Differentiating between anthropogenic calcite in plaster,ash and natural calcite using infrared spectroscopy: implications in archaeology

Infrared spectroscopy provides information not only on the type of calcium carbonate polymorph, but also on the extent of atomic order. In calcite, three major infrared absorption peaks are identified: ν₃, ν₂, and ν₄. It was shown that the ratio between ν₂ and ν₄ bands reflects the order of the calcite crystal structure. In this paper we analyse this ratio in geologically formed calcites, archaeological plasters, modern plasters and experimentally prepared plasters. For the geological calcite, the values of the ν₂/ν₄ ratio are around 3, whereas for the experimentally prepared plasters, the values are around 6.5. The ν₂/ν₄ ratio for archaeological plasters varies from 3 to 6. This shows that a high ratio is indicative of disorder in the crystal, and implies that the calcite was formed from calcium oxide at high temperatures. It also implies that this disorder can be preserved for at least 14,000 years. The ν₂/ν₄ ratio of calcite from archaeological sites can thus be used to differentiate between anthropogenic calcite, such as in plaster, mortar and wood ash, from geogenic calcite, such as in limestone. The ratio may also be used to identify plaster or ash that still retains its original crystals and therefore carbon-14 content.     

À propos d’un cours inédit de Michel Foucault sur l’analyse existentielle de Ludwig Binswanger (Lille 1953–54)On Michel Foucault’s unpublished lectures on Ludwig Binswanger’s existential analysis (Lille 1953–54)Über Michel Foucaults Unveröffentlichte Vorlesungen Zur Daseinsanalyse Ludwig Binswangers (Lille 1953–54)

This paper aims to analyze Michel Foucault’s position toward phenomenological psychology and psychopathology during the 1950s, in light of the new documentary sources available today. Our investigation is especially focused on one of the courses given by Foucault at the University of Lille between 1952 and 1954, namely, the course on “Binswanger and phenomenology” (1953-54). The analysis of this course, which was conceived by Foucault within the context of a philosophical reflection on the anthropological problem of psychopathology, will finally allow us to re-ascribe Foucault the place he deserves in the field of “philosophy of psychiatry”.     

New insights into Byzantine glass technology from loose mosaic tesserae from Hierapolis (Turkey): PIXE/PIGE and EPMA analyses

This study focuses on the Byzantine glass tesserae from Hierapolis (Phrygia, central Turkey). Fifty-seven samples of loose tesserae from two sites in the town (the theatre and the church of St. Philip) are analysed by particule-induced X-ray emission and particule-induced gamma ray emission and electron probe X-ray microanalysis to obtain the chemical composition and identify the colourants and opacifiers. The aims are to add new information to the scant knowledge of the Byzantine glassmaking technology, to constrain the chronology of the mosaics and to trace the supply routes of the tesserae. In the destruction layers of the theatre, tesserae produced following the Roman glassmaking technology (natron glass opacified by calcium and lead antimonate) were found. They were made using a Levantine 1 raw glass, generally attributed to the early Byzantine period (fifth to sixth c.). In the church, the samples attest a technological change from Roman tradition, and a complex pattern according to building history (two phases are attested, probably in the sixth and eighth to ninth c.), and a multiplicity of supply. Three glass types and some recipes not attested before in this chronological range for the production of tesserae are documented, such as the use of a local low-chlorine natron glass for the production of black and red tesserae, the blue colouring by a source of cobalt with zinc in a natron glass tessera and the opacification with tin oxide (both in a lead-free and in a high-lead natron glass), as well as with quartz.     

The Swiss community in Genoa from the Old Regime to the late nineteenth century

Abstract

Drawing on extensive and original archival research, this article is the first to reconstruct the origins and historical development of the Swiss community of Genoa from the sixteenth to the late nineteenth century. During these four centuries, the Swiss were constant and significant agents of the Genoese economy and society. The Swiss presence in the city dates back to the mid 1500s, when Swiss soldiers were the predominant component of the army of the Republic. In the 1700s the Swiss community broadened its economic scope and varied its social configuration. It consisted of both a well-established Protestant, élite of merchant-bankers and textile entrepreneurs and a lower layer of craftsmen, confectioners, street vendors and servants. By the end of the 1700s the Swiss élite was such a thriving and well-integrated group that in 1799 Genoa was selected to be the seat of the first Swiss consulate of the Italian peninsula, the second in Europe after Bordeaux (1798). From the Restoration (1815) to Italian Unification (1861), the Swiss merchant-bankers and textile industrialists continued to be active promoters of the city's economic and trading system. In the decades after Unification (1861–80s), Swiss capital investments moved into new economic sectors (steam-shipping and maritime insurance) that contributed to the modernization of the Genoese and Italian merchant fleet. During the nineteenth century the Swiss community created its own social spaces and identity within the city – a church, a cemetery, a school, and a charitable foundation. As in many other northern Italian cities, the consolidation of the community's external image did not weaken the Swiss élite's integration with the local Genoese upper class.     

Building materials from Thamusida (Rabat,Morocco): a diachronic local production from the Roman to the Islamic period

A total of 67 bricks and tiles found in different archaeological contexts during excavations at Thamusida have been investigated here. The first analysed set consists of 27 bricks found in the area of an Islamic ceramic workshop, which was active at Thamusida from the 8th century onwards. The second set of 40 bricks and tiles was found mostly in situ. They date to the Roman occupation of the site (1st-3rd century AD). Thirteen of them bear different types of stamps. In addition, two types of clay (7 samples) from the surrounding area were analysed as reference for the materials used in the local ceramic production. The samples were investigated by optical microscopy, scanning electron microscopy, X-ray diffraction and X-ray fluorescence. The results allowed reconstructing two local productions of building materials: one during Roman and one during Islamic times, both using local grey tirs (without any manipulation or temper additions) as raw materials. Imports were further identified, tracing both short- and medium-range trade connections. Banasa could be addressed as a likely production site of bricks stamped QAP and APP, while the bay of Tangiers should be indicated as a likely provenance of bricks stamped C∞ and HADRIAVG.     

Establishing the Middle Sea: The Late Bronze Age of Mediterranean Europe (1700–900 BC)

Journal of Archaeological Research - The Late Bronze Age (1700–900 BC) represents an extremely dynamic period for Mediterranean Europe. Here, we provide a comparative survey of the...     

An early Iron Age assemblage of faience beads from Ashkelon,Israel: chemical composition and manufacturing process

The microstructure and chemical composition of eight faience beads from an early Iron Age (12th century BCE) assemblage found in the ancient city port of Ashkelon (Israel) are determined by means of FTIR spectrometry, pXRF, microRaman and SEM-EDS analysis. The results are compared with published data of Egyptian and Near Eastern artifacts. Each sample exhibits a hue which is obtained by adding a specific colorant to the glazing mixture. A new gray chalcopyrite-manganese-based colorant was identified. Cementation glazing was most likely used in the manufacturing process of the specimens analyzed, except for the blue bead, which is an Egyptian blue frit. The results suggest that these objects represent a unique assemblage, quite different from contemporary Egyptian and Near Eastern materials, and provide new information regarding the Iron Age faience evidence in the southern Levant.