Reine und angewandte Chemie Die Entstehung einer neuen Wissenschaftskonzeption in der Chemie der Aufklärung

In its attempt to achieve acknowledgement and support as a true science and academic discipline eighteenth-century chemistry experienced that the traditional distinction between theory and practice, respectively between science and art, was an incriminating heritage and did not longer conform to the way chemists saw themselves. In order to substitute the former, socially judging classification into theoretical science and practical art, J. G. Wallerius from Uppsala coined the term pure and applied chemistry in 1751. The idea behind this new conception was that it ought to be chemistry's research aim and not the kind of work, be it manual or intellectual, which was to decide about its branches and their dignity. The change in orientation which took place during the eighteenth century, and which is symbolized by the new dichotomy “pure and applied”, led towards a revaluation of the utilitarian aspects of chemistry. Its historical roots reach back to a long and fruitful cooperation of, and interaction between chemistry and economy, which was reinforced by the Stahlian tradition in Germany and Scandinavia. Subsequently, it was its strong economic bias that helped chemistry to become institutionalized and accepted as an academic discipline distinct from the medico-pharmaceutical profession. The analysis of this change of attitudes, behaviour and institutional pattern suggests that, at least during the period of institutionalization of this particular discipline, social structures and the intrinsic scientific contents are so tightly interrelated, that any division into “internal”, cognitive developments (facts, theory and subject-matter) and “external” conditions (social context and stategies of institutionalization) would be artificial, since they both constitute the scientific community as a context of argumentation and action.     

PROVENIENCE STUDY OF MEDIEVAL BULGARIAN GLASSES BY NAA AND CLUSTER ANALYSIS

The neutron activation analysis results from 30 glass samples were subjected to cluster analysis. The reliable localization of part of the medieval glass finds from Preslav enabled the evaluation of the variety of the production of a medieval glass workshop (ninth-tenth century), allowing conclusions to be made about the technological level of glass-making in Bulgaria during the Middle Ages. The work proved that NAA followed by cluster analysis is a successful approach to finding the local and chronological features of the investigated glasses.     

SPECTROCHEMICAL ANALYSIS OF SOME MEDIAEV AL GLASS FRAGMENTS FROM CATALAN GOTHIC CHURCHES

AAS, FE and OES are each used in the analysis of thirteen samples of fragments of window glasses from three Catalan Gothic churches: Sta. Maria del Mar (Barcelona, Spain), Pedralbes Monastery (Barcelona, Spain) and Girona Cathedral (Spain). Two kinds of stained window glass are found. Special attention is paid to Co/Cu, Co/Ni and Cu/Ni ratios for blue glasses and Mn/Cu and Fe/Cu ratios for red glasses.     

Day-to-day variations in nearshore bar patterns on a small sandy beach through a lunar tidal cycle

Nearshore water circulation and bar patterns at Coledale, New South Wales, were surveyed daily over thirty-six consecutive days, from 3 November to 8 December 1978, to identify sequences of changes that might occur in response to spring-to-spring tide cycles of fourteen days, changing barometric and wind conditions associated with the passage of anticyclonic weather systems across the coast, and day to day variation in the nearshore wave regime. During the survey the bar patterns tended to vary from transverse bars, through a composite arrangement incorporating longshore and transverse bars, to a longshore bar pattern as the tide changed from its spring to neap tide phase. However, this sequence was too brief to unequivocally establish variations in nearshore bar pattern that might be attributed to the fourteen day, spring-to-spring tide cycle. Nevertheless, morphologic changes occurring in response to wave regime fluctuation at Coledale were broadly in accord with studies from elsewhere by Dolan et al. (1979, 1982), and Clarke and Eliot (1982, 1983) in that bars and rips were systematically distributed along the beach. At Coledale, bars tended to relocate approximately 0.4 and 0.75 of the distance along the beach from its southern end. The preferred bar spacing closely matches hypothetical standing waves trapped between the headlands of the Coledale embayment. Temporally, the nearshore morphology is highly responsive to wave regime changes such that, as primary breaker heights decrease and remain below H_max=1.0m, the bar pattern changes from longshore through mixed to transverse bar patterns within three to five days. On one occasion the bar pattern switched from a longshore to a transverse bar pattern within twenty-four hours.     

TESTING SIZE-DENSITY RELATIONSHIPS WITHOUT RATIO-VARIABLES,MULTICOLLINEARITY, LOGARITHMIC TRANSFORMATIONS,OR REGRESSION ANALYSIS*

Using data describing the historical distribution of county seats in the United States, we (1) replicate the traditional ratio-variable test of the size-density law, (2) test a new multivariate, nonratio form of the law, and (3) introduce an alternative method of testing, one which avoids three possible problems in traditional analyses: ratio-variables, multicollinearity, and logarithmic transformation.     

The determinants of county growth

The determinants of population and employment growth were explored from a broader interregional (as opposed to intraregional) perspective. Data for the 1970s, at the county level of disaggregation, were used to analyze the effects of economic, demographic, and climatic variables on population and employment growth in a simultaneous equation framework. The use of data from the more than 3000 US counties provides a considerably larger testing ground than those used in previous research. The point of departure was a conventional, general equilibrium model in which both households and producers are geographically mobile. The study's dependent variables refer to population, total, and manufacturing employment densities. Family income had a powerful effect in stimulating both population and employment density. A 10% increase in family income led to a 7.9% increase in total and a 9.2% increase in manufacturing employment densities. High family income must stand for high demand, and thus, firms are drawn to an area. High family income also drew households to an area. A 10% increase in family income led to a 5.5% increase in population density. High family income must represent "good" neighborhoods for households. High family income was positively correlated with population and employment density, but in other recent studies either a negative and significant relationship or an insignificant relationship were reported. Local taxes consist of the receipts of county government and those of municipalities, townships, school districts, and special districts within the county. The elasticities reported in Table 4 suggest that a 10% increase in such taxes resulted in about a 0.072% reduction in county population density during the decade. The Industrial Revenue Bonds (IRBs) and the percent of the labor force that is unionized are 2 potential policy instruments at the state level. The study results suggest that IRBs have not stimulated either manufacturing or total employment, and the coefficients were statistically insignificant in the structural equations. The elasticities imply that a 10% increase in percent union reduces total employment by 0.42% and manufacturing employment by 0.18%. The effect on population was tiny. Further, while not intended, the interstate highway program may have been a significant redistributor of population and employment but has not caused immigration of people and jobs from central cities.