Georadar investigations in the central nave of Hagia Sofia,Istanbul (Turkey)

Within an interdisciplinary project to study Istanbul’s Hagia Sofia, a georadar survey was carried out in the central nave to assess if the deformations of the structure previously observed could be related to a differential behavior of the subsoil caused by architectural remains underneath. This study faces an unusual challenge since it was necessary to study the space beneath the scaffolding placed for the restoration works. The survey of the central nave was successful and allowed the detection of remains of walls that probably formed the basement of a previous 18- by 22-m structure. In addition, another interesting feature was discovered 2 m below the marble mosaic in the southeastern part of the nave. Although it is not possible to define its function, it seems that there could be a close relationship between this 2- by 3-m buried structure and the marble mosaic in the floor surface. Although some structures were identified under the floor of Hagia Sofia, there are no major changes in the topography of the central nave floor.     

The glass of Nogara (Verona): a “window” on production technology of mid-Medieval times in Northern Italy

The site of Nogara (province of Verona, Italy) provides valuable insights into the complexities of the glass industry in mid-Medieval times, due to its timing, which ranges mainly between the 10th and 11th centuries AD, and to the great quantity of glass findings, mainly tableware. In the present paper, the combination of archaeological, chemical and textural data allows us to identify production technologies in a time-interval perceived to be a period of technological transition for glass. In particular, the frequent occurrence of recycled natron glass and only a few glass samples made with soda plant ash indicate that recycling of earlier glass was common in inland Northern Italy in the 10th–11th centuries AD. In addition, blue and reticello decorations were obtained by recycling earlier glass mosaic tesserae, as shown by much Co, Cu, Sn, Sb and Pb and the presence of crystallised calcium antimonates. A few glass samples with chemical compositions intermediate between natron and soda plant ash glass were also identified, suggesting a gradual change in glass composition from natron-based towards soda ash-based production technology, which prevailed in the 13th-14th centuries. In conclusion, the difficulty in describing mid-Medieval glass as a well-defined entity, due to the great propensity for recycling earlier glass samples which causes variability in chemical compositions, particularly those of trace elements, is clearly documented here. In any case, this paper contributes to a new type of chrono-typological scanning and to more detailed knowledge of glass production technology during mid-Medieval times in Northern Italy, little found in the literature until now.     

Plants and Vegetation in the Archaeological Park of Neapolis of Syracuse (Sicily,Italy): A Management Effort and also an Opportunity for Better Enjoyment of the Site

Syracuse has been inscribed on the UNESCO World Heritage List since 2005. Notable for its visible traces of the ancient Greek city, the inscribed sites are mainly located on the Ortigia Islet and in the Neapolis Archaeological Park. In this park, in addition to monuments of global significance such as the Greek theatre carved into the rock in the fifth century bc, wild flora of great interest are preserved. Some species may have been introduced in the classical period. In 2013, significant maintenance interventions of green areas were made, aimed at safeguarding the monuments and the most relevant flora present. This activity provided an opportunity to create, through an interdisciplinary project, some guidelines for the management of the green cover, and has also created new opportunities for the use of the site through thematic routes.     

A hypothesis on different technological solutions for outdoor and indoor Roman wall paintings

The determination of the chemical composition of different parts of wall paintings (pigments, mortars and binders) provides information about technology of preparation of an artefact. Herein, we present a multi-methodological characterisation of wall paintings from a Roman archaeological site in Cuma, focusing on differences between an indoor (domus) and outdoor fabrication (a temple, Tempio con Portico (TCP)). Both pigments, binders and mortars were studied via a combination of destructive/μ-destructive (mass spectrometry, ionic chromatography, ICP-based techniques) and non-destructive (Raman microscopy, small-angle neutron scattering (SANS) and X-ray diffraction) methodologies. Particularly, the systematic presence of dolomite only in mortars from TCP may suggest an intentional use of such limestone for the outdoor fabrication of public interest. Differences between TCP and domus are also related to the composition of the pigment binder. In particular, the detected binders (studied by LC-MS/MS and GC-MS) were proteinaceous in the case of domus (possibly egg and animal glue) and drying oils in the case of TCP. Ultimately, our multi-methodological study provides an overall picture of the material components of paintings from fabrications with different use, proposing a hypothesis on technological choices according to conservative and destination reasons.     

Chemical Residues as Anthropic Activity Markers. Ethnoarchaeology,Experimental Archaeology and Archaeology of Food Production and Consumption

ABSTRACT

Chemical residues preserved in floors can be considered anthropic activity markers. In fact, residues are strictly related to the activities performed and reflect their spatial distribution. We present a synthesis of the work carried out over the last few decades in Mexico and Italy related to the study of chemical residues in floors. Residues can be identified performing specific chemical analyses both of plastered or earthen floors samples. We outline a methodological approach concerning the use of the markers of the activities to interpret food production and consumption in the archaeological record, based upon evidence from experimental, ethnoarchaeological and archaeological examples. Here we point out the advantages and problems of such an approach, mainly related to equifinality, of the use of spot tests and gas chromatography coupled with mass spectrometry techniques using examples from different sites in the world.     

Wood exploitation and food supply at the border of the Roman Empire: the case of the vicus of Thamusida – Sidi Ali ben Ahmed (Morocco)

This paper presents the results of inter-disciplinary work drawing on archaeobotanical and archaeometric studies to trace the agroforestry landscape and the supply economy at the vicus of Thamusida in north-west Morocco at the border of the Roman Empire. The available data indicate the self-sufficiency of the settlement in both forestry and agricultural products throughout the period investigated from the end of the 1st century BC to the beginning of the 4th century AD. Charcoal data testify to the presence of a Quercus suber forest in the close surroundings of the site and its exploitation for a variety of forestry products such as timber, fuelwood, cork, and probably also leaves and acorns to feed livestock. The overwhelming presence of Q. suber in the archaeological layer investigated clearly indicates that this forest was under human influence prior to Roman occupation and was already partially degraded. Charred seed and fruit remains suggest that the diet of both troops and civilians was mainly based on locally grown products and that all the inhabitants of the site had access to good cereals such as barley, naked wheats and pulses with large seeds such as horse bean and pea; quality fruits, such as olive and grape, were also produced locally for fresh consumption. Organic residue analyses of the contents of ceramic vessels and plastered vats allowed archaeobotanical data to be complemented, thereby shedding light on some of the imports at Thamusida. Despite the remote location of this settlement, imported goods such as oil and wine were transported here in amphorae from different parts of the Empire.     

New compositional data on ancient mortars from Hagia Sophia (Istanbul,Turkey)

This study shows the results of a multidisciplinary collaboration between the University of Calabria (Italy) and the National Autonomous University of Mexico (UNAM), about the compositional characterization of some mortars taken from Hagia Sophia in Istanbul (Turkey), one of the most important buildings in antiquity. Twenty samples of joint mortars were analysed by micro-chemical analyses (SEM-EDS), X-ray powder diffraction (XRPD), optical microscopy (OM) and transmission electron microscopy (TEM). The compositional study allowed us to define, with more detail, the construction phases of the fifth, sixth and tenth century. The petrographic analysis in thin section by optical microscopy showed four typologies of sands, used as aggregate, with specific compositional features. SEM-EDS analyses and TEM observations of the binder around the ceramic fragments of the aggregate showed the presence of different morphologies of single C-S-H compounds.