On the origins of extractive metallurgy: new evidence from Europe

The beginnings of extractive metallurgy in Eurasia are contentious. The first cast copper objects in this region emerge c. 7000 years ago, and their production has been tentatively linked to centres in the Near East. This assumption, however, is not substantiated by evidence for copper smelting in those centres. Here, we present results from recent excavations from Belovode, a Vin?a culture site in Eastern Serbia, which has provided the earliest direct evidence for copper smelting to date. The earliest copper smelting activities there took place c. 7000 years ago, contemporary with the emergence of the first cast copper objects. Through optical, chemical and provenance analyses of copper slag, minerals, ores and artefacts, we demonstrate the presence of an established metallurgical technology during this period, exploiting multiple sources for raw materials. These results extend the known record of copper smelting by more than half a millennium, with substantial implications. Extractive metallurgy occurs at a location far away from the Near East, challenging the traditional model of a single origin of metallurgy and reviving the possibility of multiple, independent inventions.     

Provenance of Iron Age iron in southern Germany: a new approach

Ores, slag, and blooms from an Early Iron Age smelting site in the Black Forest, southern Germany, were analysed in view of their possible provenance in combination with products from a modern smelting experiment. Rather than employing lead isotope ratios, like in a previous study, osmium and strontium isotope ratios are used for the discussion of provenance. The results of the smelting experiment with iron ores from the archaeological site and their comparison with original finds show the high potential of osmium as a tracer to determine provenance. Strontium may be an additional indicator but possible contaminations need to be assessed. A Celtic iron ingot has also been analysed to check the potential of osmium for further provenance studies.