volcanic aquifer and several mud pools/hot springs on the internal flanks of the crater which strongly interact with the current fumarolic system (steam‐heated pools). Some of these pools, the crater lake and a cold spring emerging from the 1982 pumice deposits, have been sampled and analysed. Water–volcanic gas interactions determine the heating (43–99°C) and acidification (pH 2–4) of the springs, mainly by H2S oxidation. Significantly, in the study area, a significant NH3 partial pressure has been also detected. Such a geochemically aggressive environment enhances alteration of the rock in situ and strongly increases the mineralization of the waters (and therefore their electrical conductivity). Two different mineralization systems were detected for the crater waters: the soap pool‐lake (Na+/Cl? = 0.4, Na/Mg>10) and the crater mud pools (Na+/Cl? > 10, Na/Mg < 4). A deep boiling, Na+‐K+‐Cl?‐rich water reservoir generally influences the Soap Pool‐lake, while the mud pool is mainly dominated by water‐gas–rock interactions. In the latter case, conductivity of sampled water is directly proportional to the presence of reactive gases in solution. Therefore, chemical evolution proceeds through neutralization due to both rock alteration and bacterial oxidation of ammonium to nitrate. The chemical compositions show that El Chichón aqueous fluids, within the crater, interact with gases fed by a geothermal reservoir, without clear additions of deep magmatic fluids. This new geochemical dataset, together with previously published data, can be used as a base line with which to follow‐up the activity of this deadly volcano.  相似文献   
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Abstract

The Rothschild bank in Naples was founded following the Restoration of 1815, and thereafter played a major role in the financial affairs of the Kingdom of the Two Sicilies and other Italian states until Italy’s Unification after which its operations were transferred to Turin and Rome in 1863. This article examines the career of Karl Rothschild and his son Adolphe in Naples, and describes their close contacts with the Neapolitan government, their intervention to finance the return of Pope Plus IX to Rome following the revolution of 1848–9, and their financial dealings with Cavour and the Kingdom of Piedmont-Savoy in the early 1850s. As well as contacts with the parent Rothschild banking operations in Frankfurt and London, the article examines the Rothschilds’ relations with other foreign and local bankers in Naples. It also explores their role in Neapolitan society and their role in the re-establishment of the Jewish community in Naples in 1830, which they continued to watch with interest long after the family’s banking interests in the city had been wound up.  相似文献   
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A combination of energy dispersive X-ray fluorescence (ED-XRF) and 2D proton nuclear magnetic resonance (1H NMR) relaxometry was employed for the characterization of two groups of similar ceramic fragments from the high-medieval production of the Phlegrean area (Miseno and Cuma, Southern Italy). Both methods are based on the use of non-destructive and portable instruments. This approach allows to correlate complementary microstructural features of ceramics, both dependent and independent of the firing technique.  相似文献   
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The lack of written sources for many of the medieval castles in the northern Apennines (Italy) makes it difficult to completely establish the most ancient historical phases of these settlements. The church of San Michele belongs to an abandoned fortified settlement of the Castle of Benabbio, in the mountains surrounding Lucca. Thanks to an epigraph still visible on the façade, the church foundation is dated back to AD 1218. However, several archaeological findings at the settlement seem to suggest stages of encastlement that are older than the church foundation.  相似文献   
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This paper investigates the impact of the main criterion employed by the European Commission for the allocation of the largest portion of Structural Funds, based on the threshold of the 75% of European Union (EU) average gross domestic product (GDP) per capita. We focus on the 2014–2020 programming period and on EU-15 regions to analyze if this criterion has penalized some of them, as a consequence of the 2004 EU enlargement, which has represented an exogenous shock in the allocation process, due to the economic backwardness of new member states. Through the application of Synthetic Control Methods and Difference-in-Differences estimators at different geographical scales, we show that regions that did not obtain the less developed status in both the programming period 2007–2013 and 2014–2020, but that would have obtained it in the period 2014–2020 without the 2004 EU enlargement, experienced a significantly lower GDP per capita growth between −10.5% and −5.7%. Conversely, territories that in the period 2014–2020 lost the less developed status, previously obtained in the time frame 2007–2013, were not characterized by a significantly lower economic growth, providing some evidence of the effectiveness of the safety net.  相似文献   
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