EVALUATION OF THE MANGANESE ESR METHOD OF MARBLE CHARACTERIZATION

Results suggest that ESR studies of Mn⁺² in marble can provide an excellent discriminator for the determination of marble provenance. In comparison with other methods of quantitative analysis for manganese such as AA or NAA, the ESR method determines only Mn⁺² rather than total Mn, is inexpensive and rapid with no chemical preparation required, and does not consume the sample.     

PROVENIENCE STUDY OF MEDIEVAL BULGARIAN GLASSES BY NAA AND CLUSTER ANALYSIS

The neutron activation analysis results from 30 glass samples were subjected to cluster analysis. The reliable localization of part of the medieval glass finds from Preslav enabled the evaluation of the variety of the production of a medieval glass workshop (ninth-tenth century), allowing conclusions to be made about the technological level of glass-making in Bulgaria during the Middle Ages. The work proved that NAA followed by cluster analysis is a successful approach to finding the local and chronological features of the investigated glasses.     

SPECTROCHEMICAL ANALYSIS OF SOME MEDIAEV AL GLASS FRAGMENTS FROM CATALAN GOTHIC CHURCHES

AAS, FE and OES are each used in the analysis of thirteen samples of fragments of window glasses from three Catalan Gothic churches: Sta. Maria del Mar (Barcelona, Spain), Pedralbes Monastery (Barcelona, Spain) and Girona Cathedral (Spain). Two kinds of stained window glass are found. Special attention is paid to Co/Cu, Co/Ni and Cu/Ni ratios for blue glasses and Mn/Cu and Fe/Cu ratios for red glasses.