Can the Raman spectrum of anatase in artwork and archaeology be used for dating purposes? Identification by Raman microscopy of anatase in decorative coatings on Neolithic (Yangshao) pottery from Henan,China

Scanning electron microscopy/energy dispersive X-ray analysis has earlier shown that the white background layer (slip) on painted pottery sherds (Yangshao culture, Henan, China, 4200 BC) is composed of kaolinitic clay containing titanium in the assumed form of TiO₂ at just 1 wt%. The same samples of white slip have now been studied by Raman microscopy, revealing bands characteristic of anatase, but none from the majority species, the matrix of kaolinitic clay. These results highlight the extraordinarily intense Raman scattering from even trace amounts of anatase and thus the need to recognise that, although the colours of archaeological artefacts are almost always determined by the nature of the matrix, the Raman spectrum may be determined by a highly scattering trace component such as anatase. The significance of anatase as a potential date-marker pigment on works of art and archaeological artefacts is discussed.     

The Old and the New: Qualifying City Systems in the World with Classical Models and New Data

Zipf's rank‐size rule, lognormal distribution, and Gibrat's urban growth models are considered as summarizing fundamental properties of systems of cities. In this article, they are used as statistical benchmarks for comparing the shapes of urban hierarchies and evolutionary trends of seven systems of cities in the world including BRICS, Europe, and United States. In order to provide conclusions that avoid the pitfalls of too small samples or uncontrolled urban definitions, these models are tested on some 20,000 urban units whose geographically significant delineations were harmonized in each country over 50 years between 1960 and 2010. As a result, if the models appear not always statistically valid, their usefulness is confirmed since the observed deviations from empirical data remain limited and can often be interpreted from the geohistorical context of urbanism proper to each world region. Moreover, the article provides new free software which authorizes the reproducibility of our experiments with our data bases as well as with complementary data.     

Ultrathin sectioning techniques

Epoxy mixtures incorporating Araldite available in Australia have been used to embed Recent organisms, fossils and sedimentary rocks. Resultant sections of embedded material may be less than 10 micrometres thick and give increased resolution of fine structures. Mixtures used and sectioning techniques are described.