Chemical analyses of the earliest pigment residues from the uttermost part of the planet (Beagle Channel region,Tierra del Fuego,Southern South America)

This paper presents the results of chemical analyses of the organic and inorganic fractions of pigment residues found in three archaeological sites located in the Beagle Channel region, Tierra del Fuego, Southern South America. Twenty-one archaeological samples have been analysed through XRD, SEM–EDX, FT-IR and GC–MS in order to characterise their inorganic colouring components and to search for the presence of organic substances used as binders. Lipids found in some samples are considered as potential binders. These organic components are compared to those found in archaeological sediment samples from the same layers where the pigments have been found, in order to search for potential taphonomic contaminations of the latter by the former. Results show that such contaminations are unlikely, hence the lipid contents are deemed of anthropic origin. The pigment sample results are also compared to data from analyses of natural sediment samples collected in several localities of the Beagle Channel in order to search for potential natural pigment sources. Results show that organic and inorganic components of these sediments are not the same than those present in the archaeological pigment samples, hence the pigment raw material sources have not been yet located. All these data provide for the first time evidence of the existence of ancient activities of pigment sourcing and paint preparation with organic binders which range from 6000 BP to 1900 BP in the southernmost region of the planet.     

Effects of distance from stone source on landscape-scale variation in Oldowan artifact assemblages in the Paleo-Olduvai Basin,Tanzania

Ongoing excavations at Olduvai Gorge, Tanzania, reveal tremendous variability among stone artifact assemblages across the Plio-Pleistocene Olduvai Lake Basin during Bed I and lower Bed II times. Theoretically, stone artifact traces of Oldowan hominin land use are determined by the distribution of larger mammal carcasses and arboreal refuge from predation as well as proximity to stone material sources.     

Roman blue-green bottle glass: chemical–optical analysis and high temperature viscosity modelling

Chemical analysis, optical absorption spectroscopy and mathematical modelling of high temperature viscosity have been carried out on five 1st–2nd century AD Roman blue-green bottle glass fragments from Coppergate, York. Modelled viscosities indicate remarkable consistency within the sample set studied and support the suggestion that temperatures of ∼1000–1150 °C were required to remelt these glasses and to provide suitable viscosities for forming articles. Iron redox ratios (Fe²⁺/ΣFe), analysed SO₃ contents and the absence of characteristic Fe³⁺–S²⁻ amber absorption bands suggest that melting conditions for all studied glasses were mildly, rather than strongly, reducing (estimated pO₂ ≈ 10⁻¹–10⁻⁶ bar). These furnace conditions are consistent with the effects of combustion gases and carbonaceous matter contained in the raw materials.     

Degradation processes in colourless Roman glass: cases from the Bocholtz burial

A group of Roman glass objects from the Bocholtz burial in the SW of Limburg (The Netherlands) was found to have been subject to varying degrees of degradation. Many of the 25 colourless glass objects were fragmented to pieces <0.1 cm (“sugared”), whereas the three transparent blue-green glass objects were in near-pristine state. Analyses using SEM, XRF and EDS revealed that the fragmentation was the direct result of the intense leaching of Na₂O from the glass structure and its replacement with water. The resulting gel layers with low-Na₂O contents and large amounts of water are sensitive to cracking when they dry out. Thin-walled glass appears to be less sensitive to cracking from the resulting stress than thick-walled glass. Local differences in the moisture regime during burial also influence the severity of the glass degradation. Glass with low concentrations of CaO seems to be the most sensitive to this form of degradation. The typical blue-green Roman glass is less sensitive as it generally has considerably higher concentrations of CaO.     

Modelling of hydrology and potential population levels at Bronze Age Jawa,Northern Jordan: a Monte Carlo approach to cope with uncertainty

An annual water balance model for Wadi Rajil, in Northern Jordan, is used to simulate the ancient water supply system for the Early Bronze Age site of Jawa. The model includes: water delivery from the catchment; local pond storage; and water demand for people, animals and irrigation. A Monte Carlo approach is used to incorporate the uncertainty associated with a range of factors including rainfall, evaporation, water losses and use. The stochastic simulation provides estimates of potential population levels sustainable by the water supply system. Historical precipitation estimates from a Global Circulation Model, with uncertainty bounds, are used to reconstruct the climate at Jawa in the Early Bronze Age (EBA). Model results indicate that the population levels in the predicted wetter conditions during parts of the EBA could have risen to ∼6000 and may have been higher in wet years. However, palaeoclimatic proxies also suggest prolonged droughts in the EBA; and during these periods the water management system was unable to provide adequate supply for a population of 6000. The utility of Monte Carlo based hydrological modelling as a tool within archaeological science is discussed.     

Correlation between modern plant δN values and activity areas of Medieval Norse farms

This further nitrogen isotopic study of Greenlandic Norse archaeological sites provides new evidence of the affect of past human activity on modern plant δ¹⁵N values. Grass samples were taken from a number of spatially defined features at four Norse farms and one site interpreted to be a seasonally occupied herding station (sæter). At the farms, un-naturally high δ¹⁵N values were found for plants from each sampled feature, including those from the likely infields and a churchyard. At the sæter no strong isotopic effect was expected and none was found. Comparing the data from the farms we found that the average plant δ¹⁵N values were similar for features that were functionally alike. We conclude from these observations, that the unusually high plant δ¹⁵N values reflect the strong conservation of the isotopic composition of the nitrogenous materials deposited in the past, and the magnitude of the values reflects the amount of this material admixed in the soil. The results confirm previous exploratory studies of this isotopic effect and further demonstrate its potential value as an archaeological tool.     

Elemental analysis and characterization of ochre sources from Southern Arizona

Iron oxides and other associated minerals (ochre) were widely used in ancient times, however, the use and procurement of these materials is not well understood and there has been little research on the elemental characterization of the material compared to other artifact classes. To assess the possibility of identifying ochre differences between locations, the original potential geological sources should be thoroughly characterized. This paper describes the collection of potential geologic sources of ochre in the Tucson basin of Arizona, sampling of those sources, instrumental neutron activation analysis (INAA), and subsequent multivariate analysis of the data. This paper has several goals, including characterizing geochemical trends within and between ochre sources, identifying the important elements in geochemical characterization of ochre, and establishing a database for further investigations. This preliminary study indicates that the inter- and intra-source variations in geological sources of ochre in the Tucson basin region can be differentiated. Future analysis of iron oxide artifacts will be performed to examine correlations between artifacts and sources and provide a basis for further deductions concerning ancient ochre procurement.