Geochronology of plutonic rocks from the Sanandaj-Sirjan zone,Iran and new zircon and titanite U-Th-Pb ages for granitoids from the Marivan pluton

The Sanandaj-Sirjan zone of Iran is a metamorphic belt consisting of rocks which were metamorphosed under different pressure and temperature conditions and intruded by various plutons ranging in composition from gabbro to granite. The majority of these granitoids formed along the ancient active continental margin of the Neo-Tethyan ocean at the southeastern edge of the central Iranian microplate. Geochronological data published in recent years indicate periodic plutonism lasting from Carboniferous through Mesozoic to late-Paleogene times (from ca. 300 to ca. 35 Ma) with climax activity during the mid- and late-Jurassic. The age constraints for plutonic complexes, such as Siah-Kouh, Kolah-Ghazi, Golpayegan (Muteh), Azna, Aligoodarz, Astaneh, Borujerd, Malayer (Samen), Alvand, Almogholagh, Ghorveh, Saqqez, Marivan, Naqadeh and Urumieh, clearly indicate the periodic nature of magmatism. Therefore, the Sanandaj-Sirjan zone preserves the record of magmatic activity of a complete orogenic cycle related to (1) Permocarboniferous(?) rifting of Gondwana and opening of the Neo-Tethyan ocean, (2) subduction of the oceanic crust, (3) continental collision and (4) post-collision/post-orogenic activities. The formation of the Marivan granitoids, northwestern Sanandaj-Sirjan zone, for which we present U-Pb zircon and titanite ages of ca. 38 Ma, can be related to the collisional and post-collisional stages of this orogenic cycle.     

Towards the application of desorption electrospray ionisation mass spectrometry (DESI-MS) to the analysis of ancient proteins from artefacts

The detection and identification of protein residues from archaeological artefacts has been the subject of considerable controversy over the past two decades, this controversy spurring the application of a range of different analytical methods. Part of the debate surrounds the ability of the methods to uniquely identify original proteins. Another is the apparent contradiction between the ease of extraction in the laboratory of residues that have managed to survive in sediment over millennia; some studies use simple solvents including water, whilst others claim that efficient extraction requires the destruction of the artefact.Desorption electrospray ionisation mass spectrometry (DESI-MS) offers the potential to directly analyse proteins bound to the surface of artefacts. The method permits desorption of analytes under ambient conditions directly from a wide range of surfaces with little or no sample preparation. This has already led to its application in a range of areas, including forensic analysis of trace levels of narcotic drugs. It does not require destruction of the artefact (e.g. by drilling or dissolution) and can work in concert with other methods (for instance it could be used as a screening tool prior to lipid extraction).Here we report the construction of a DESI-MS interface and consider the potential of the method to contribute to the debate surrounding the preservation of proteins on artefacts. The DESI-MS interface was fitted to a conventional ion trap mass spectrometer and tested using peptides and proteins artificially applied to the surface of flint flakes and potsherd samples. A range of intact proteins was analysed; the DESI interface identified test proteins up to a maximum molecular weight of approximately 20 kDa. Peptides generated from these and larger proteins could be detected using DESI-MS following tryptic digestion in situ. The collected data allowed identification of the originating proteins. The potential applications to archaeological science of this new analytical tool are discussed.     

Real-time Seismic Damage Detection of Concrete Shear Walls Using Artificial Neural Networks

Concrete shear walls are widely employed in buildings as a main resistance system against lateral loads. Early identification of seismic damage to concrete shear walls is vital for deciding post-earthquake occupancy in these structures. In this article, a method based on artificial neural networks for real-time identification of seismic damage to concrete shear walls was proposed. Inter-story drifts and plastic hinge rotation of concrete walls were used as the inputs and outputs of a MLP neural network. Modal Pushover Analysis was employed to prepare well-distributed data sets for training the neural network. The proposed method was applied to a five-story concrete shear wall building. The results from the network were compared with those obtained from Nonlinear Time History Analysis. It was observed that the trained neural network successfully detected damage to concrete shear walls and accurately estimated the severity of seismic-induced damage.     

Better than an Ironclad: Leonard Isitt,Temperance and Greater Britain

The English-born New Zealand temperance activist, the Rev. Leonard M. Isitt, undertook a number of temperance ‘missions’ in Britain between 1895 and 1905, offering historians a deeper insight into the lived reality of the ‘British world’ and ‘Greater British’ identity. Addressing several areas of imperial historiography, the article uses newspapers from both New Zealand and Britain to acquire a truly ‘Greater British’ perspective of an imperially mobile individual, from which can be drawn lessons about imperial identities and ‘networks’. Isitt's participation in a self-consciously imperial temperance movement highlights the development of a New Zealand identity that depended upon both contrast and commonality with Britain, but it also points to a politics of imperial peregrination, with the temperance reformer's visits to the ‘Mother Country’ factoring in the highly divisive drink question in both New Zealand and Britain. The article concludes with reflections on the nature and limitations of a ‘Greater British’ politics.