Modern and fossil charcoal: aspects of structure and diagenesis

The structures and compositions of modern and fossil charcoal samples were compared in order to evaluate charcoal degradation processes in archaeological sites. Modern charcoal samples produced in campfires contain two major phases: graphite-like microcrystallites and a non-organized phase. These phases create a mosaic-like structure with differing relative proportions depending on the taxonomic source of the wood used. Fossil charcoal samples (Tel Dor, Israel: 3000 years BP and Kebara Cave, Israel: 40,000 years BP) also contained the graphite-like microcrystallites and the non-organized phases, but were clearly altered compared to modern charcoal. The graphite-like phase of the fossil charcoal has much higher electrical resistivity, and its ESR properties show that it has markedly altered surface electronic states. Infrared spectra show the presence of additional carboxylate groups. Oxidation has therefore altered the structure. This appears to be a “self-humification” process that affects the graphitic component, and probably the non-organized phase as well.     

Stamped bricks from the ager cosanus (Orbetello,Grosseto): integrating archaeometry,archaeology, epigraphy and prosopography

This paper documents a comprehensive study of thirty-two stamped bricks found in territory of the ancient town of Cosa (Ansedonia, Grosseto). The geographical distribution of these materials distinguished ‘municipal’ productions, i.e. those found within the territory of Cosa (ager cosanus) only, and ‘urban’ productions, i.e. those found in the ager cosanus, as well as in the territory comprising Rome and its suburbs and/or the entire Tiber Valley. Main aim of the study was to verify the provenance of ‘municipal’ productions, by a combination of archaeological, epigraphical, prosopographical and archaeometrical (OM, SEM–EDS, ICP-OES, ICP-MS, INAA) research instruments and techniques. Data integration revealed that six ‘municipal’ productions (over a total of nine) were produced in the territory surrounding the Cosa's promontory, using marine and fluvial clayey deposits. Conversely, three ‘municipal’ productions were assigned to the ‘urban’ area, and possibly assigned to the Tiber Valley. An important distinction was made among the ‘urban’ productions, proving the feasibility of their discrimination.     

The application of biometry and LA-ICP-MS to provenance isolated bones: a study of hominin remains from Oumm Qatafa Cave,Judean Desert

Three hominin phalanges were recently identified in old faunal collections attributed to the Late Acheulean (Layer D2) dated to ca. 213 Kya, from Oumm Qatafa Cave (Judean Desert), a site excavated in 1928–1949. In terms of general appearance (colour, patina and adhering sediment), these specimens resembled the fauna with which they were found, but the likelihood of stratigraphic problems especially in old excavations, the presence of 4th millennium b.c. burials in the topmost Layer A at the site and the absence of any mention of Late Acheulean hominin remains in publications relating to the site prompted us to verify that the phalanges were indeed in situ. Osteometric examination showed the phalanges to be indistinguishable from those of Middle Paleolithic Levantine anatomically modern humans (AMHS) as well as Upper Paleolithic and recent populations, thus contributing little to the resolution of their provenance. To further investigate this issue, we compared the elemental composition of the phalanges to that of fauna from the same and overlying archaeological layers using non-destructive laser ablation–inductively coupled plasma mass spectrometry (LA-ICP-MS). The results showed a close resemblance in elemental composition between the phalanges and fauna from Layer D2, implying that they are in situ. This would indicate either an early occurrence of AMHS in the region or the presence of an ancestral archaic Homo. We propose that LA-ICP-MS offers a useful minimally invasive method for provenancing isolated human and faunal remains.     

Degradation of mud brick houses in an arid environment: a geoarchaeological model

A common assumption in Near Eastern tell archaeology is that the majority of sediments originate from degraded mud bricks. Little is known about the mechanism of mud brick wall degradation. Here we present a detailed macro- and microscopic ethnoarchaeological study of the degradation of a mud brick house and propose a comprehensive mechanism for tell formation processes in arid environments. The study took place in southern Israel by trenching a ca. 60 year old abandoned mud brick house, followed by extensive sediment sampling. Macroscopic observations showed that mud brick walls degrade by collapse of single bricks and/or collapse of intact wall parts, either inwards or outwards. In addition, infill sediments within the house and outside it, in close proximity to its walls, form alternating sedimentary layers of various colors and textures. The degraded mud brick material lost its distinctive macroscopic structure, which makes it impossible to accurately identify this material by field observations alone. Mineralogical and elemental analyses established the sources of the house infill sediments, namely mud bricks and wind blown sediments. Alternating layers mostly originate from mixing between degraded mud brick material and wind blown sediments. Micromorphological observations revealed microscopic mechanisms of mud brick degradation and include processes of mud slurry gravity flows, sediment coatings and infillings, wind abrasion of walls, small-scale puddling, and bioturbation. This study provides a working scheme for site formation of abandoned mud brick structures in arid environments. It provides a set of criteria by which it is possible to differentiate floors from post-abandonment sedimentary features and thus improves the reliability of activity area research.     

Sediments exposed to high temperatures: reconstructing pyrotechnological processes in Late Bronze and Iron Age Strata at Tel Dor (Israel)

Many of the sediments analysed from Tel Dor (Israel) show structural alterations indicating that they were exposed to high temperatures. This observation is consistent with the abundant evidence for use of pyrotechnology from the earliest exposed Middle Bronze Age strata through the Roman period. Such structurally altered sediments may well represent one of the more widespread and durable records of pyrotechnology, and as such could be invaluable for reconstructing past human activities. The specific aims of this research are therefore to develop the means for identifying local sediments that were altered by different pyrotechnological activities and to elucidate the varying circumstances whereby sediments were exposed to high temperatures in a Late Bronze and Iron Age 1 section.     

Colourless glass from the Palatine and Esquiline hills in Rome (Italy). New data on antimony- and manganese-decoloured glass in the Roman period

A collection of 21 glass samples (18 colourless and 3 light aqua blue) found in recent excavations performed at the Palatine and Esquiline hills in Rome has been investigated by means of SEM-EDS, EMPA and LA-ICP-MS. The glass was recovered in the “Baths of Helagabalus” and the Horti Lamiani. The collection included cups and bowls widely attested in Rome and Ostia from the late second to the first half of the third century AD. The analyses assigned this collection to the RC/LAC-MnSb groups (Roman and Late Antique colourless glass with both antimony and manganese) which seemed closely related to the Levantine area.     

The study of pitch via gas chromatography–mass spectrometry and Fourier-transformed infrared spectroscopy: the case of the Roman amphoras from Monte Poro,Calabria (Italy)

The analysis of the composition of organic residues present in ancient pottery are an important source of information for archaeologists. The chemical characterisation of these materials gives information on diets, habits, technologies and original use of the vessels.     

Glass and metal analyses of gold leaf tesserae from 1st to 9th century mosaics. A contribution to technological and chronological knowledge

An archaeometric study was carried out on 40 gold leaf tesserae from mosaics in Italy dated 1st to the 9th century AD. Glass layers and gold leaf were both analysed by X-ray microanalysis. The main aim was the identification of the composition of the glass and of the gold leaf, in order to assess the variations in composition and nature of the tesserae in the examined period.     

Differentiating between anthropogenic calcite in plaster,ash and natural calcite using infrared spectroscopy: implications in archaeology

Infrared spectroscopy provides information not only on the type of calcium carbonate polymorph, but also on the extent of atomic order. In calcite, three major infrared absorption peaks are identified: ν₃, ν₂, and ν₄. It was shown that the ratio between ν₂ and ν₄ bands reflects the order of the calcite crystal structure. In this paper we analyse this ratio in geologically formed calcites, archaeological plasters, modern plasters and experimentally prepared plasters. For the geological calcite, the values of the ν₂/ν₄ ratio are around 3, whereas for the experimentally prepared plasters, the values are around 6.5. The ν₂/ν₄ ratio for archaeological plasters varies from 3 to 6. This shows that a high ratio is indicative of disorder in the crystal, and implies that the calcite was formed from calcium oxide at high temperatures. It also implies that this disorder can be preserved for at least 14,000 years. The ν₂/ν₄ ratio of calcite from archaeological sites can thus be used to differentiate between anthropogenic calcite, such as in plaster, mortar and wood ash, from geogenic calcite, such as in limestone. The ratio may also be used to identify plaster or ash that still retains its original crystals and therefore carbon-14 content.     

À propos d’un cours inédit de Michel Foucault sur l’analyse existentielle de Ludwig Binswanger (Lille 1953–54)On Michel Foucault’s unpublished lectures on Ludwig Binswanger’s existential analysis (Lille 1953–54)Über Michel Foucaults Unveröffentlichte Vorlesungen Zur Daseinsanalyse Ludwig Binswangers (Lille 1953–54)

This paper aims to analyze Michel Foucault’s position toward phenomenological psychology and psychopathology during the 1950s, in light of the new documentary sources available today. Our investigation is especially focused on one of the courses given by Foucault at the University of Lille between 1952 and 1954, namely, the course on “Binswanger and phenomenology” (1953-54). The analysis of this course, which was conceived by Foucault within the context of a philosophical reflection on the anthropological problem of psychopathology, will finally allow us to re-ascribe Foucault the place he deserves in the field of “philosophy of psychiatry”.