Spectrochemical Characterization of Red Pigments Used in Classic Period Maya Funerary Practices

We studied the composition, colour chromaticity and form of application of red pigments in human bone samples from seven Classic period Lowland Maya sites. The samples were analysed by X‐ray diffraction, scanning electron microscopy (SEM) and X‐ray energy‐dispersive spectroscopy (EDS). Colour was measured using conventional colour identification standards (Munsell) and reflectance spectroscopy. Cinnabar and hematite were identified as the pigments used. We conclude that the reflectance method has advantages over conventional visual results, as it provides precise, objective and quantifiable optical data to distinguish the chromaticity, colour saturation and brightness of the pigments.     

For Whom the Bells Fall: Metals from the Cenote Sagrado,Chichén Itzá

Bells of copper and copper alloys and gold–copper alloys were deposited in events at the Cenote Sagrado at Chichén Itzá, Mexico during the site's primary occupation (ad 750–1050) and in later centuries. Housed in three museums in the United States and Mexico, bells (n = 38) were evaluated for traces of fabrication and alteration using Vis–UV–IR optical microscopy. Bulk compositions were determined through p‐ED‐XRF. Phases and compositional variation by depth were characterized through XRD and RBS. The technological styles of bell groups were ascribed to communities of metallurgical practice, from West and Central Mexico to Costa Rica and Panama.     

A Multidisciplinary Approach for the Archaeometric Study of Pozzolanic Aggregate in Roman Mortars: The Case of Villa dei Quintili (Rome,Italy)

This contribution focuses on the study of historical mortars from a Roman archaeological site known as Villa dei Quintili, a monumental villa located in the south‐eastern part of Rome (Italy). The study was carried out on 38 mortar samples, collected from several edifices within the complex. A multi‐analytical approach, including polarized optical microscopy, scanning electron microscopy coupled with energy‐dispersive system and laser ablation inductively coupled plasma mass spectrometry, was used to analyse the pozzolanic material used for the preparation of mortars. Data obtained on both major and trace elements were compared with the compositions of Pozzolana Rossa, Pozzolana Nera and Pozzolanella samples from the Alban Hills volcanic district, collected from a historic quarry nearby, as well as with literature data. The results of such a multidisciplinary approach allowed us to recognize the use of all three pozzolan types for the aggregate fraction of examined mortars from the Villa dei Quintili.     

A Multi‐Method Database of the Black and White Marbles of Göktepe (Aphrodisias), Including Isotopic,EPR, Trace and Petrographic Data

A database of the ancient marbles of Göktepe near Aphrodisias is reported, and includes 160 white, black and bichrome samples from 13 quarries and two waste deposits. The quarries are grouped into four districts. Districts 1 and 2, to the north, produced exclusively black or dark grey marbles (nero antico). Districts 3 and 4 produced white statuary marble. Nero antico and a black and white stone were also quarried in district 4, where the black marble surfaces again. The samples were characterized using petrography, isotopic analysis, EPR spectroscopy and trace analysis. The Göktepe white exhibits an unparalleled combination of fine grain, low EPR intensity and high strontium concentration that often allows easy identification. The isotopic values are less distinctive and similar to those for Carrara. In most cases, however, they are tightly grouped and also quite indicative. The black marbles exhibit a much weaker metamorphic overprint. With respect to the white marbles, they show analytical similarities but also notable differences. Therefore, establishing their provenance can be more difficult and may require the support of petrographic analysis. The results suggest that the Göktepe marbles were among the most prized and widespread statuary marbles used in Roman times, particularly from the early second century ad onwards.     

Diagenesis and elemental geochemistry under varying reservoir oil saturation in the Junggar Basin of NW China: implication for differentiating hydrocarbon‐bearing horizons

In this paper, we attempt to differentiate hydrocarbon‐bearing reservoir horizons of the Junggar Basin of NW China based on the characteristics of diagenesis and associated elemental geochemistry. Reservoirs at this site have varying levels of oil saturation that correlate with the degree of dissolution in minerals (e.g., calcite and feldspar). Four different horizons with varying diagenetic mineral assemblages were observed, including (i) kaolinite‐rich, oil‐dominated horizons, (ii) kaolinite–pyrite–hematite‐rich, oil–water‐dominated horizons, (iii) siderite–chlorite‐rich, water‐dominated horizons, and (iv) chlorite‐rich horizons with negligible hydrocarbon production. The mean MnO content of the representative diagenetic mineral (e.g., calcite) in each of the above horizons is >2.5, 2.0–2.5, 1.5–2.0, and <1.0 wt%, respectively. We propose that the above methodology can be used for the identification of reservoir hydrocarbon‐bearing horizons. We argue that the indicators presented here can be applied in oil exploration across the Junggar Basin.     

Life and Death in Neolithic Southeastern Italy: The Strontium Isotopic Evidence

There is a strong relation between people's structured identities and their chemical biographies: these can reflect the way individuals choose to reside and/or move. The strontium isotope ratio (⁸⁷Sr/⁸⁶Sr) of skeletal remains is considered a useful proxy to assess residential mobility and social practices in past populations; however, so far, it has only occasionally been applied to prehistoric contexts in the Mediterranean. In this paper, we present ⁸⁷Sr/⁸⁶Sr data of human and animal samples from several Neolithic sites in the Apulian Tavoliere (southeastern Italy), namely, Grotta Scaloria, Passo di Corvo, Masseria Candelaro and La Torretta/Poggio Imperiale. Data obtained from dental enamel reflect the local origin of the individuals and allowed us to differentiate function and meaning of the sites examined. In particular, within a generally homogeneous background of Sr signatures, the range of ⁸⁷Sr/⁸⁶Sr at Scaloria Cave is greater than at the other sites, with variation likely to be related to funerary practices. We interpret this as the evidence of the ritual use of the cave, which implied the gathering of people of different origin. The relative variation of the Sr signature among individuals, either intersite or intrasite can be tentatively associated with mobility during life as well as with social practices, such as access to foods from geologically different environments. Copyright © 2015 John Wiley & Sons, Ltd.