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71.
Characterization of a Historical Cannonball from the Fortress of San Juan De Ulúa Exposed to a Marine Environment 下载免费PDF全文
M. Hernandez M. Hernandez‐Escampa C. Abreu J. Uruchurtu M. Bethencourt A. Covelo 《Archaeometry》2016,58(4):610-623
Metallurgical analyses and chemical characterizations were carried out on historical cannonballs from the Fortress of San Juan de Ulúa, Veracruz, México. Cannonballs dating from the 18th and 19th centuries share metallurgical characteristics similar to those of material coming from a shipment of ammunition found in the wreck of a sunken French ship from the battle of Trafalgar. The analyses show that the base material is grey cast iron with a carbon equivalent of 4.94 and a ferritic–perlitic matrix, in which the high phosphorus content has led to the formation of iron phosphide compounds in conjunction with a homogeneous distribution of carbon graphite flakes of Type C. In addition, corrosion products from samples revealed the presence of various crystalline iron compounds (X‐ray diffraction), mostly highly chlorinated iron compounds identified as akaganeite. X‐ray fluorescence identified various characteristics of the corrosion products as a function of the sampling depth. FT–IR spectroscopy revealed that the main difference between the corrosion products (internal and external) is determined by the number of organic species. Differential scanning calorimetry corroborated that these corrosion products are thermally stable compounds at elevated temperatures. 相似文献
72.
A Box Containing Carpenter's Accessories from The Akko 1 Shipwreck,Israel: Archaeometallurgical Analysis of Surviving Ironwork 下载免费PDF全文
The Akko 1 shipwreck was an Egyptian armed vessel, built at the beginning of the 19th century. A wooden saw handle and a box containing iron nails and two split pins were discovered towards the stern. Given their function, location and context, these were part of the ship's carpenter's tools and accessories. A methodology was developed for conducting systematic metallurgical analysis in order to understand the manufacturing process of the surviving ironwork items, as well as to enlarge our knowledge regarding ironworking technologies during the early 19th century. Such methodology may assist in the future understanding of the technological evolution of similar wrought‐iron objects. The results demonstrated that the artefacts have a wrought‐iron heterogeneous microstructure and were manufactured by hot‐working prior to surface hardening by pack carburization. 相似文献
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HEDONIC PRICING WHEN HOUSING IS ENDOGENOUS: THE VALUE OF ACCESS TO THE TRANS‐ISRAEL HIGHWAY* 下载免费PDF全文
Standard hedonic house pricing assumes that house prices are independent of the intangible to be priced. A methodology is proposed in which the supply as well as the demand for housing depends on the intangible. The methodology is applied to value access to the Trans‐Israel Highway (TIH). Using spatial panel data (2002–2008) we show that TIH had two effects on the housing market. It increased house prices in locations with greater access to TIH, and it affected housing construction. Standard hedonic pricing would have underestimated the value of access because it ignores the effects of housing construction on the intangible to be priced. House prices began to increase three years before TIH was inaugurated, but housing construction did not anticipate the inauguration of TIH. 相似文献
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LOCALIZATION AND INDUSTRY CLUSTERING ECONOMETRICS: AN ASSESSMENT OF GIBBS MODELS FOR SPATIAL POINT PROCESSES 下载免费PDF全文
The objective of this paper is to assess an approach to statistical modeling of point referenced establishment data that permit inclusion of “environmental” or establishment‐specific covariates and specific forms of interestablishment interaction. Gibbs models are used to decompose the conditional intensity of the spatial point process into trend and interaction components. The trend is composed of access measures (primarily different classes of roads) and three different interaction processes are tested: Geyer, area interaction, and Strauss hard core. While the models used have proved to be useful in ecology, we are unaware of any applications to establishment or firm data. In empirical application, the models yield intuitively appealing results for the trend component, and the ability to specify the interaction component gives deeper insights into interestablishment spatial dynamics than any previously published methods. 相似文献
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We examine the relationship between individual commuting behavior and household responsibilities, with a focus on gender differences in that relationship. Using the Dutch Time Use Survey for the years 2000 and 2005, we analyze the relationship between commuting time, home production, and childcare. To deal with reverse causality, we use Propenstity Score Matching techniques to obtain imputed data for individuals. We find that the effect of home production on commuting time for women is more than double that for men, while childcare time has an effect on women's commuting behavior only. Our results shedding light on the Household Responsibility Hypothesis. 相似文献
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