Minateda rock shelters (Albacete) and post-palaeolithic art of the Mediterranean Basin in Spain: pigments,surfaces and patinas

The inorganic and organic fractions of two microsamples of prehistoric paint from the same site, the Minateda rock shelters, are analysed here for the first time. The two samples correspond to two rock shelters of different styles (Levantine and schematic) – Abrigo Grande de Minateda (The Great Rock Shelter of Minateda) and Abrigo del Barranco de la Mortaja (Del Barranco de la Mortaja Rock Shelter). Since its discovery, historiographical tradition has emphasised the Abrigo Grande de Minateda, with its magnificence and complexity, as emblematic of the origin and evolution of rock art in the Mediterranean Basin of the Iberian Peninsula (a UNESCO World Heritage Site). Four complementary techniques –Microphotography, Scanning Electron Microscopy-Energy Dispersive X-Ray Spectroscopy (SEM-EDX), Raman Spectroscopy and Gas Chromatography–Mass Spectroscopy (GC–MS)– were combined to identify and characterise the physicochemical properties of the paint and of the surface. We present an interpretation of the results that leads us to define complex taphonomic alterations beyond the usual distinction of layers that include the surface, pigments and patinas.     

A high-resolution electron microscopic and energy-dispersive spectroscopic study on the molecular mechanism underpinning the natural preservation of 2300 Y.O. naturally-mummified human remains and the occurrence of small-sized [Zn][Al]Carbon spheres

In this paper we use Scanning and Transmission Electron Microscopy, and Energy Dispersive Spectroscopy to characterize the surface of the skin of a 2300 YO, naturally-preserved mummy, belonging to a two-year and eight month girl (“Pepita”), found inside a cave located in Altamira, Querétaro, México (21°40′–20°01′; 99°03′–100°36′). The cave was found in Sierra Gorda, an orographic region with a relief of sedimentary origin from the Gulf of Mexico, composed by high mountains with altitude values surpassing 3000 m above sea level, with ample and steep canyons, and a prominent role on the exploitation and distribution of cinnabar (HgS). The skin showed the presence of small-sized spherules, containing Al (≤43%) in the most exposed region (5–10 μm depth). Thin layers and structural microdomains covered small and large spheres. Structures conformed by stacked, nano-sized particles located far-from-the bunches contained C (≤45%), Zn and Si (≤10%), and minor amounts of Ca (≤2.6%). By contrast, regions between spheres contained high amounts of Ca (≤23%) and Al (≤15%), but lacked Zn and Si. Carbon spheres showed two distinctive composition, a signature that their formation might have occurred in a least two different stages via concentric growth mechanisms, with the incorporation of Zn and Al at a later stage. [Zn][Al]Carbon spheres showed morphology and growth patterns that compared to those resulting from the hydrothermal carbonization by Fe²⁺ ions under mild conditions, suggesting a common mechanism of formation. Textural changes of thin films found between [Zn][Al]Carbon spheres were attributed to differences in viscosity, which might have contributed to increases in functionality and specific surface area (by means of decreases in size) and, in turn, facilitating the sequestration of biomolecules. We propose that the presence of [Zn][Al]Carbon spheres provides protection against bacterial and UV attack. The physical properties of these spheres helped entrap biomolecules. Taken together, these factors contributed to the preservation of Pepita.     

The siege of Barbastro 1064–65: a reassessment

In 1064 a large army of foreign troops, especially Normans and Catalans, fought against the Muslims at the fortress city of Barbastro, located in Zaragoza. The siege of Barbastro is, for several reasons, one of the most controversial battles of the early reconquest in Spain. Some of the problems that historians of the crusades and the reconquest have struggled with are: the indulgence letter that Alexander II allegedly granted to the soldiers at Barbastro and whether this makes Barbastro the ‘First’ crusade preceding the one called by Pope Urban II. In addition, the extent of involvement by Pope Alexander and the Cluniacs in propagating the ‘crusade’ has been debated. Equally problematic has been the identification of the leader of the Christian soldiers. Candidates chosen for the enigmatic leader have been Duke William VIII of Aquitaine, William of Montreuil, and the Norman, Robert Crispin. A review of the secondary and primary sources reveals that many long-held conclusions are in need of re-evaluation. A complete reassessment of these and other related problems is the intent of this study.     

Classification and provenance of soapstones and garnet chlorite schist artifacts from Medieval sites of Tuscany (Central Italy): insights into the Tyrrhenian and Adriatic trade

Soapstones (talc-bearing schists) and garnet chlorite schist artifacts found in Medieval archaeological sites of Tuscany (Central Italy) were classified, in order to define provenance of the different lithotypes. In Italy and throughout the Central Europe, these greenschist facies metamorphic rocks are generally known, among the archaeologists, as the pietra ollare from the Alps. The investigated Tuscan archaeological sites are between 6 and 13th century AD and were strictly linked, in that period, to the well defined network trade running along Tyrrhenian coast. Samples come from little containers used for cooking and preserving food and showing traces of lathe manufacturing at their sidewalls. According to modal mineralogy, petrographic texture, XRD, SEM-EDS and whole rock chemistry we recognised, among the 18 studied findings, three different petrographic groups of the Alpine pietra ollare. (i) Fine grained magnesite talc schists (i.e. soapstones) from outcrops of the Central Alps located in the Valchiavenna area. (ii) Garnet chlorite schists from the Valle d'Aosta region. (iii) Amphibole talc schists (i.e. soapstones) with a provenance in the Ticino area. It is worth noting that artifacts of pietra ollare lithotypes from the Western Alps (i.e. garnet chlorite schists and amphibole talc schists) were not detected in the archaeological sites of the Middle Adriatic coast of the Central Italy, belonging to the same Medieval time interval. This emphasises that the petrographic groups of pietra ollare from the Alps spread to the south of the Po Plain according to Western and Eastern trade along the Italian Peninsula, using respectively, the Tyrrhenian and the Adriatic Sea commercial routes.     

Plague immunodetection in remains of religious exhumed from burial sites in central France

The skeletons of four Benedictine nuns and two priests were exhumed from two burial sites in central France. The corpses were dated to the 16th– 18th centuries (archaeological dating).     

Internationalization in the Helsinki Metropolitan Area: Images,Discourses and Metaphors

This paper investigates promotional images in the Metropolitan Area of Helsinki, focusing on the projection, outside national boundaries, of specific “ideas” concerning the cities of Helsinki, Espoo and Vantaa. After introducing the Helsinki Metropolitan Area, presenting its geographical features, urban dynamics, actual problems and actors involved in image-building, the focus of this research will be a comparison between the images proposed in promotional materials and policy documents by the various territorial units, looking at their differences, overlaps, synergies and clashes. In fact, as will be discussed, even if the images proposed by the cities consist of the same thematic fields (technology, nature, culture, etc.), they contain slightly different implicit messages, targets, representations of the cities, values, strategic orientations and approaches.     

Unglazed pottery from the masjed-i jom’e of Isfahan (Iran): technology and provenance

The masjed-i jom’e of Isfahan is one of the earliest mosques of Iran. Since 1970, Italian researchers performed an extensive archaeological investigation uncovering huge amounts of finds. This study aims at investigating the technological features and provenance of the unglazed pottery finds by using a minero-petrographic approach. Twenty-three samples of storage, table and cooking wares were selected based on the recurrence of typologically identifiable fragments and fabrics. Two bricks, seven production indicators (spacers, kiln furniture, slags) and a local clay were analysed for comparison. The production indicators and most of the pottery show high-CaO concentration. Thick-walled wares contain coarse sedimentary/metamorphic inclusions. Samples with thinner walls contain similar but fine/well-sorted inclusions. The mineralogy and microstructure indicate firing temperatures mainly ranging from 850 to 1000 °C. Low-CaO samples contain coarse sedimentary inclusions; in one sample, volcanic lithics are present. Firing temperatures range from about 800 to 950 °C, and the low-CaO character can be related to their specific function for cooking foods. One sample, found in older stratigraphic levels, differs for its peculiar calcitic temper and lower firing temperature. Local production of most samples was constrained by the composition of the inclusions compatible with the sediments of the Isfahan area. High-CaO pottery shows compositional affinity with production indicators, local clay and tiles produced in Isfahan during the Safavid period. Cooking ware usually contains local temper, with the exception of a sample with volcanic inclusions, for which a non-local provenance is supposed. No appropriate information is, however, available regarding the low-CaO clays used in the area.     

«Une mission glorieuse et profitable» réforme missionnaire et économie sucrière dans la province jésuite du Brésil au début du XVIIe siècle

At the beginning of the seventeenth century, the Jesuit province of Brazil is affected by tensions which reveal the complexity of its relation both with the colonial society and with the Roman center of the order. The paper is focused on an exceptional and original document about which nothing is clearly identified (author, date), theAdvertências para a província do Brasil. It allows a precise analysis of the missionary enterprise, as an economico-political experience (the Jesuits become one of the most important sugar producers of the country), and as a spiritual experience (through the salvation of the missionaries and the conversion of the Indians). This document is centered on thealdeia which is described as the main structure for the action of the Jesuits in Brazil. In that way, it reveals a global vision of the mission, geopolitical, economical and religious, which has systematically been overshadowed by the traditional historiography, whose approach of the missionary phenomenon was exclusively spiritual.     

The Prehistoric Exploration and Colonization of Fuego-Patagonia

The main goal of this paper is to review the earliest archaeological evidence for the presence of humans in Fuego-Patagonia. The paleoenvironmental and paleoclimatic framework is briefly introduced, followed by a discussion of its relevance to understanding the exploration and colonization of Fuego-Patagonia. Technological and faunal evidence from a number of sites from the southern extreme older than 10,000 B.P. is analyzed. This leads to the conclusion that an early entry, at least 12,000 years old, appears best to accommodate the available chronological evidence. On the other hand, data from the Northern fringes of Patagonia clearly suggest an earlier human colonization.     

A Late Roman ceramic production from Pompeii

The Via Lepanto site is one of the best examples showing how the Vesuvian region was partially reconstructed and earlier re-occupied after Vesuvius's eruption in the year 79 AD. The large amount of ceramic finds illustrates the typology in use in this area during the IV and V century AD. Analyses were focused on table and cooking ware productions. Archaeometric data were obtained using chemical and minero-petrographical methods (OM, XRD, XRF and SEM). Grain size measurements using Image Analyses on thin sections and a geochemical comparison with clayey deposits outcropping in the Campania region permitted the identification of the raw materials used for these pottery productions. XRD and SEM completed the data set, establishing the protocols used for pottery production in the Pompeii area during Late Roman period. The Via Lepanto site was part of an exchange network of markets with a periodic frequency, where locally produced and imported pottery was sold, indicating a flourishing network of exchanges spanning short, medium and long distances.